@Article{jrm.2021.015400,
AUTHOR = {Xiaohua Gu, Shiwei Lyu, Siwen Liu},
TITLE = {Alcoholysis of Waste Polyurethane Rigid Foam and Its Modification with Lignin for Recovery},
JOURNAL = {Journal of Renewable Materials},
VOLUME = {9},
YEAR = {2021},
NUMBER = {11},
PAGES = {1913--1926},
URL = {http://www.techscience.com/jrm/v9n11/42812},
ISSN = {2164-6341},
ABSTRACT = {A bi-component alcoholysis agent containing propylene glycol (PG) and ethanolamine (ETA) was used to catalyst
the degradation of the waste polyurethane rigid foam. The oligomer polyols obtained through degradation were
used as raw materials to produce recycled polyurethane rigid foam composites with lignin as reinforcing filler.
The effect of alcoholysis mass ratio on degradation was investigated by analyzing the viscosity, hydroxyl content
and chemical structure of the degradation products. The effect of lignin addition on the properties of regenerated
polyurethane rigid foam were investigated by analyzing water absorption rate, compressive strength, porosity,
thermal stability, thermal conductivity coefficient, morphology and thermal stability of the recycled polyurethane
rigid foam. Results show that different mass ration of PG to ETA significantly affects the degradation of waste
polyurethane rigid foam. Besides, only with the addition of appropriate amount of lignin, the regenerated polyurethane rigid foam composites can meet the Chinese national standard “rigid polyurethane foam for building
thermal insulation” (GB/T21558-2008). At this point, the composite is with good mechanical and thermal prperties, including high compressive strength, excellent thermal insulation performance, complete cell morphology
and good thermal stability.},
DOI = {10.32604/jrm.2021.015400}
}