TY  - EJOU
AU  - Sahmim, Wissem 
AU  - Boer, Febrina Dellarose 
AU  - Chapuis, Hubert 
AU  - Obounou-Akong, Firmin 
AU  - Pizzi, Antonio 
AU  - Gérardin, Philippe 
AU  - Gérardin-Charbonnier, Christine 

TI  - Feasibility Study of the Synthesis of Isocyanate-Free Polyurethanes from Catechin
T2  - Journal of Renewable Materials

PY  - 2022
VL  - 10
IS  - 5
SN  - 2164-6341

AB  - With the current trend of increasing efforts to develop non-isocyanate-based polyurethanes (NIPUs), this study aimed to check the feasibility of the development of a method using cyclic carbonate modified catechin and amine to synthesis non-isocyanate urethane with the objective to further extend these results to polyurethane synthesis. The methods used in this study consist of four steps: glycidilation of catechin, hydrolysis of epoxide, cyclic carbonate synthesis, and carbamate synthesis through condensation of butylamine. The resulting products were analyzed using FTIR (Fourier transform infrared) spectroscopy and NMR (nuclear magnetic resonance) spectroscopy. The results showed that carbamate could be successfully obtained through this four-steps synthesis, opening the possibility to further developments for the synthesis of polyurethanes starting from catechin and condensed tannins.
KW  - Catechin; cyclic carbonate; isocyanate-free; glycidilation; carbamate

DO  - 10.32604/jrm.2022.016365