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  • Open Access

    ARTICLE

    Impact of Polymerization Protocol on Structure-Property Relationships of Entirely Lipid-Derived Poly(ester urethane)s

    Shegufta Shetranjiwalla, Shaojun Li, Laziz Bouzidi, Suresh S. Narine*

    Journal of Renewable Materials, Vol.5, No.5, pp. 333-344, 2017, DOI:10.7569/JRM.2017.634102

    Abstract The impact of polymerization protocol on phase structure and properties of entirely lipid-derived thermoplastic poly(ester urethane)s (TPEU)s was investigated. The TPEUs were synthesized from 1,7-heptamethylene diisocyanate, polyester diols and 1,9-nonanediol (ND) as chain extender. A two-stage polymerization method was used to prepare two TPEUs; one in which ND was added in the first stage of polymerization as part of the prepolymer and another in the second stage after the prepolymer was formed. Two very different morphologies exhibiting different degrees of phase separation were obtained, driven by the sequence of addition of the chain extender. The More >

  • Open Access

    ARTICLE

    Tailoring the Properties of Thermoplastic Starch with Bamboo Powder and/or Hollow Glass Microspheres

    Liliane Cruz Gomes de Souza Santos1*, Eliane Ayres2, Flávio Renato de Góes Padula1

    Journal of Renewable Materials, Vol.5, No.3-4, pp. 307-312, 2017, DOI:10.7569/JRM.2017.634121

    Abstract In this study, bamboo powder and/or hollow glass microspheres were added to thermoplastic cassava starch in order to overcome its drawbacks. The composites were characterized by scanning electron microscopy (SEM), tensile testing, water contact angle measurement and X-ray diffractometry (XRD), in addition to their thermal properties. The mechanical strength of the composites showed a general decline with increasing bamboo powder content while the water contact angles increased up to 15% of bamboo powder content (% w/w dry starch). The addition of hollow glass microspheres provides an optimal balance between hydrophobicity and mechanical strength. The results More >

  • Open Access

    ARTICLE

    Biobased Additives as Biodegradability Enhancers with Application in TPU-Based Footwear Components

    Isabel Patrícia Fernandes1, Mariana Barbosa1, Joana Soares Amaral2, Vera Pinto3, José Luís Rodrigues3, Maria José Ferreira3, Maria Filomena Barreiro1*

    Journal of Renewable Materials, Vol.4, No.1, pp. 47-56, 2016, DOI:10.7569/JRM.2015.634126

    Abstract Among the wide variety of materials employed in the manufacture of shoes, thermoplastic polyurethanes (TPUs) are one of the most widely used. Given its widespread use, and associated waste management problems, the development of more biodegradable and evironmentally compatible solutions is needed. In this work, a polyester-based TPU used in the footwear industry for outsoles production was modifi ed by compounding with lignin, starch and cellulose at content of 4% (w/w). The biodegradability was evaluated by using agar plate tests with the fungi Aspergillus niger ATCC16404, the Gram-negative bacteria Pseudomonas aeruginosa ATCC9027 and an association More >

  • Open Access

    ARTICLE

    THE EFFECT OF MELTING ON MIXED CONVECTION HEAT AND MASS TRANSFER IN NON-NEWTONIAN NANOFLUID SATURATED IN POROUS MEDIUM

    R.R. Kairia, Ch. RamReddyb,*

    Frontiers in Heat and Mass Transfer, Vol.6, pp. 1-7, 2015, DOI:10.5098/hmt.6.6

    Abstract In this paper, we investigated the influence of melting on mixed convection heat and mass transfer from the vertical flat plate in a non-Newtonian nanofluid saturated porous medium. The wall and the ambient medium are maintained at constant, but different, levels of temperature and concentration. The Ostwald–de Waele power-law model is used to characterize the non-Newtonian nanofluid behavior. A similarity solution for the transformed governing equations is obtained. The numerical computation is carried out for various values of the non-dimensional physical parameters. The variation of temperature, concentration, heat and mass transfer coefficients with the power-law More >

  • Open Access

    ARTICLE

    Multi-institutional outcomes and cost effectiveness of using alvimopan to lower gastrointestinal morbidity after cystectomy and urinary diversion

    Anup Vora, Daniel Marchalik, Hanaa Nissim, Keith Kowalczyk, Gaurav Bandi, Kevin McGeagh, John Lynch, Krishnan Venkatesan, Reza Ghasemian, Jonathan Hwang, Mohan Verghese

    Canadian Journal of Urology, Vol.21, No.2, pp. 7222-7227, 2014

    Abstract Introduction: Radical cystectomy is associated with significant morbidity and cost, with rates of gastrointestinal complications as high as 30%. Alvimopan is a mu opioid receptor antagonist that has been shown in randomized-control trials to accelerate gastrointestinal recovery in patients undergoing bowel resection with primary anastamosis. We report our experience with gastrointestinal recovery for patients undergoing cystectomy with urinary diversion treated with alvimopan and cost benefit associated.
    Materials and methods: Between January 2008 and October 2012, 80 patients underwent radical cystectomy with urinary diversion at two institutions. Forty-two patients in our study did not receive alvimopan preoperatively.… More >

  • Open Access

    REVIEW

    Thermoplastic Starch: Current Development and Future Trends

    Fengwei Xie1,*, Paul Luckman1, John Milne1, Lachlan McDonald1, Conor Young1, Chen Yang Tu1, Teo Di Pasquale1, Reinhard Faveere1, Peter J. Halley1,2

    Journal of Renewable Materials, Vol.2, No.2, pp. 95-106, 2014, DOI:10.7569/JRM.2014.634104

    Abstract Starch is a biopolymer that is widely available from agriculture/nature and thus is renewable and cheap. In addition, starch-based materials are biodegradable, offering a great advantage over traditional nonbiodegradable synthetic polymers. However, the poor processibility and product performance of starch have greatly impeded the wide application of starch in real applications. This paper reviews the current developments of the production of thermoplastic starch as a commodity renewable material. The biological origins of the feedstock, formulation development, processing requirements, as well as the important aspects that need to be addressed when designing a product from starch More >

  • Open Access

    ARTICLE

    Foam-Laid Thermoplastic Composites Based on Kraft Lignin and Softwood Pulp

    Antti Ojala1,*, Lisa Wikström1, Kalle Nättinen2, Jani Lehmonen3, Karita Kinnunen-Raudaskoski4

    Journal of Renewable Materials, Vol.2, No.4, pp. 278-284, 2014, DOI:10.7569/JRM.2014.634126

    Abstract This article presents a new method of producing thermomoldable nonwoven materials based on kraft lignin (KL) and softwood kraft pulp (KP). A mixture of starch acetate (SA) and triethyl citrate (TEC) was used as a water insoluble plasticizer for KL. The thermoplastic lignin (TPL) material with the optimized ratio of KL, SA and TEC was prepared in a twin-screw extruder. The TPL compound was ground and mixed with KP fi bers to produce thermoformable sheets using foam-laid technology. The formed webs were compression molded (CM) into plates and mechanically tested. The foam-laid composites had tensile More >

  • Open Access

    ARTICLE

    Variability of Metarhizium anisopliae var. anisopliae based on the Random Amplified Polymorphic DNA technique

    García-Pereyra J1, GN Aviña-Martínez1, AA Orozco-Flores2, OG Alvarado-Gómez3, M García-Montelongo4, G Alejandre-Iturbide5, JN Uribe-Soto5, H Medrano-Roldan6

    Phyton-International Journal of Experimental Botany, Vol.83, pp. 37-43, 2014, DOI:10.32604/phyton.2014.83.037

    Abstract It was analyzed the genetic variability of (1) three strains of a pathogenic fungi of the genus Metharhizium anisopliae var anisopliae, named MA22, MA24 and MA25, brand spesifik®; (2) two strains of the product Metasaven®, named MA1A and MAII; one strain of the product Metatron®; and a native strain named MACN. This latter strain was directly isolated from the insect chapulin (Brachystola magna), from the farmer, corn plots in Durango, located in north central Mexico. Studies were conducted in the laboratory of molecular biology of the Technological Institute of the Valley of Guardiana in Durango, Mexico, from… More >

  • Open Access

    ARTICLE

    FUNDAMENTALS AND APPLICATIONS OF NEAR-FIELD RADIATIVE ENERGY TRANSFER

    Keunhan Parka,∗, Zhuomin Zhangb

    Frontiers in Heat and Mass Transfer, Vol.4, No.1, pp. 1-26, 2013, DOI:10.5098/hmt.v4.1.3001

    Abstract This article reviews the recent advances in near-field radiative energy transfer, particularly in its fundamentals and applications. When the geometrical features of radiating objects or their separating distances fall into the sub-wavelength range, near-field phenomena such as photon tunneling and surface polaritons begin to play a key role in energy transfer. The resulting heat transfer rate can greatly exceed the blackbody radiation limit by several orders magnitude. This astonishing feature cannot be conveyed by the conventional theory of thermal radiation, generating strong demands in fundamental research that can address thermal radiation in the near field. More >

  • Open Access

    ARTICLE

    Fully Renewable Thermoplastic Poly(ester urethane urea)s from Bio-based Diisocyanates

    Donglin Tang1,2, Shanmugam Thiyagarajan2,3, Bart A.J. Noordover1,*, Cor E. Koning1, Daan S. van Es3, Jacco van Haveren

    Journal of Renewable Materials, Vol.1, No.3, pp. 222-230, 2013, DOI:10.7569/JRM.2013.634116

    Abstract A series of fully renewable poly(ester urethane urea)s (PEUs) were synthesized from bio-based starting materials, e.g., the polyester diol, the diisocyanates including L-lysine diisocyanate (LDI) and isoidide diisocyanate (IIDI), the chain-extenders including 1,4-diaminobutane (bDA), diaminoisoidide (iDA) and di(aminobutyl) urea (b2 DA). It is found that the PEU based on the novel diisocyanate, IIDI, exhibits satisfactory thermal and mechanical properties. The LDI-based PEUs show less favorable thermal and mechanical properties than the IIDI-based counterpart, since the chemical structure of LDI is less regular than that of IIDI. However, by introducing a urea-containing dimeric diamine (b2 DA) More >

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