TY - EJOU
AU - Ranjan, R.
AU - Negi, C. M. S.
AU - Choubey, S. K.
AU - Tiwary, K. P.
TI - Study of structural, morphological and optical properties of Mn+2 doped CdS nanoparticles synthesized at various doping concentration
T2 - Chalcogenide Letters
PY - 2023
VL - 20
IS - 10
SN - 1584-8663
AB - Manganese-doped cadmium sulphide semiconductor nanoparticles (CdS: Mn) NPs have
been created utilizing a microwave-assisted solvothermal technique at different Mn
concentrations (0, 1%, 3%, and 5%). The chemicals utilized for the preparation of Mn
doped CdS nanoparticles were sodium sulphide (Na2S.xH2O), manganese chloride
(MnCl2.4H2O), and cadmium acetate (CH3COO)2Cd., H2O). To determine the structural
dimensions of the generated nanoparticles, the Debye-Scherer equation was used to
calculate the average crystallite size at the full-width half maximum (FWHM) of the
diffraction peaks. FTIR spectra analysis was used to look at the various functional and
vibrational groups present in the Mn-doped CdS nanoparticle sample. The structure
features of the produced nanoparticles have been examined using X-ray diffraction
patterns. Energy dispersive X-rays were employed to ascertain the chemical composition
of the synthesized nanoparticles. The optical properties and quantification of the energy
band gap of the nanoparticles have been done using UV-V spectroscopy. According to
XRD calculations, the cubic zinc-blend structure of the generated NPs had a crystal size of
between 4 and 7 nm. By using EDX spectroscopy, the incorporation of Mn at the CdS
lattice was confirmed.
KW - Mn-doped CdS nanoparticles
KW - X-ray diffraction
KW - FTIR spectra
KW - UV visible spectra
DO - 10.15251/CL.2023.2010.709