M. VASUMATHI^1,a,*, VELA MURALI^2,b, S. RASHIA BEGUM^1,c, N. RAJENDRAN^2,d

Journal of Polymer Materials, Vol.36, No.1, pp. 1-11, 2019, DOI:10.32381/JPM.2019.36.01.1

Abstract In the Fibre Metal Laminate (FML), Carbon Reinforced Aluminium laminate (CARALL), aluminium is placed next to carbon fibres. The potential difference between the aluminium and carbon is larger, leads to galvanic corrosion, which tries to bring down the durability of the FML. To bring down the effect of corrosion, a material layer is introduced between fibres and aluminium so as to separate them thus lowering the possibility of occurrence of corrosion. Another approach is to coat the surfaces of aluminium with different proportions of aluminium oxide nano particles prior to fabrication of the FML. For More >

Ingrid Souza Vieira da Silva¹, Natália Soares Prado¹, Patrícia Gontijo de Melo², Danilo Campion Arantes³, Mara Zeni Andrade⁴, Harumi Otaguro¹, Daniel Pasquini^1,*

Journal of Renewable Materials, Vol.7, No.1, pp. 73-87, 2019, DOI:10.32604/jrm.2019.00042

Abstract In this work, nine different types of edible coating based on pectin, cellulose nanocrystals, glycerol, and essential oil of lemongrass were prepared and used to coat strawberries with a film formed directly on the surface of the coated fruit. The effects of the different edible coatings on refrigerated fruits in terms of weight loss, titratable acidity, total soluble solids, pH, and anthocyanin content was evaluated after 2 days, 4 days, 6 days, and 8 days of storage. Application of the edible coatings reduced the weight loss of the coated strawberries and the anthocyanin content. The More >

Azam Sardari^1,2, Ali Asghar Sabbagh Alvani^1,2,3,*, Seyed Reza Ghaffarian^1,2

Journal of Renewable Materials, Vol.7, No.1, pp. 31-40, 2019, DOI:10.32604/jrm.2019.00045

Abstract In this study, three sorts of polyols were successfully synthesized from castor oil using a Dean-Stark quick, eco-friendly and high-efficiency method. For this purpose, castor oil was epoxidized in the presence of two types of catalysts including γ-alumina and formic acid, named as ECOAl and ECOF, respectively. Epoxidized castor oils were then characterized by use of hydrogen nuclear magnetic resonance (H-NMR) and oxirane oxygen content analysis. The relative percentages of conversion double bond to oxirane were obtained 96% and 74% for ECOAl and ECOF, respectively. Ring opening reaction of ECOAl was performed by two types More >

A. Abolins*, V. Yakushin and D. Vilsone

Journal of Renewable Materials, Vol.6, No.7, pp. 737-745, 2018, DOI:10.32604/JRM.2018.00119

Abstract Linseed oil was epoxidized using hydrogen peroxide (H2O2), acetic acid (AcOH) and ion exchange resin Amberlite IR-120 as a catalyst. Epoxidized oil was separately dissolved in isopropyl alcohol (IPA) or diethylene glycol butyl ether (DGBE) and phosphorylated with different amounts of phosphoric (H3PO4) acid (1%, 2%, 3% and 5%). The formation of phosphate polyesters was confirmed by Fourier-transform infrared (FTIR) and 31P nuclear magnetic resonance (NMR) spectra. Based on the synthesized polyols, polyurethane (PU) coatings were prepared. PU coating based on linseed oil diethylene glycol ester polyol was used as the reference. For the characterization More >

Kunal Wazarkar, Anagha Sabnis*

Journal of Renewable Materials, Vol.6, No.5, pp. 517-528, 2018, DOI:10.7569/JRM.2017.634181

Abstract This research work discloses the preparation of polyurethane coatings from cardanol modified using thiolene chemistry, wherein unsaturated long alkyl chain of cardanol was successfully utilized via thiol-ene click reaction to synthesize polyol. For this purpose, cardanol and thioglycerol was reacted in the presence of Irgacure 184 (photoinitiator) and 1,8-Diazabicyclo[5.4.0]undec-7-ene (catalyst) and exposed to UV light for 12 h at 80 °C. One mole of thioglycerol was successfully added across the double bond of fatty chain of cardanol and confirmed by chemical and spectroscopic analysis. Further, the polyol thus prepared was cured with various polyisocyanates, viz., More >

Kunal Wazarkar, Anagha Sabnis*

Journal of Renewable Materials, Vol.6, No.4, pp. 438-449, 2018, DOI:10.7569/JRM.2017.634159

Abstract The research work presented in this article deals with the synthesis of cardanol-based polyol and its curing with hexabutoxymethyl melamine (HBMM) for application in coatings. Cardanol-based polyol was prepared via thiol-ene click reaction using thioglycerol. Unsaturation present in the long chain of cardanol was successfully utilized to synthesize polyol via thiol-ene coupling. The reaction was carried out between cardanol and thioglycerol in the presence of Irgacure 184 (photoinitiator) and 1,8-Diazabicyclo[5.4.0]undec-7-ene (catalyst) under UV light for 12 h at 80 °C. After completion of the reaction, one mole of thioglycerol was successfully added across the double More >

Ragab E. Abou-Zeid^1*, Mohamed A. Diab¹, Salah A. A. Mohamed², Ahmed Salama¹, Hind Abdullah Aljohani³, Kamel Rizq Shoueir⁴

Journal of Renewable Materials, Vol.6, No.4, pp. 394-401, 2018, DOI:10.7569/JRM.2017.634156

Abstract The current article addresses a new strategy for the preparation of polylactic acid/cellulose nanocrystal (PLA/CNCs) nanobiocomposite films with improved structural morphology, mechanical and barrier properties for food packaging applications. The addition of hexadecyltrimethylammonium bromide (CTAB) and sodium lauryl sulfate (SLS) as cationic and anionic surfactants respectively, was found to play a crucial role in preventing re-aggregation of the CNCs during drying and improving the dispersion of CNCs in the PLA. The coated paper was characterized using mechanical tests, water vapor permeability (WVP), X-ray diffraction (XRD), scanning electron microscopy (SEM) and air permeability. The results showed More >

Mingzhe Jiang¹, S. Nicole DeMass¹, D. Ross Economy², Thomas Shackleton¹, Christopher L. Kitchens^1*

Journal of Renewable Materials, Vol.4, No.5, pp. 377-387, 2016, DOI:10.7569/JRM.2016.634131

Abstract Spin coating was used to cast a uniform film of cellulose nanocrystals with low surface roughness and variable thickness as a function of operational parameters that include rotational speed and dispense suspension concentration. The film thickness was controllable from 40 nm up to 1 μm with surface roughness an order of magnitude less than blade-coating methods. The degree of radial orientation was qualitatively assessed and shown to be variable with processing parameters. Under specific processing conditions, the formation of striation patterns was observed and associated with film drying instability. The striation patterns are periodic in… More >

Monique de Alvarenga Pinto Cotrim^1*, Jessyca Aparecida Paes Dutra², Suzana Gonçalves Carvalho², Janaina Cecília Oliveira Villanova², Eliane Ayres¹

Journal of Renewable Materials, Vol.4, No.1, pp. 9-17, 2016, DOI:10.7569/JRM.2015.634122

Abstract In recent years there has been an increasing demand for the application of natural products to address problems in the environment. The use of products derived from renewable resources can provide a sustainable strategy to replace totally or partially synthetic products. Cymbopogon, commonly known as lemongrass, is a tropical grass cultivated mostly for its essential oil, which has demonstrated several bioactivities, including antibacterial and antifungal properties. In the present work the formation of inclusion complex between β-cyclodextrin (β-CD) and lemongrass essential oil (LGEO) as well as its fi xation onto cotton fabric were investigated. Inclusion More >

Pronob Gogoi, Dhaneswar Das, Shyamalima Sharma, Swapan K. Dolui^*

Journal of Renewable Materials, Vol.3, No.2, pp. 151-159, 2015, DOI:10.7569/JRM.2014.634129

Abstract Alkyd resins based on Jatropha curcas oil with different molar ratios of phthalic anhydride (PA) and maleic anhydride (MA) were prepared by alcoholysis followed by polyesterifi cation reaction. The progress of the reaction was traced by the determination of acid value at regular time intervals. From the kinetic study the extent of the reaction was found in the range of 52.4–61.2%. The prepared resins were blended with a commercially available fast-curing epoxy resin in order to improve the properties like curing time, chemical resistance, tensile strength, and thermal stability. The morphology study of the blends More >