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  • Open Access

    ARTICLE

    Effect of the back contact electrode on the performances of the ultra-thin photovoltaic cells based on the CdS/CdTe heterojunction

    A. M. Radutaa,b, A. M. Panaitescua, A. Radua, L. Iona, V. A. Antohea,c, O. Tomaa, S. Iftimiea, S. Antohea,d,*

    Chalcogenide Letters, Vol.20, No.12, pp. 871-882, 2023, DOI:10.15251/CL.2023.2012.871

    Abstract This paper proposes a comparative study between two sub-micrometric multi-layered photovoltaic cells, based on AII–BVI compounds, using different structures for the holes transport and collection electrode. Using the modified form of the Shockley equation, the diode factor, n, the reverse saturation current, I0, and the series Rs and shunt Rsh resistances were evaluated and their effect on the photovoltaic cells performances were discussed. The photovoltaic performances were analysed by current-voltage characteristics at illumination in standard AM 1.5 conditions, and the specific parameters were determined. More >

  • Open Access

    ARTICLE

    Formation of PbS microstructured films by CBD method and study of structural properties

    G. Amirbekovaa, Zh. Tolepova,*, N. Guseinova, R. Nemkaevaa, T. Kuanyshbekovb, A. Ramazanovaa, D. Tlaubergenovaa

    Chalcogenide Letters, Vol.20, No.12, pp. 857-861, 2023, DOI:10.15251/CL.2023.2012.857

    Abstract Microcrystalline lead sulfide (PbS) films were synthesized using the chemical deposition method. The films were deposited on pre-cleaned glass substrates and polished silicon wafers. Chemicals of high purity were utilized in the process. The morphology, composition, and structure of the films were characterized using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD). The films exhibited a galena phase with a face-centered cubic structure belonging to the Fm-3m space group. The average grain size was determined using the WilliamsonHall method, revealing a homogenous structure. Raman spectroscopy further confirmed the structural integrity of More >

  • Open Access

    ARTICLE

    Characterization of undoped and doped CdS nano-thin films by ZnO for photocatalytic application

    A. Thamera, S. Mohamedb,*

    Chalcogenide Letters, Vol.20, No.12, pp. 847-856, 2023, DOI:10.15251/CL.2023.2012.847

    Abstract Using Sol-gel technology, nanocomposite CdS: ZnO thin films with an equal molar ratio of 0.5 M on a glass substrate for water decontamination purposes. The ZnO doping ratios were (0, 1, 3, 5) vol. The ultrastructural, morphological, and optical properties of the prepared thin films were studied using X-ray diffraction (XRD), atomic force microscopy (AFM), and UV-vis spectra. The results indicated that the prepared nanostructured CdS: ZnO thin films contain uniformly spaced crystalline grains of both CdS and ZnO. The ZnO-doped selection ratio and uniform grain distribution produced outstanding photocatalytic and photocatalytic performance. With a More >

  • Open Access

    ARTICLE

    Chitosan/PVA Films and Silver Nanoparticle Impregnated Nanofibrous Dressings for Evaluation of their Wound Healing Efficacy in Wistar Albino Rat Model

    SOBHA KOTA*, RATNAKUMARI ANANTHA, VAYUNANDANA RAO GOVADA, PRADEEP DUMPALA

    Journal of Polymer Materials, Vol.40, No.3-4, pp. 285-303, 2023, DOI:10.32381/JPM.2023.40.3-4.10

    Abstract The exoskeleton of marine shrimp contains a natural, biocompatible polymer chitin, which is dumped as a waste. The study proposes the sustainable single-pot-extraction of chitosan from the waste and its use in the fabrication of wound-dressings, and thus leverage its piezoelectric, antioxidant, hypoglycaemic and medicinal properties in wound-healing. The Fourier transform infrared spectrum revealed that marine chitosan contains functional groups with N-O, O-H, and CO stretching. Scanning electron micrographs demonstrated the spherical and mesoporous structures of the extracted chitosan. X-ray diffraction analysis showed a semi-crystalline phase of chitosan particles with a mean size of 28.9… More >

  • Open Access

    PROCEEDINGS

    Peeling by Pulling: Characterizing the Mechanical Behavior of Nanoscale Thin Films

    Zhaohe Dai1,*

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.26, No.2, pp. 1-1, 2023, DOI:10.32604/icces.2023.09223

    Abstract The flexible and clinging nature of ultra-thin films require the understanding of their elastic and adhesive properties in a wide range of circumstances from fabrications to applications. Simultaneously measuring both properties, however, is extremely difficult as the film thickness diminishes to nanoscales. In this talk, I will show our recent work that addresses such difficulties through peeling by vertically pulling thin films off from the substrates (we thus refer to it as “pull-to-peel”). Particularly, we perform in-situ pull-to-peel of graphene and MoS2 films in a scanning electron microscope and achieve simultaneous determination of their Young’s More >

  • Open Access

    PROCEEDINGS

    Flexoelectric Polar Patterns in Wrinkled Thin Films

    Hongxing Shang1,*, Xu Liang1, Shengping Shen1

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.25, No.1, pp. 1-1, 2023, DOI:10.32604/icces.2023.09816

    Abstract Flexoelectricity is the coupling effect of polarization and strain gradients, which tends to be more pronounced in thin films owing to size dependency. When subjected to in-plane compression, a filmsubstrate system will form complex wrinkle morphologies along with large-area and tunable strain gradients. The wrinkle-induced strain gradients can locally break the inversion symmetry of dielectrics and thus introduce flexoelectric polarization. Here, an electromechanical coupling model is developed to theoretically deal with flexoelectric polar patterns in wrinkled thin films. By analyzing the energy competition of elastic potential and electrostatic energy, the amplitude, wavelength, and critical strain… More >

  • Open Access

    REVIEW

    Cellulose-Based Films for Food Packaging Applications: Review of Preparation, Properties, and Prospects

    Xiaoyan Liu1,2, Zhao Qin1,2,*, Yuxiang Ma1,2, Huamin Liu1,2,*, Xuede Wang1,2

    Journal of Renewable Materials, Vol.11, No.8, pp. 3203-3225, 2023, DOI:10.32604/jrm.2023.027613 - 26 June 2023

    Abstract Packaging is a food preservation technology widely used in the world. Naturally-sourced, biodegradable polymers are becoming increasingly popular in the food packaging sector. Packaging films prepared using cellulose as raw material would contribute to resource sustainability, but the difficulty of cellulose solubilization limits their further development. In view of this, a series of novel solvent systems (LiCl/DMAc, ILs, TBAH/DMSO, NMMO, alkali/urea solutions, metal-complex solutions) were used to prepare high-strength and high-performance cellulose-based films; their characteristics and the mechanisms involved were investigated. Composite films prepared by blending cellulose with various polymers (synthetic polymers, natural polymers, proteins More > Graphic Abstract

    Cellulose-Based Films for Food Packaging Applications: Review of Preparation, Properties, and Prospects

  • Open Access

    ARTICLE

    Preparation and Performance of Pueraria lobata Root Powder/Polylactic Acid Composite Films

    Shuang Zhao1, Shenglan Chen2, Shuan Ren1, Gang Li3, Ke Song1,4, Jie Guo1,4, Shima Liu1,4, Jian He1,4, Xianwu Zhou1,4,*

    Journal of Renewable Materials, Vol.11, No.6, pp. 2531-2553, 2023, DOI:10.32604/jrm.2023.026066 - 27 April 2023

    Abstract Petroleum-based materials, such as plastic, are characterized by adverse environmental pollution; as a result, researchers have sought alternative degradable plastics that are environmentally friendly, such as polylactic acid (PLA). PLA has shown great potential to replace petroleum-based plastics. In this study, seven different samples of unmodified Pueraria lobata root powder (PRP) with different contents (i.e., 0, 5, 10, 15, 20, 25, and 30 wt%) and three different modified PRPs (i.e., treated with NaOH, NaOH-KH-550, and Formic) were used to reinforce polylactic acid (PLA) via solution casting process. These prepared PRP/PLA composite films were characterized using SEM,… More > Graphic Abstract

    Preparation and Performance of <i>Pueraria lobata</i> Root Powder/Polylactic Acid Composite Films

  • Open Access

    ARTICLE

    Preparation and Properties of Vegetable-Oil-Based Thioether Polyol and Ethyl Cellulose Supramolecular Composite Films

    Ruyu Yan1,2,3,4, Jian Fang1,*, Xiaohua Yang2,3,4,5,6, Na Yao2,3,4,5,6, Mei Li2,3,4,5,6, Yuan Nie2,3,4,5,6, Tianxiang Deng2,3,4,5,6, Haiyang Ding2,3,4,5,6, Lina Xu2,3,4,5,6, Shouhai Li2,3,4,5,6,*

    Journal of Renewable Materials, Vol.11, No.4, pp. 1937-1950, 2023, DOI:10.32604/jrm.2023.025126 - 01 December 2022

    Abstract Ethyl cellulose (EC), an important biomass-based material, has excellent film-forming properties. Nevertheless, the high interchain hydrogen bond interaction leads to a high glass transition temperature of EC, which makes it too brittle to be used widely. The hydroxyl group on EC can form a supramolecular system in the form of a non-covalent bond with an effective plasticizer. In this study, an important vegetable-oil-based derivative named dimer fatty acid was used to prepare a novel special plasticizer for EC. Dimer-fatty-acid-based thioether polyol (DATP) was synthesized and used to modify ethyl cellulose films. The supramolecular composite films… More > Graphic Abstract

    Preparation and Properties of Vegetable-Oil-Based Thioether Polyol and Ethyl Cellulose Supramolecular Composite Films

  • Open Access

    ARTICLE

    Pulse Laser Deposition of HfO2 Nanoporous-Like Structure, Physical Properties for Device Fabrication

    Shams B. Ali1, Sarmad Fawzi Hamza Alhasan1, Evan T. Salim2,*, Forat H. Alsultany3, Omar S. Dahham4,5

    Journal of Renewable Materials, Vol.10, No.11, pp. 2819-2834, 2022, DOI:10.32604/jrm.2022.021609 - 29 June 2022

    Abstract The pulsed laser deposition (PLD) technology was used to effectively create conductive nano and micro hafnium oxide with great purity and transparency for (HfO2) nanofilms. In many optoelectronics devices and their applications, the presence of a high dielectric substance like a nano HfO2, between the metal contacts and the substrates was critical. We used the Pulsed Laser Deposition method to fabricate an Al/HfO2/p-Si Schottky barrier diode where the nanostructured HfO2 films as an intermediate layer and varied substrate temperatures. The optical result reveals a high degree of transparency (93%). The optical bandgap of deposited HfO2 films was observed… More >

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