A. A. Mansour^a, H. A. Salman^b, S. A. Abdul Wahab^c, N. F. Habubi^c, S. S. Chiad^d,*, Z. S. A. Mosa^c, Y. H. Kadhim^d

Chalcogenide Letters, Vol.21, No.3, pp. 275-284, 2024, DOI:10.15251/CL.2024.213.275

Abstract To grow SnS films, the spray pyrolysis deposition (SPD) process is applied. The films were deposited at various substrate temperatures (S_T) of 400, 450, and 500 degrees Celsius for two hours. Through XRD analysis, the impact of ST on the structure was investigated. Peak (113) crystallite sizes were 13.16, 21.48, and 38.87 nm, respectively, at base temperatures of (400, 450, and 500) ℃. The effect of ST on the structure was examined using XRD analysis. A predominat Peak at (113) plane. The crystallite sizes at base temperatures of (400, 450, and 500) ℃ were 13.16, 21.48, More >

J. M. Shi^*, H. F. Zhang, H. C. Wang

Chalcogenide Letters, Vol.21, No.3, pp. 263-274, 2024, DOI:10.15251/CL.2024.213.263

Abstract This study presents the synthesis and characterization of 3D ZnO@MoS₂ nanocomposites, demonstrating their superior performance in photoelectrochemical applications. Employing a combination of hydrothermal and solvothermal methods, the research focuses on creating heterostructures with optimized interfacial characteristics. The ZnO@MoS₂ composites show a substantial increase in photocurrent density (1.02 mA/cm^²), compared to ZnO nanorods (0.32 mA/cm^²), underlining enhanced charge separation efficiency. In electrocatalytic hydrogen evolution, the heterostructures exhibit a lower onset potential (-175 mV vs RHE) and reduced Tafel slope (51 mV/dec), indicating improved catalytic activity over MoS₂ nanosheets. Additionally, the composites demonstrate a significant increase in electrochemical capacitance (398 More >

M. Boonkam, P. Tamdee, P. Tongying^*

Chalcogenide Letters, Vol.21, No.4, pp. 335-342, 2024, DOI:10.15251/CL.2024.214.335

Abstract This work presents a facile hydrothermal synthesis method for fabricating a multifunctional composite of copper zinc tin sulfide (CZTS) nanoparticles coated onto sepiolite fibers. Morphological analysis confirms the firm attachment of approximately 10 nm CZTS nanoparticles onto the sepiolite surface. Elemental analysis verifies the presence of constituent elements from both CZTS and sepiolite, with a slight deficiency in Cu and an abundance of Zn observed. The compositional formula of CZTS in the composite is estimated as Cu_1.93Zn_1.05Sn_0.98S_4.04. Notably, the material exhibits a narrow band gap of 1.5 eV, enabling effective utilization of the entire visible light More >

L. R. Gahramanli^a,b,*, S. Bellucci^a, M. B. Muradov^b, M. La Pietra^a, G. M. Eyvazova^b, C. V. Gomez^a, J. Bachmann^c

Chalcogenide Letters, Vol.21, No.7, pp. 513-527, 2024, DOI:10.15251/CL.2024.217.513

Abstract A new type of Ag₂S-CdS/Ag/GNP nanocomposite material was successfully synthesized in the presented work. The structural and physical properties of compounds were studied separately and together. Ag₂S-CdS/Ag/GNP nanocomposite materials were studied by Xray diffraction (XRD), Ultraviolet-Visible (UV-Vis), Fourier Transform Infrared (FTIR), Raman spectroscopy and Scanning Electron Microscopy (SEM). Based on the results, Ag nanowires (NWs) were successfully synthesized, and then it was determined that during the hybridization process, two phases of acanthite Ag₂S and the cubic crystal system of Ag₂O were formed. Then, Ag₂S-CdS NWs were formed from mixed monoclinic Ag₂S and hexagonal CdS. In the absorption spectrum… More >

D. N. Alhilfi^a,*, A. S. Al-Kabbib^b

Chalcogenide Letters, Vol.21, No.8, pp. 641-649, 2024, DOI:10.15251/CL.2024.218.641

Abstract The electrochemical deposition method created a CdSe thin film on FTO glass substrates. The film was examined using field scanning electron microscopy, energy dispersive spectroscopy, X-ray diffraction, Raman spectroscopy, and optical and electrochemical measurements. The results show that the CdSe nanoparticles were evenly distributed on the substrate, with a Cd/Se ratio of 63.30% Se and 36.70% Cd. The XRD revealed a polycrystalline, hexagonal structure. The film is n-type semiconductor concentration with a carrier concentration of 1.194×10²⁰ cm^-3 . The CdSe showed 552.5 mF/cm² of specific capacity with energy and a power density of 2.5 mW/cm² and 9000 mW/cm² More >

M. Sudha^a,*, A. B. Madhan^b, M. Revathi^c, N. Thangaraj^d

Chalcogenide Letters, Vol.21, No.9, pp. 757-764, 2024, DOI:10.15251/CL.2024.219.757

Abstract An inexpensive spray pyrolysis process has been used to create thin layer of tin disulphide. The concentration, flow rate, and nozzle to substrate distance were tuned as deposition parameters to produce high-quality thin films. Temperature is varied in the range 200˚C to 350˚C. Through physical research, properties such as the structural, electrical and optical were examined. The films generated are SnS2 with a hexagonal structure, as revealed by X-ray diffraction. EDAX analysis confirms SnS2 thin films. Scanning electron microscopy indicated uniform stacking and material adherence to the glass substrate. A 2.22 eV straight band gap More >

R. A. Ulwali^*, N. K. Abbas

Chalcogenide Letters, Vol.21, No.12, pp. 1011-1020, 2024, DOI:10.15251/CL.2024.2112.1011

Abstract Pure zinc sulfide nanoparticles and doped with silver (0.5,1,1.5,2.5, and 3.5) % wt. were prepared by green method. The structural properties were studied using X-ray diffraction technology(XRD). The diffraction patterns showed the particles were crystalline and had a zinc-blend structure with different average grain size. The surface topography was investigated by Scanning Electron Microscope (FE-SEM), it was found the shape is spherical and had different nanosized. Chemical purity was studied using Energy Dispersive X-ray Spectroscopy(EDX), the results showed the appearance of basic elements (Zn, S) and silver. The results of Fourier Transform Infrared Spectroscopy(FTIR) showed More >

Md. Riyadh Arefin^1,2, Md. Sabibul Haque¹, A. K. M. Golam Sarwar^1,*

Phyton-International Journal of Experimental Botany, Vol.93, No.12, pp. 3411-3442, 2024, DOI:10.32604/phyton.2024.058893 - 31 December 2024

Abstract Tea estates in Bangladesh are currently experiencing frequent waterlogging stress due to heavy rainfall or flooding under changing climate scenarios. The development of waterlogging-tolerant tea cultivars is, therefore, crucial for sustainable tea production with increased yield in waterlogging-affected areas. In this study, a total of two hundred tea genotypes were screened for waterlogging tolerance based on yield and quality potentials. Tea genotypes were raised at the nursery and evaluated with 13 traits at the seedling and mature stages. Descriptive and multivariate analysis of the recorded data of measured traits were performed for clustering the… More >

Jiangyi Zhou, Bin Cao, Sivakumar Esakkimuthu, Mao Mu^*, Shuang Wang^*

Journal of Renewable Materials, Vol.12, No.12, pp. 2069-2078, 2024, DOI:10.32604/jrm.2024.054905 - 20 December 2024

Abstract Seaweed, as a third generation of biomass energy, has significant potential to replace non-renewable fossil fuels. Among various conversion technologies, hydrothermal liquefaction can effectively convert seaweed into bio-oil. However, most current research on hydrothermal liquefaction products focuses on the oil phase and solid phase, with little attention given to the utilization of the aqueous phase by-product. In this study, the large seaweed Enteromorpha prolifera was selected as the raw material. The aqueous phase containing organic components was prepared through hydrothermal liquefaction at different temperatures, which was then mixed with the polymer polyvinyl alcohol to produce high-value… More >

Aswinraj Anbazhagan¹, Piyali Roy Choudhury¹, Sahila Sambandam², Jayakumari Lakshmanan Saraswathi^1,*

Journal of Polymer Materials, Vol.41, No.4, pp. 299-313, 2024, DOI:10.32604/jpm.2024.056261 - 16 December 2024

Abstract Petroleum-based cured epoxy polymers, used widely in aerospace, marine, and automotive industries, pose environmental threats due to their toxicity. Therefore, developing alternative curing systems for epoxy resin is crucial. This study explores the use of bio-based phenalkamines as curing agents for epoxy resin to enhance the mechanical properties of polymer composites and fiber-reinforced laminates. The functional groups, morphology, and thermal properties of the composites were analyzed using Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). Mechanical properties of two epoxy systems—EP-TETA (triethylenetetramine-cured) and EP-PA (phenalkamine-cured)—were evaluated according to ASTM standards. More > Graphic Abstract