TY - EJOU AU - Sauget, A. AU - Zhou, X. AU - Pizzi, A. TI - MALDI-ToF Analysis of Tannin-Resorcinol Resins by Alternative Aldehydes: Glyoxal and Glutaraldehyde T2 - Journal of Renewable Materials PY - 2014 VL - 2 IS - 3 SN - 2164-6341 AB - Glyoxal and glutaraldehyde are two viable alternatives to formaldehyde for the preparation of tanninresorcinol-aldehyde adhesive but lead to less resistant glue joint. Tannin-resorcinol-glyoxal (TRG1) and tannin-resorcinol-glutaraldehyde (TRG2) resins have been prepared and analyzed by matrix-assisted laser desorption/ionization time of fl ight (MALDI-ToF) spectrometry to understand the chemical process behind the pre-curing of these resins and possibly the causes of this lower resistance. The analysis showed that TRG resins are not a simple mix of resorcinol-aldehydes oligomers and fl avonoids, but a much more complex combination of various species including tannin-aldehydes and tannin-resorcinol oligomers. KW - Tannin resin KW - natural resin KW - MALDI-ToF DO - 10.7569/JRM.2013.634138