@Article{JPM.2019.36.02.3,
AUTHOR = {FEHMI SALTAN, AYLIN PALAMUTLU, HAKAN AKAT},
TITLE = {Copolymerization of 5-[4-(methacryloylamino)phenyl]- l0,15, 20-triphenylporphyrin with Styrene: Investigation of Spectroscopic, Structural and Thermal Properties},
JOURNAL = {Journal of Polymer Materials},
VOLUME = {36},
YEAR = {2019},
NUMBER = {2},
PAGES = {133--147},
URL = {http://www.techscience.com/jpm/v36n2/56074},
ISSN = {0976-3449},
ABSTRACT = {In this work, tetraphenylporphyrin (TPP) compound was first synthesized by the condensation
reaction of pyrrole and benzaldehyde using Adler method. Then, the synthesized
tetraphenylporphyrin was nitrated with sodium nitrite. Nitro-functionalized porphyrin (TPP-NO<sub>2</sub>
)
compound was reduced to amine-functional using ammonia and this amine- functionalized
porphyrin was reacted with methacryloyl chloride to obtain porphyrin-derived radical monomer
(TPP-MAO). Copolymer was synthesized with obtained porphyrin functional monomer and styrene
by free radical polymerization method. Structural characterization and spectroscopic studies of
the synthesized compounds were carried out by FTIR, H<sup>1</sup>
-NMR, UV spectroscopy. The molecular
weight and thermal properties of the copolymer were determined using gel permeation
chromatography (GPC) and thermogravimetry (TG). Tetraphenyl porphyrin containing polymer
shows good photoluminescence property.},
DOI = {10.32381/JPM.2019.36.02.3}
}