A phosphogypsum-based subgrade stabilizer (PBSS) was formulated using industrial by-product phosphogypsum (PG), mixed with slag and calcium-silicon-rich active material (GSR). The active powder (AP) was used to modify PBSS, and PBSS-AP was obtained. PBSS and PBSS-AP were each mixed with 10% silty soil, and cement and lime (CAL: 5% lime + 2% cement) were used as the traditional material for comparative experiments. Samples were cured under standard conditions, and tested for unconfined compressive strength (UCS), water stability, volume expansion, and leachate, to explore the stabilization effect of the three solidified materials on silty soil. The results showed that the comprehensive performance of sility soil mixed with 12% PBSS-AP was the best. The CaO, SiO2 and Al2O3 provided by PG, Slag and GSR will react with water to form a stable C-S-H gel, which is conducive to stabilizing the soil. Field application results showed that the compaction exceeded 95%, the deflection was 144.9 mm, and UCS was 2.5 MPa after 28 days. These findings indicated that PBSS-AP is an effective stabilizer for subgrade soils.
Phosphogypsum (PG), a by-product of industrial production of phosphoric acid and phosphate fertilizer, has a unique characteristic where it swells after absorbing water [1]. The annual global production of PG is approximately 100–280 million tons [2–4]. The rate of PG utilization is low compared to that of other industrial wastes, owing to the fact that phosphogypsum swells after absorbing water, and also contains dangerous elements [5]. Nevertheless, previous studies have shown that PG can be used in the manufacture of cement admixtures, mortars, sulphuric acid, soil improvers, and salts [6–10]. Although, the amount of PG used in production of these products is relatively small, it is challenging to overcome its large accumulation [7,11–13]. Consequently, PG now occupies large amounts of land areas that could otherwise be used for cultivation. When rainwater soaks into the ground, several harmful substances penetrate, causing soil compaction and contaminating groundwater, thereby causing serious threats to people’s lives [12].
Lime and cement are traditional soil subgrade stabilizers that are extensively used in road engineering, owing to their superior economic and excellent solidification effects [14–18]. However, production of lime and cement requires large amounts of natural raw materials, and the process emits large amounts of harmful exhaust gases, such as CO2, SO3, and NOX [19,20]. To protect the ecological environment and lower road construction cost, researchers are currently exploring use of industrial waste as a substitute for traditional cement and lime. For example, Mavroulidou [21] explored approaches to improve different clay properties of waste paper sludge [21], while Seslija et al. [22] used fly ash to replace natural materials as building materials. On the other hand, Etim et al. [16] used iron ore tailings and lime as soil conditioners to improve the properties of black cotton soil. Their results showed that these materials significantly reduced the environmental impact of iron ore tailings disposal, and the improved soil could be used as a low-flow roadbed material. Moreover, Reginald and Abir [23] explored the potential use of cement and lime-activated blast furnace slag in solidified mixed contaminated soils, by determined unconfined compressive strength and leaching toxicity.
The Chinese government’s emphasis on the need for environmental protection has resulted in reduction in production and use of traditional road building materials that have high energy consumption and high emissions, such as lime and cement [24–26]. Since the demand for raw materials in road engineering remains high, researchers have shifted attention onto PG as an alternative material to cement and lime, with the aim of increasing its industrial-scale consumption opportunities. In fact, PG can solve the problem of excessive cost of traditional materials in road construction. Since its first use in road engineering in the USA in 1980, analytical results have shown that PG mixed with soil results in a stable structure [2]. To date, however, only a handful of studies have explored the use of PG in large-scale road engineering, mainly because large amounts of PG have poor effects on soil pressure resistance and water stability [27]. For example, Ding et al. [5] reported that excessive use of PG in roads caused roadbeds and pavements to swell and form cracks. In addition, Tebogo et al. [3] explored the properties of soils solidified with large amounts of PG and other wastes. In the present study, the active material AP was used to modify PG, with the aim of improving the unconfined compressive strength, water resistance, and volume stability of phosphogypsum-based soil-solidified materials (PBSS). In addition, performance of the solidified materials after application in road construction was also evaluated.
Materials and MethodsMaterialsSoil
Silty soil from northern Jiangsu, China was used in the current study. The construction standards of a normal roadbed indicate that soil to be used should be mixed with that of solidified material under an optimal moisture content [28]. Prior to stabilization, the chemical composition of the silty soil was determined via X-ray fluorescence spectrometry. Results for specific test results are presented in Table 1, whereas results of the basic physical properties of the silty soil determined in accordance with the specifications of the Chinese GB/T 50123-1999, are shown in Table 2.
Chemical composition of silty soil
Composition
SiO2
Fe2O3
Al2O3
TiO2
CaO
MgO
K2O
Na2O
P2O5
MnO
LOI
Content (%)
59.97
4.14
12.58
0.69
8.28
2.59
2.37
1.50
0.32
0.06
7.23
Note: R2O: alkali metal oxide; LOI: loss on ignition at 1000°C.
Basic physical properties of silty soil
Basic nature
Specific gravity
Liquid limit (%)
Plastic limit (%)
Dry density Maximum (g/cm3)
Optimum moisture content (%)
Density (g/cm3)
Value
2.61
30
16
1.71
16
1.79
Results showed that SiO2 (59.97%) was the main component of the silty soil, followed by Al2O3 (12.58%), and CaO (8.28%) (Table 1). The silty soil had a specific gravity of 2.61 g/cm3, with liquid and plastic limits of 30 and 16%, respectively, and an optimum moisture content of 16% (Table 2).
Soil Stabilization Material
The main raw materials for preparation of PBSS included original PG, Calcium-silicon-rich active material GSR, and slag. Original PG is provided by Jiangsu Yuxing Chemical Industry Co., Ltd., China. GSR, and slag purchased from Suqian Huawo Building Materials Trading Co., Ltd., China. Lime and cement (CAL) are traditional soil-solidified materials used on roadbeds. Since the subgrade is likely to expand if the amount of lime in the subgrade is too high, used 2% and 5% cement and lime, respectively, in the soil [29,30]. The main chemical components of the original PG, Slag, and GSR based on X-ray fluorescence spectrometry are presented in Table 3.
Next, explored the properties of the newly solidified material PBSS prepared using a large amount of industrial PG, and modified into PBSS-AP by adding AP. Results indicated that PBSS-AP could improve performance of solidified silty soil, thus ultimately meeting the roadbed requirements. The proportion of the original PG in PBSS was selected as 40% following several orthogonal and optimization experiments, and based on the compressive strength of the sample and amount of phosphogypsum used. In addition, used traditional CAL samples for comparative experiments to explore stability of PBSS in the subgrade soil. Since the newly solidified PBSS material comprised large amounts of PG, it was necessary to explore long-term stability of the cured sample. This included long-term analysis of samples solidified by three different materials, namely PBSS, PBSS-AP, and CAL. To this end, several tests including, analysis of UCS, water stability, volume stability, and toxicity of leachate, were performed.
Chemical composition of raw materials
Material
SiO2
Al2O3
CaO
Fe2O3
SO3
MgO
TiO2
P2O5
LOI
PG
11.68
2.96
30.53
0.35
46.55
0.48
—
1.65
3.57
Slag
38.56
13.20
26.24
3.77
0.70
14.22
0.56
0.05
0.74
GSR
21.35
5.45
57.03
3.69
3.10
4.01
0.28
0.16
2.51
Note: R2O: alkali metal oxide; LOI: loss on ignition at 1000°C.
Additives
The additive, AP, is an inorganic and silicon-rich powder developed to improve early strength of soil-solidified materials. The optimal proportion of AP in the present study was 5% of PBSS. The active material AP was thoroughly mixed with PBSS for 3 minutes during formulation of PBSS-AP to improve uniformity of contact between the additive and PBSS. See Table 4 for the AP chemical composition.
Chemical composition of AP
Material
SiO2
Al2O3
CaO
Fe2O3
SO3
MgO
K2O
MgO
LOI
AP
91.34
1.25
1.45
1.32
0.31
1.14
1.02
—
2.17
Note: R2O: alkali metal oxide; LOI: loss on ignition at 1000°C.
Experimental MethodsSample Preparation
Silty soil was first dried for 24 h, in a blast-drying oven at 80°C, to evaporate all water, then sieved to remove impurities. The solidified material was mixed with the silty soil for 30 s using a cement mortar mixer, distilled water added to the contents, followed by uniform mixing. The stirring continued for 3 min based on the optimal moisture content (slow stirring for 2 min, rapid stirring for 1 min). The resulting mixture had a maximum dry density and optimal moisture content of 1.67 g/cm3 and 15%, respectively. A hollow cylindrical steel mold, with an inner diameter of Φ 50 mm × 50 mm, was used for sample preparation. The uniformly mixed mixture was first placed in a mold, and press-molded using a hydraulic jack. Thereafter, the sample was incubated in a standard curing box maintained at a temperature of 20 ± 2°C, and relative humidity 90%.
Unconfined Compressive Strength (UCS)
Analysis of the sample UCS was divided into two parts. The first part entailed determination of the effect of different amounts of PBSS in the soil on the UCS value of the sample, while the second involved analyzing the effect of silty soil with different solidified materials (CAL, PBSS, and PBSS-AP) on the UCS value of the sample. The amount of PBSS and PBSS-AP in the soil was maintained at 10%, to avoid swelling due to excess phosphogypsum content and reduce application costs. The experimental method was based on the specifications of the Chinese standard JTG E51-2009, which is similar to ASTM D-2166. UCS of the sample was determined using WHY-200 microcomputer-controlled automatic compression tester.
Determination of Water Stability
Previous studies have shown that analysis of water stability is an indispensable test following completion of road subgrade construction, while the degree of damage to the roadbed after rainwater erosion can directly affect quality of the road [31,32]. In this study, the low-lying section of the road was immersed in water to simulate the effect of long-term rainy weather on the roadbed. The experiment was performed by immersing the prepared sample in a water tank for different periods of time and periodically observing the shape of the sample. The sample was taken out on day 3, 7, 28, and 60. Next, moisture on the surface of the sample was gently absorbed using a dry paper towel, and the sample weighed. The rate of water absorption Rw in the sample under different soaking times was calculated as follows:
Rw=G2−G1G1×100%
where Rw represents water absorption, G1 and G2 denote mass of the sample before and after immersion in water, respectively, at a specific time. The sample’s UCS value was also determined after soaking. All water stability experiments were performed in accordance with the requirements of the Chinese standard JTG E51-2009.
Determination of Volume Stability
CaSO4·2H2O reacts with calcium oxide (CaO) and activated alumina (Al2O3), after addition of PG to the soil, to produce hydrated calcium sulphoaluminate (generally referred to as ettringite), which rapidly explodes when exposed to water, thereby causing significant damage to the road bed and surface [27]. In the present study, the rate of volume expansion in the sample was determined according to the guidelines in the Chinese Standard GB/T 50123-1999, with the aim of determining variations in sample volume following addition of the three different solidified materials to silty soil.
Leachate Test
A Leachate test was performed according to the latest Chinese Standard HJ 557-2010. Specifically, the cured sample at a certain age was first crushed and passed through a sieve (with a 3 mm aperture), then 100 g of the sieved sample particles mixed with 1000 ml of deionized water in a clean plastic bottle. The oscillation frequency of the horizontal oscillator was adjusted to 100 ± 10 times/min with an amplitude of 40 mm. Next, the leachate was shaken at room temperature for 8 h, and let to stand on the bench for 16 h. Finally, the supernatant was filtered through a 0.45 μm microporous membrane, and the filtered leachate collected for testing.
Microscopic Analysis
A scanning electron microscope (SEM) (JEOL, JSM-5900, Japan) was used to examine the surface topography of pure PBSS and PBSS-AP paste-hardened bodies. Differences in surface and structure between them were then compared.
Laboratory Test ResultsUnconfined Compressive Strength
UCS results across test samples at different ages, after addition of different soil solidified materials, are presented in Fig. 1. Summarily, the proportion of PBSS and PBSS-AP was maintained at 10%, whereas the traditional lime-cement system comprised 5% lime and 2% cement. Moreover, the UCS of the sample doped with the PBSS material was significantly higher than that of conventional lime-cement material (Fig. 1). The early strength of the PBSS-AP sample was also significantly improved. The UCS of the PBSS-AP sample at 7 days was approximately 4 MPa, whereas that in the sample with Lime-cement was approximately 2 MPa. Notably, the late strength of the PBSS sample was the most significant, increasing from less than 3 MPa at 7 days of curing to more than 4 MPa after 28 days. No significant changes in UCS value of the lime-cement sample during a similar period, with 2.5 MPa recorded after 28 days of curing. The UCS of the PBSS-AP sample showed only a slight increase in the later period due to the high strength in the early period.
Effect of different soil stabilizing materials on UCS (means and standard deviations)
Changes in UCS, after addition of different amounts of PBSS, are shown in Fig. 2. Summarily, UCS increased from 3.2 MPa after 7 days of curing, to 4.4 MPa at day 28, when PBSS proportion was increased to 15%. However, the increase in UCS was not statistically significant relative to that observed in samples with 10% PBSS over the same period.
Effect of different PBSS dosage on UCS (means and standard deviations)
Water Stability
Samples mixed with lime and cement had lower weights than those from PBSS and PBSS-AP under similar conditions (Fig. 3). This was mainly attributed to the fact that PBSS and PBSS-AP samples were continuously absorbing water from a hydration reaction to produce a structurally stable hydrated calcium aluminate (C-A-H) [5]. However, CAL had a more stable hydration reaction, and a lower UCS value than those obtained in PBSS and PBSS-AP samples.
Weight of samples with different stabilizing materialsat different times (means and standard deviations)
Lime-cement samples had a significantly higher water absorption rate than PBSS and PBSS-AP under different times (Figs. 4 and 5), mainly because the lime inside lime-cement samples required more water to decompose [33]. Notably, PBSS and PBSS-AP samples became denser due to the hydration reaction, and water molecules were not easily accessible. Apart from the sample’s special structure, another reason for the higher absorption rate may be that water molecules continuously gained entry to the inside of the sample for the hydration reaction. Furthermore, the sample had a lower water absorption rate after 28 days of curing than at 7 days. The rate of water absorption for PBSS-AP sample immersed in water was 7.3% after 3 days, and 8.2% after 60 days. Notably, no statistically significant differences in this change, mainly because the internal reaction of the sample ended after 28 days [34]. In addition, PBSS-AP modified sample had a stronger hydration reaction capacity, which made it to have a higher water absorption rate than that of the PBSS sample.
Water absorption rate of different samples after 7 days curing
Water absorption rate of different samples after 28 days curing
The UCS values of all samples were significantly lower after 7 days of immersion curing, following which the trend showed an increase (Fig. 6). The CAL, PBSS, and PBSS-AP samples immersed for 3 days had UCS values of 1.2, 1.7, and 2.5 MPa, respectively. This is because the strength of the sample in the standard environment was mainly provided by the soil itself and the product of the hydration reaction of the solidified material. Specifically, water molecules gradually entered the sample after immersion in water, thereby destroying the soil structure, and reducing strength. However, hydration of the solidified material increased with increase in soaking time, which gradually enhanced sample strength. In addition, both PBSS and PBSS-AP samples had stronger water resistance effects than lime-cement samples, mainly due to decomposition of lime in the lime-cement samples after water absorption [33]. The water molecules entered the inside, and damaged the structural stability of the samples.
Trends in UCS values of the samples after immersion (samples cured for 7 days)
Profiles of UCS values of samples cured for 28 days and the corresponding trends after immersion in water are shown in Fig. 7. Summarily, samples cured for 28 days had higher water resistance than those cured for 7 days. In addition, CAL, PBSS, and PBSS-AP samples had UCS values of 1.3, 2.2, and 2.4 MPa, respectively, after 3 days of immersion in water. Notably, a slight increase in UCS was observed with increase in immersion time, mainly because the hydration reaction of the solidification material was completed after 28 days [34], which stabilized the UCS value.
Trends in UCS values of the samples after immersion (samples cured for 28 days)
Volume Stability
Results showed that the PBSS sample had poor volume stability, while its expansion rate rapidly increased from 0.01% to 0.09% after 10 h and 240 h of water immersion, respectively (Fig. 8). In addition, CAL (0.08%) and PBSS-AP (0.06%) samples exhibited a relatively slow increase in expansion rate after immersion in water for 240 h. However, the PBSS-AP sample had a significantly higher volume stability, mainly due to the accelerated hydration reaction rate of the solidified material inside the sample, which resulted in high early strength, stable structure, and reduced expansion of the sample. Continuous hydration reaction of the solidified material inside the sample, improved stability of the structure of the sample, and the volume of the three samples was stable after immersion for 500 h.
Relationship between sample volume expansion rate and time
Further analysis revealed presence of micro cracks on the surface of CAL samples, and these were significant after immersion in water for some time. Notably, PBSS-AP samples exposed to the same conditions had a better appearance (Fig. 9), indicating that use of PG as a solidifying material for the soil improved stability and expansion ratio. Notably, the PBSS-AP sample had a significantly lower expansion rate than PBSS, although this was still to that of the CAL sample. Overall, these results indicated that AP is a suitable solidification material for subgrade soil.
Appearance of samples under different curing conditions. (a) CAL cured for 28 days in a standard room; (b) CAL cured for 28 days in water; (c) PBSS-AP cured for 28 days in a standard room; (d) PBSS-AP cured for 28 days in water
Leachate Test
Results of the leachate test for PBSS-AP samples are presented in Table 5. Summarily, although PBSS-AP samples had several possible harmful elements, they were significantly lower than limits specified in the Chinese Standard GB 5085.3-2007. This indicates that use of PBSS-AP as a roadbed construction material does not pause a threat to the environment.
Leachate test results of PBSS-AP samples
Element
Ba
Cr
Cu
Ni
Pb
Zn
Concentration (mg/L)
0.094
0.023
Nd
Nd
Nd
0.004
Limit (mg/L)
100
5
100
5
5
100
Note: Nd-not detected.
Microscopic Analysis
Used microscopy to explore differences between PBSS and PBSS-AP samples, targeting hardened bodies made from these two materials. Results are presented in Fig. 10.
SEM images of PBSS and PBSS-AP hardened body: (a) PBSS cured for 3 days; (b) PBSS-AP cured for 3 days; (c) PBSS cured for 28 days; (d) PBSS-AP cured for 28 days
Results showed that no hydration reaction of PBSS and PBSS-AP was completed in the early stage, although more ettringite was formed at this stage (Fig. 10). However, it was found that significantly lower ettringite content and significantly higher hydrated product C-S-H content after 28 days. In addition, PBSS-AP had less ettringite content, denser hardened body, and higher strength than PBSS (Figs. 10c and 10d), indicating that it performed better in soil solidification [5].
Field Application
To explore the practical application effect of the soil subgrade stabilizer material developed using industrial by-product PG, selected a provincial road under construction in the northern part of Jiangsu Province, China, for field testing. The study area has a warm temperate monsoon climate zone, while the basic landform type of the test section was that of the Xuhuai yellow floodplain area. The river is gentle, with no scouring, while its surface layer is mainly composed of silty soil. The area has soft soil, falls into category IV, while its surface water is slightly corrosive to reinforced concrete structures.
Specifically, PBSS-AP was used as the solidified material for field testing, with a dosage set to 12%. The test section was the K2+500-K2+720 left non-motor vehicle road base of the provincial road reconstruction project. The test section parameters were designed as: 30 cm, 12% PBSS-AP treatment soil (compact degree ≥88%) + 30 cm, 12% PBSS-AP treatment (compaction degree ≥ 93%) + 20 cm, and 12% PBSS-AP treatment (compaction degree ≥ 96%). In addition, selected top and bottom width of the non-motorized roadbed to be 6.71 and 7.91 m, respectively, then divided the section into three layers (including a base layer), with a slope of 1:1.5. Profile of the design layer is presented in Fig. 11, while the main construction process is illustrated in Fig. 12.
Sectional view of the subgrade design layer
Field test specific construction process: (a) Mechanical paving; (b) Mechanical stirring; (c) Roller compaction and leveling; (d) Curing
The test section was first cured for two days, according to the project schedule, then local quality inspection department personnel invited to analyze performance of the roadbed, including compaction and deflection. Final test results revealed that the lower, upper and base layer beds had 95%, 95% and 97% compaction rates, respectively (Table 6). Moreover, the surface had a deflection of 144.9 mm (Table 7), while its UCS value reached 2.5 MPa after 28 days (Table 8).
Results from on-site inspection showed that all the data met the requirements, and reliability of PBSS-AP in road engineering (subbase + roadbed) was preliminarily verified. To further explore the quality of the roadbed, leachate and roadbed deformation will be continuously tracked and monitored during the winter and summer of each year.
Test results of compaction degree
Detection site
Test items
Test results
Request/standard value
Remarks
Road bed
Upper road bed
Compaction degree
95%
≧93%
Fulfil requirements
Down road bed
95%
≧88%
Fulfil requirements
Road surface
Subbase
97%
≧96%
Fulfil requirements
Test result of deflection value
Serial number
Detection section
Total number of test points
Deflection average (0.01 mm)
Standard deviation (0.01 mm)
Deflection representative value (0.01 mm)
Technical indicators(0.01 mm)
Result determination
1
K1+540—K1+720 Left non-motor vehicle lane
20
99.8
22.57
144.9
≦212.0
qualified
Test result of UCS
Curing time (d)
7
14
28
UCS (MPa)
1.5
2.0
2.5
Conclusion
In summary, soil samples with 10% PBSS had higher UCS values than those with CAL over a similar period. However, a 15% increase in PBSS caused a slight increase in UCS value after 28 days. The PBSS-AP sample showed a better stabilization effect, whereas the UCS values after 7, 14, and 28 days were 3.8, 4.0, and 4.3 MPa, respectively, which were significantly higher than those of PBSS and CAL samples.
The PBSS-AP sample had the most stable internal structure and the strongest water corrosion resistance, as evidenced by a higher UCS value relative to those obtained in PBSS and CAL samples at the same immersion period. Notably, the PBSS-AP sample had a UCS value of 3 MPa after 28 days of curing, and 60 days of immersion in water.
Results from Leachate test revealed that the PBSS-AP sample had a significantly lower concentration of harmful elements relative to the limit specified in the Chinese standard GB 5085.3-2007. In addition, field testing results, combined with the Chinese standard JTG D30-2015 and Chinese standard JTJ034-2000 requirements, showed that the main indicators (such as UCS, deflection, and compaction) of the roadbed solidified by PBSS-AP met the requirements for second-class roads in the People’s Republic of China, whereas some of the indicators met the requirements for first-class roads. Taken together, these findings indicated that PG is suitable for largescale application in road construction.
Data Availability: Data used to support the findings of this study are available from the corresponding author upon request.
Funding Statement: This work was supported by funds from the Jiangsu Provincial Science and Technology Department’s Social Development-Major Science and Technology Demonstration Project (Grant No. BE2018697), the Jiangsu Provincial Science and Technology Department Social Development Project (Grant No. BE2017704) and the Scientific Research Project of the Suqian Municipal Transportation Bureau.
Conflicts of Interest: The authors declare that they have no conflicts of interest to report regarding the present study.
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