Estefanía Lidón Sánchez-Safont¹, Jennifer González-Ausejo¹, José Gámez-Pérez¹, José María Lagarón², Luis Cabedo^1*

Journal of Renewable Materials, Vol.4, No.2, pp. 123-132, 2016, DOI:10.7569/JRM.2015.634127

Abstract Novel biodegradable composites based on poly(3-hydroxybutirate-co-3-hydroxyvalerate) (PHBV) and different contents of purifi ed alpha-cellulose fi bers (3, 10, 25 and 45%) were prepared by melt blending and characterized. The composites were characterized by scanning electron microscopy (SEM), wide-angle X-ray scattering (WAXS) experiments, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic mechanic analysis (DMA) and Shore D hardness measurements. Disintegrability under composting conditions was studied according to the ISO 20200 standard. Morphological results showed that high dispersion of the fi bers was achieved during mixing. Good adhesion on the fi ber-matrix interface was also detected by More >

Itxaso Algar¹, Clara Garcia-Astrain¹, Alba Gonzalez², Loli Martin³, Nagore Gabilondo¹, Aloña Retegi^1*, Arantxa Eceiza^1*

Journal of Renewable Materials, Vol.4, No.1, pp. 57-65, 2016, DOI:10.7569/JRM.2015.634124

Abstract Bacterial cellulose/montmorillonite (BCMMT) hybrid bionanocomposite membranes were prepared by in-situ assembling or one-step biosynthesis process. The presence of MMT in BC membranes was confi rmed by thermogravimetric analysis and quantifi ed by mass spectrometry, resulting in bionanocomposites with MMT contents between 7–13 wt%. The incorporation of MMT during BC biosynthesis modifi ed BC morphology and led to lower porosity, even though higher water holding capacity was achieved. Bionanocomposites showed improved thermal stability and water vapor and oxygen gas barrier properties up to 70 and 80% with respect to neat BC membranes. This improvement was related More >

José M. R. C. A. Santos^*, Ana R. Sampaio, Joana Branquinho

Journal of Renewable Materials, Vol.4, No.1, pp. 31-40, 2016, DOI:10.7569/JRM.2015.634123

Abstract Cellulose-based materials are one of the most widely used materials provided by nature to mankind. In particular, cotton fi bers have been used for millennia to produce clothing items. This wide usage stems from the inherent properties of cotton fabrics such as hydrophilicity and permeability to water vapor. However, increasingly sophisticated uses for cotton-based clothing (e.g., technical textiles) demand specifi c properties such as hydrophobicity and oleophobicity for repellent functions. The current surface treatments used to attain these functionalities are based on thermally initiated polymerization reactions, using water-based formulations. Thus, the current technologies are energy-… More >

Monique de Alvarenga Pinto Cotrim^1*, Jessyca Aparecida Paes Dutra², Suzana Gonçalves Carvalho², Janaina Cecília Oliveira Villanova², Eliane Ayres¹

Journal of Renewable Materials, Vol.4, No.1, pp. 9-17, 2016, DOI:10.7569/JRM.2015.634122

Abstract In recent years there has been an increasing demand for the application of natural products to address problems in the environment. The use of products derived from renewable resources can provide a sustainable strategy to replace totally or partially synthetic products. Cymbopogon, commonly known as lemongrass, is a tropical grass cultivated mostly for its essential oil, which has demonstrated several bioactivities, including antibacterial and antifungal properties. In the present work the formation of inclusion complex between β-cyclodextrin (β-CD) and lemongrass essential oil (LGEO) as well as its fi xation onto cotton fabric were investigated. Inclusion More >

Yadong Liu¹, Guangcheng Huang^1,2, Yuanyuan Pang^1,2, Miaomiao Han¹, Shengxiang Ji^1,*

Journal of Renewable Materials, Vol.3, No.2, pp. 113-119, 2015, DOI:10.7569/JRM.2014.634141

Abstract In this work, we report a one-pot synthesis of amphiphilic miktoarm cellulose graft copolymers, cellulose (-graft-oligo(L-lactide))-graft-oligo(N-isopropylacrylamide) (Cell(-g-OLLA)-g-ONIPAM), with dual side chains of oligo(L-lactide) and oligo(N-isopropylacrylamide) using 2-bromoisobutyl bromide functionalized cellulose (Cell(-OH)-Br) as the macroinitiator, by simultaneously conducting ring-opening polymerization and atom transfer radical polymerization using Cu/CuBr/PMDETA/Sn(Oct)₂ as the catalytic system. The chemical structures and thermal properties of Cell(-g-OLLA)-g-ONIPAMs were characterized with ¹ H and ¹³C nuclear magnetic resonance spectroscopy, differential scanning calorimetry and thermal gravimetric analysis. Cell (-g-OLLA)-g-ONIPAM could self-assemble into micelles in the aqueous solution as confi rmed by environmental scanning electron microscopy and dynamic light More >

Vu Thanh Phuong^1,2, Steven Verstichel³, Patrizia Cinelli^1,4, Irene Anguillesi¹, Maria-Beatrice Coltelli¹, Andrea Lazzeri^1,*

Journal of Renewable Materials, Vol.2, No.1, pp. 35-41, 2014, DOI:10.7569/JRM.2013.634136

Abstract Cellulose acetate (CDA) cannot be processed as raw material because it starts to decompose before melting. Triacetin and diacetin were tested to improve CDA processing versus conventional phthalate as environmentally sustainable plasticizers, because of their low toxicity and fast biodegradability. The addition of triacetin and diacetin allowed melt processing of CDA and the results of tensile tests outlined their effect as plasticizers. The values of mechanical properties were compatible with the requirements for applications in rigid packaging. From the results of biodegradation tests it can be concluded that for pure cellulose acetate, complete biodegradation was More >

Antonio J. F. Carvalho

Journal of Renewable Materials, Vol.2, No.2, pp. 118-122, 2014, DOI:10.7569/JRM.2014.634108

Abstract Two nanocelluloses from eucalyptus, namely microfi brillated cellulose (MFC) and cellulose nanocrystals (CNC), were prepared and compared by transmission electron microscopy (TEM). The MFC fi bers are 20–30 nm wide and are composed of very homogeneous bundles of aligned regular elementary fi brils of 3–5 nm diameter. They show long straight portions and short fl exible zones, attributed to crystalline and amorphous zones, respectively. The needle-shaped CNC was approximately 200 nm long and 10 nm wide in the wider portion. A model for the MFC structure, whose fl exible zones are formed by alignment of More >

Marta Martínez-Sanz, Amparo López-Rubio, Maria José Fabra, José M. Lagaron^*

Journal of Renewable Materials, Vol.2, No.2, pp. 107-117, 2014, DOI:10.7569/JRM.2014.634106

Abstract Due to their high crystallinity and aspect ratio, bacterial cellulose nanowhiskers (BCNW) represent an appealing choice for the development of fully biobased nanocomposite materials with high barrier performance. However, their strong tendency to self-associate, together with their highly hydrophilic character, has restricted the production of nanocomposites containing cellulose nanowhiskers by industrial processing techniques such as melt compounding. Th is article presents an overview of the latest published results carried out within our group and also in other relevant literature, which have led to the development of an effi cient strategy for the incorporation of highly… More >

M.C. Lagel¹, A. Pizzi^1,2, S. Giovando³, A. Celzard⁴

Journal of Renewable Materials, Vol.2, No.3, pp. 220-229, 2014, DOI:10.7569/JRM.2014.634113

Abstract With the depletion of fossil resources, tannin extracts can be a natural alternative to some synthetic products. Hydrolysable chestnut tannin extracts have been used to partially replace phenol in PF resins for phenolic rigid foams. Phenol-formaldehyde-chestnut tannin (PFT) phenolic foams were initially made from copolymerized PFT resins of different molar ratio. The PFT foams so prepared were tested for thermal conductivity, these being slightly worse than that of pure PF foams; and for mechanical and water absorption, these two properties being better than those of pure PF foams. Indeed, PF resins represent an important part More >

Aparecido Junior de Menezes^1,3,*, Elson Longo², Fábio Lima Leite¹, Alain Dufresne³

Journal of Renewable Materials, Vol.2, No.4, pp. 306-313, 2014, DOI:10.7569/JRM.2014.634121

Abstract In the work presented in this article surface chemical modifi cation was applied to ramie cellulose nanocrystals by grafting organic acid chlorides presenting different lengths of the aliphatic chain. The objective of this surface chemical treatment was to enhance the nonpolar nature of the grafted nanocrystals and improve their dispersibility in a nonpolar polymeric matrix. The occurrence of the chemical modifi cation was evaluated by Fourier transform infrared (FTIR) spectroscopy, the degree of crystallinity by X-ray diffraction, and the morphology by scanning electron microscopy with fi eld emission gun (FEG-SEM) and atomic force microscopy (AFM). More >