N. K. Cinsy^*, R. R. Jeya Geetha

Chalcogenide Letters, Vol.20, No.2, pp. 121-129, 2023, DOI:10.15251/CL.2023.202.121

Abstract The characterizations of synthesized CdZnS nanoparticles with Clitoria ternatea (Asian pigeon wings) leaf extract were done by the chemical precipitation method. The formation of CdZnS nanoparticles with the extract was confirmed by making use of XRD, SEM analysis and EDAX. XRD disclosed the structure and also the particle size. SEM investigation of CdZnS NPs confirmed shape and size. The optical studies were executed for the prepared sample. From the obtained UV-visible spectrum, band gap energy was determined using the Tauc plot. The photocatalytic activity of the processed sample was also analysed. More >

A. Gahtar^a,*, C. Zaouche^b, A. Ammari^c,d, L. Dahbi^e

Chalcogenide Letters, Vol.20, No.5, pp. 377-385, 2023, DOI:10.15251/CL.2023.205.377

Abstract In this work, the bimetallic (Ni,Co) sulfide film of 852.213 nm thickness was successfully deposited using the spray pyrolysis technique at 300 °C. The compound was prepared with a mixture of nickel acetate (C₄H₆O₄Ni. 4H₂O), cobalt chloride (CoCl₂. 6H₂O), and thiourea (CS(NH₂)₂) as precursors for Ni, Co, and S, respectively. The temperature and sedimentation time were 300 °C and 10 min, respectively; the film was then, characterized without any thermal post-treatment. The structural, morphological, optical and electrical analysis were carried out to investigate the different properties of the material. The X-ray diffraction analysis confirmed the presence of NiCo₂S₄… More >

K. A. Mohammed^a,*, N. H. J. Al Hasan^b, L. R. Al-Ameer^c, D. S. Abdul-Zahra^d, Y. D. Dwivedi^e, K. H. Salem^f, M. K. Agarwal^g, R. S. Zabibah^h, M. A. Alkhafajiⁱ

Chalcogenide Letters, Vol.20, No.8, pp. 599-608, 2023, DOI:10.15251/CL.2023.208.599

Abstract This study examined the properties of polyvinyl alcohol (PVA) as a matrix composite, specifically focusing on the characterization techniques of UV-Visible spectroscopy, X-ray diffraction (XRD), and scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDX). The investigation centered around a novel hybrid structure composed of CdZnS nanoparticles implanted within a composite matrix of PVA and Fe₂O₃. The analysis of microstructure data provided evidence of the influence of CdZnS nanoparticles on the structural characteristics of PVA–Fe₂O₃. The composites that were synthesized exhibited significant absorption peaks at wavelengths of 233 nm and 234 nm for PVA-Fe₂O₃ and PVA-Fe₂O₃-CdZnS, respectively. More >

M. N. Abdel-Salam^a, N. Sabry^b, E. S. Yousef^c,d, E. R. Shaaban^a,*

Chalcogenide Letters, Vol.20, No.11, pp. 759-777, 2023, DOI:10.15251/CL.2023.2011.759

Abstract This study focused to prepare poly-crystalline (ZnSe)_1-xCu_x thin films, where x values vary from 0 to 0.1 %. the effect of Cu ratios dopant on structural, phases and optical properties has been investigated. As prepared thin films were deposited onto a cleaning glass substrate under high vacuum conditions (10^-7 mbr) at room temperature using the “ evaporation technique”. The analysis results according to data of the X-ray diffraction technique of all films refer to the growth polycrystalline with hexagonal wurtzite structure of Zn-Se with no presence of any further phases. The changes in numerous parameters such… More >

A. Thamer^a, S. Mohamed^b,*

Chalcogenide Letters, Vol.20, No.12, pp. 847-856, 2023, DOI:10.15251/CL.2023.2012.847

Abstract Using Sol-gel technology, nanocomposite CdS: ZnO thin films with an equal molar ratio of 0.5 M on a glass substrate for water decontamination purposes. The ZnO doping ratios were (0, 1, 3, 5) vol. The ultrastructural, morphological, and optical properties of the prepared thin films were studied using X-ray diffraction (XRD), atomic force microscopy (AFM), and UV-vis spectra. The results indicated that the prepared nanostructured CdS: ZnO thin films contain uniformly spaced crystalline grains of both CdS and ZnO. The ZnO-doped selection ratio and uniform grain distribution produced outstanding photocatalytic and photocatalytic performance. With a More >

PARSOTAM H. PARSANIA^1,*, JIGNESH V. PATEL², JIGNESH P. PATEL³

Journal of Polymer Materials, Vol.40, No.3-4, pp. 271-284, 2023, DOI:10.32381/JPM.2023.40.3-4.9

Abstract Bisphenol-C epoxy crotonate resin was synthesized by reacting 8.09g epoxy resin of bisphenolC, and 2.15g crotonic acid using 25 mL 1,4-dioxane as a solvent, and 1 mL triethylamine as a catalyst at reflux temperature for 1-6 h. Solid epoxy crotonate (ECCR) is highly soluble in common organic solvents. ECCR was characterized by its acid (24.5-1.5 mg KOH/g) and hydroxyl (504.5-678.4 mg KOH/g) values. The structure of ECCR is supported by FTIR and 1 HNMR spectroscopic methods. A DSC endothermic transition at 229o C indicated melting followed by thermal polymerization of ECCR. ECCR is thermally stable… More >

NEETU TRIPATHI, DIBYENDU S. BAG^*, MAYANK DWIVEDI

Journal of Polymer Materials, Vol.40, No.3-4, pp. 227-269, 2023, DOI:10.32381/JPM.2023.40.3-4.8

Abstract Over the last three decades, there has been considerable interest in the captivating mechanical properties displayed by auxetic materials, highlighting the advantages stemming from their distinct negative Poisson's ratio. The negative Poisson's ratio observed in auxetic polymeric materials is a result of the distinctive geometries of their unit cells. These unit cells, encompassing structures such as chiral, re-entrant, and rotating rigid configurations, are carefully engineered to collectively generate the desired auxetic behaviour. This comprehensive review article explores the field of auxetic polymeric materials, offering a detailed exploration of their geometries, fabrication methods, mechanical properties, and More >

K. KRISHNAMOORTHY^a,*, N. PRABHU^b

Journal of Polymer Materials, Vol.40, No.3-4, pp. 215-226, 2023, DOI:10.32381/JPM.2023.40.3-4.7

Abstract The acoustic emission monitoring with artificial neural networks predicts the ultimate strength of glass/epoxy composite laminates using Acoustic Emission Data. The ultimate loads of all the specimens were used to characterise the emission of hits during failure modes. The six layered glass fiber laminates were prepared (in woven mat form) with epoxy as the binding medium by hand lay-up technique. At room temperature, with a pressure of 30 kg/cm², the laminates were cured. The laminates of standard dimensions as per ASTM D3039 for the tensile test were cut from the lamina. The Acoustic Emission (AE) test More >

CONGHUI XU, ZHEQING GONG, XIAOLONG CHEN, LIJUN CHEN^*

Journal of Polymer Materials, Vol.40, No.1-2, pp. 47-58, 2023, DOI:10.32381/JPM.2023.40.1-2.4

Abstract The self-crosslinking polyacrylate latex was prepared via the semi-continuous seed emulsion polymerization technology that methyl methacrylate(MMA) and butyl acrylate (BA)were used as the main monomers and hexafluorobutyl methacrylate (HFMA) and monobutylitaconate (MBI) were used as the modified monomers and glycidyl methacrylate (GMA) was used as the crosslinked monomer which were emulsified with the environmentally friendly mixed surfactant of the isomeric triethylene (9) ether (E-1309) and the lauryl polyoxyethylene ether sulfosuccinate disodium salt (MES-30). The resultant latex and its film is characterized by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimeter (DSC), laser particle sizer, contact More >

Arnoldo E. Alfaro-Corres¹, Daniel González-Mendoza², Esaú Ruiz-Sánchez^1,*, Carlos Ail-Catzin², Benjamín Valdez-Salas³, Federico Gutiérrez-Miceli⁴, Arturo Reyes-Ramírez¹, Jacques Fils Pierre¹

Journal of Renewable Materials, Vol.11, No.11, pp. 3933-3943, 2023, DOI:10.32604/jrm.2023.031129 - 31 October 2023

Abstract This work was carried out to evaluate the insecticidal effect of mono, bi and trimetallic nanoparticles (NPs) from leaf extract of habanero pepper (Capsicum chinense Jacq.) on the red flour beetle (Tribolium castaneum herbst.) and cotton mealybug (Phenacoccus solenopsis Tinsley). The results showed that Cu NPs, Cu/Mn NPs and Zn/Cu NPs had high insecticidal effect against T. castaneum (63%–80% mortality after 96 h). The Cu NPs and Zn/Cu NPs showed also insecticidal effect against P. solenopsis, but to a lesser extent (20%–28% after 96 h). With regards to the physicochemical characterization, Cu NPs had a zeta potential of 21.1 More > Graphic Abstract