TY - EJOU
AU - Zhang, Xiaoqing
AU - Schmidt, Simon
AU - Rigopoulos, Nick
AU - Gotama, Januar
AU - Petinakis, Eustathios
TI - Using CO2 -Based Polymer Polypropylene Carbonate to Enhance the Interactions in Poly(lactic acid)/Wood Fiber Biocomposites
T2 - Journal of Renewable Materials
PY - 2015
VL - 3
IS - 2
SN - 2164-6341
AB - The behavior of a biodegradable CO2
-based polymer polypropylene carbonate (PPC) as polymer matrix of
wood fi ber (WF) composites was examined and compared with that of using poly(lactic acid) (PLA) as the
matrix. The PPC/WF composites displayed poor mechanical properties as compared to PLA/WF composites
because PPC is an amorphous polymer with low Tg
and poor thermal stability. However, when PPC was
used in conjunction with PLA in WF composites, the mechanical strength and modulus of the composites
could match or even exceed the level of PLA/WF composites. The strong intermolecular interactions between
PPC and WF and those between PPC and PLA enhanced the bonding between compatible PPC/PLA matrix
and WF fi llers, resulting in improved fl exural strength and modulus over a broader temperature range that
reduced the impact of the low Tg
effect of PPC. The crystalline structures of PLA were also modifi ed in the
PPC-PLA/WF composites, while the thermal stability of the composites was improved.
KW - Polypropylene carbonate
KW - poly(lactic acid)
KW - wood fi ber
KW - biocomposites
DO - 10.7569/JRM.2014.634135