@Article{CL.2025.229.821,
AUTHOR = {A. N. Jafarova, A. F. Gochuyeva},
TITLE = {Photoelectric effects in polymer – (CdS) – ferrocene composites},
JOURNAL = {Chalcogenide Letters},
VOLUME = {22},
YEAR = {2025},
NUMBER = {9},
PAGES = {821--828},
URL = {http://www.techscience.com/CL/v22n9/64834},
ISSN = {1584-8663},
ABSTRACT = {In our work, we investigated the photoelectric effects arising in composites consisting of 
polar (fluorine-containing) and non-polar (polyolefin) polymers—such as high-density 
polyethylene (HDPE), PVDF, F42 — and an inorganic phase composed of A<sup>II<</sup>
B<sup>VI</sup>
 (CdS, 
ZnS) and ferrocene. In addition, the processes occurring in these composites during the 
creation of these effects have been studied. It was found that the parameters of the 
formation of the posistor effect in the polymer-ferrocene composite are related to the 
presence of an interphase potential barrier, which is determined by the geometric 
dimensions of the interphase transition layer, dielectric permeability, electric charge state, 
and the difference in ionization potentials of ferrocene and the transition layer. The main 
reason for the formation of the photoquenching effect of the rotational conductivity in 
polyolefin-ferrocene composites is the formation of a local electric field directed opposite 
to the external field as a result of the formation of multi-charged centers and dipole 
moments in the ferrocene phase under the influence of light. },
DOI = {10.15251/CL.2025.229.821}
}