TY - EJOU AU - Bednarz, Szczepan AU - Wesołowska, Angelika AU - Trątnowiecka, Magdalena AU - Bogdał, Dariusz TI - Polymers from Biobased-Monomers: Macroporous Itaconic Xerogels Prepared in Deep Eutectic Solvents T2 - Journal of Renewable Materials PY - 2016 VL - 4 IS - 1 SN - 2164-6341 AB - New methods of preparation of crosslinked polymers from itaconic acid as a renewable monomer have been explored. Synthesis of hydrogels and xerogels from the acid in deep eutectic solvents (DESs) are described and some basic properties of the materials are reported. Most importantly, a surfactant-free method of creation of macroporous poly(itaconic-co-bisacrylamide) by phase separation polymerization in binary mixture of the DES and poly(ethylene glycol) is demonstrated. KW - Choline chloride KW - free-radical polymerization-crosslinking KW - hydrogels KW - phase segregation KW - renewable monomers DO - 10.7569/JRM.2015.634131