TY - EJOU AU - Walterova, Edgars Vanags*, Mikelis Kirpluks, Ugis Cabulis and Zuzana TI - Highly Functional Polyol Synthesis from Epoxidized Tall Oil Fatty Acids T2 - Journal of Renewable Materials PY - 2018 VL - 6 IS - 7 SN - 2164-6341 AB - In this work, free tall oil fatty acids were epoxidized with in-situ generated peroxyacetic acid. Reaction kinetics of epoxidation was investigated by oxirane content and iodine value titrimetric determination, as well as FTIR spectra analysis. A highly functional biobased polyol was synthesized by functionalizing epoxidized tall oil fatty acids with triethanolamine using Montmorillonite K10 as a catalyst. The obtained polyol was analyzed by FTIR and MALDI-TOF MS. The most common chemical and physical characteristics of obtained polyol were determined. KW - Epoxidation KW - biobased polyol KW - ion-exchange resin catalyst KW - montmorillonite K10 KW - tall oil fatty acids DO - 10.7569/JRM.2018.634111