TY - EJOU
AU - Gayathri, R.
AU - Soundare, S. Shanmugha
AU - Haritha, K.
AU - Ariponnammal, S.
TI - Probing SnSO3/ZnSO3 nanocomposites by optical and magnetic perspective
T2 - Chalcogenide Letters
PY - 2024
VL - 21
IS - 12
SN - 1584-8663
AB - SnSO3/ZnSO3 nanocomposite has been synthesized using the hydrothermal process. The
complete formation of the SnSO3/ZnSO3 nanocomposite is confirmed by XRD and EDAX.
It displays a fascinating rectangular bar shape. The measured particle size is 100.4 nm. It
will be a promising option for optoelectronic devices. Energy gap of the SnSO3/ZnSO3 nanocomposite is 5.85 eV. The refractive index of the nanocomposite through its energy
gap is found to be 1.883. The ultraviolet (~387.2 nm) area of the PL emission spectrum
exhibits the strong efficient emission, while the green (~522.1 nm) region and the red
(~789.4 nm) region show weak and moderate emission, respectively. Radiative electronhole
recombination is seen in the UV emission at 387.2 nm, which qualifies the contender
for displays/projection-based applications. Emission peaks observed in the visible region is
attributed to various defects Frenkel or Schottky defects, Tin or Zinc interstitials and oxygen
vacancies. The finger print region's S-O, Zn-O, and Sn-O bands are confirmed by the
accurately assigned FTIR bands. At 300K, the sample displays diamagnetic behaviour.
Additionally, at 5K, it displays an intriguing super paramagnetic behaviour between -0.15
Tesla and 0.15 Tesla.
KW - SnSO3/ZnSO3 nanocomposite
KW - Hydrothermal method
KW - Structural
KW - Optical
KW - Magnetic studies
DO - 10.15251/CL.2024.2112.1001