M. F. Elkady^1,2,*, E. M. El-Sayed², Mahmoud Samy³, Omneya A. Koriem¹, H. Shokry Hassan^4,5

Journal of Renewable Materials, Vol.12, No.2, pp. 369-380, 2024, DOI:10.32604/jrm.2023.046585 - 11 March 2024

Abstract In this study, green zinc oxide (ZnO)/polypyrrole (Ppy)/cellulose acetate (CA) film has been synthesized via solvent casting. This film was used as supporting material for glucose oxidase (GOx) to sensitize a glucose biosensor. ZnO nanoparticles have been prepared via the green route using olive leaves extract as a reductant. ZnO/Ppy nanocomposite has been synthesized by a simple in-situ chemical oxidative polymerization of pyrrole (Py) monomer using ferric chloride (FeCl₃) as an oxidizing agent. The produced materials and the composite films were characterized using X-ray diffraction analysis (XRD), scanning electron microscope (SEM), Fourier transform infrared (FTIR) and… More > Graphic Abstract

Mingxuan He¹, Yahui Zheng¹, Jiaming Shen¹, Jiawei Shi¹, Yongzheng Zhang¹, Yinghong Xiao^2,*, Jianfei Che^1,*

Journal of Renewable Materials, Vol.12, No.2, pp. 215-233, 2024, DOI:10.32604/jrm.2023.043659 - 11 March 2024

Abstract

The abuse of plastic food packaging has brought about severe white pollution issues around the world. Developing green and sustainable biomass packaging is an effective way to solve this problem. Hence, a chitosan/sodium alginate-based multilayer film is fabricated via a layer-by-layer (LBL) self-assembly method. With the help of superior interaction between the layers, the multilayer film possesses excellent mechanical properties (with a tensile strength of 50 MPa). Besides, the film displays outstanding water retention property (blocking moisture of 97.56%) and ultraviolet blocking property. Anthocyanin is introduced into the film to detect the food quality since

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Juan Yan¹, Wenchao Li¹, Xianfang Zhang¹, Shisheng Liu^2,*

Journal of Renewable Materials, Vol.12, No.1, pp. 71-87, 2024, DOI:10.32604/jrm.2023.028927 - 23 January 2024

Abstract In this study, intelligent, pH-responsive colorimetric films were prepared by encapsulating anthocyanins in nanocomplexes prepared from glutenin and carboxymethyl chitosan. These nanocomplexes were added to a corn starch matrix and used in the freshness monitoring of chilled pork. The effects of anthocyanin-loaded nanocomplexes on the physical, structural, and functional characteristics of the films were investigated. The addition of anthocyanin-loaded nanocomplexes increased the tensile strength, elongation at break, hydrophobicity, and light transmittance of the films while decreasing their water vapor permeability. This is because new hydrogen bonds are formed between the film components, resulting in a More >

R. S. Ali^a,*, H. S. Rasheed^b, N. F. Habubi^c, S. S. Chiad^b

Chalcogenide Letters, Vol.20, No.1, pp. 63-72, 2023, DOI:10.15251/CL.2023.201.63

Abstract A thin film of iron disulfide (FeS₂) and Mn-doped was prepared using the chemical spray pyrolysis (CSP) method at a constant temperature of the glass substrate at around 400 °C. According to XRD examination, films were structurally cubic oriented with a predominant planar orientation (201). The doping of Mn ions in the FeS₂ host matrix was confirmed by a minor shift of the diffraction peak towards the lower 2θ values. The surface of the produced film for pyrite was homogeneous, according to the AFM investigations. According to the XRD data, the predicted grain size altered as More >

A. B. Alwany^a,b,*, G. M. Youssef^b, M. A. Algradee^a, M. A. Abdel-Rahim^c, A. Alnakhlani^a,d, B. Hassan^a,d

Chalcogenide Letters, Vol.20, No.1, pp. 19-31, 2023, DOI:10.15251/CL.2023.201.19

Abstract Thin films of Zn₅₀Se₅₀ were prepared by the vacuum evaporation technique on glass substrates. The influence of annealing temperature (T_ann.) on the structural and optical properties of ZnSe polycrystalline films was investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM) and optical transmittance T (λ). The crystalline phases that were found in the Zn₅₀Se₅₀ thin films are ZnSe, Se and Zn. The refractive index (n) and the thickness of the films (d) were calculated using Swanepoel’s method for the films annealed at (423 K). The mechanism of optical absorption follows the rule of direct transition. The values More >

H. K. Hassun^a, B. K. H. Al-Maiyaly^a, A. H. Shaban^b,*

Chalcogenide Letters, Vol.20, No.2, pp. 145-152, 2023, DOI:10.15251/CL.2023.202.145

Abstract In this work, we have examined the spectral response of (p-CuAlSe₂/n-Si) detector, (CAS) thin films deposited by thermal evaporation at RT with a thickness (450) nm, and annealing temperature at (473K) for 2 h. Optical transmission measurements displayed reasonably slight transmission besides higher absorbance trendy the visible region, energy gaps were observed by annealing, were found to be direct, and decreased with the effect of annealing. The extreme responsivity value arises at wavelength 459 nm, with improvement value of specific detectivity and quantum efficiency the annealing films be situated originate as greatest suitable aimed at numerous More >

A. K. Aqili^a,*, T. Abu-Omar^a, A. Y. Al-Reyahi^a, A. Shaheen^a, S. Al-Omari^a, I. Alhagish^a

Chalcogenide Letters, Vol.20, No.2, pp. 113-120, 2023, DOI:10.15251/CL.2023.202.113

Abstract Zinc Telluride (ZnTe) films were prepared by the closed space sublimation (CSS) method. The effect of chemical treatments with concentrated phosphoric acid, on the optical, electric and structural properties of the films was studied. Zinc-blend structure of the polycrystalline nature of the films was confirmed by x-ray diffraction (XRD) spectra. The energy dispersive x-ray (EDX) shows an increase in Te ratio on the surface of the film as exposed to phosphoric acid. In addition, the dc electrical resistivity of the films was dropped considerably. The refractive index, thickness, and thickness irregularity of the films were More >

R. H. Athab, B. H. Hussein^*

Chalcogenide Letters, Vol.20, No.2, pp. 91-100, 2023, DOI:10.15251/CL.2023.202.91

Abstract A thin film of AgInSe₂ and Ag_1-xCu_xInSe₂ as well as n-Ag_1-xCu_xInSe₂ /p-Si heterojunction with different Cu ratios (0, 0.1, 0.2) has been successfully fabricated by thermal evaporation method as absorbent layer with thickness about 700 nm and ZnTe as window layer with thickness about 100 nm. We made a multi-layer of p-ZnTe/n-AgCuInSe2/p-Si structures, In the present work, the conversion efficiency (η) increased when added the Cu and when used p-ZnTe as a window layer (WL) the bandgap energy of the direct transition decreases from 1.75 eV (Cu=0.0) to 1.48 eV (Cu=0.2 nm) and the bandgap energy for… More >

I. Nkrumah^*, F. K. Ampong, A. Britwum, M. Paal, B. Kwakye-Awuah, R. K. Nkum, F. Boakye

Chalcogenide Letters, Vol.20, No.3, pp. 205-213, 2023, DOI:10.15251/CL.2023.203.205

Abstract Single phase lead tin sulfide (PbSnS) thin films have been successfully deposited on ITO coated glass substrates using a 3-electrode electrochemical cell having graphite as the counter electrode and Ag/AgCl as the reference electrode. In this single-step electrodeposition, the PbSnS precursor thin film was directly electrodeposited on the conductive substrate from the electrolytic bath solution which contained Pb(NO₃)₂, SnCl₂.2H₂O and Na₂S₂O₃. This was followed by annealing in air at 250 °C for an hour to improve the crystallinity. The annealed films were characterized by a variety of techniques. Powder X-ray diffraction revealed peaks which were indexed to More >

R. S. Ali^a,*, H. S. Rasheed^b, N. D. Abdulameer^c, N. F. Habubi^d, S. S. Chiad^b

Chalcogenide Letters, Vol.20, No.3, pp. 187-196, 2023, DOI:10.15251/CL.2023.203.187

Abstract Chemical spray pyrolysis (CSP) was utilized to create pure Zinc Sulfide (ZnS) and magnesium (Mg) doped thin films on a clean glass substrate at a temperature equal to 400°C. X-ray diffraction test revealed a cubic wurtzite crystal structure with average crystallite sizes of 10.99 and 12.27 nm for ZnS and ZnS: Mg, respectively. XRD analysis of the doped films revealed a polycrystalline structure with a predominant peak along the (220) plane and additional peaks along the (111), (200), and (222) planes. The grain size raised from 10.99 to 12.27 nm as a result of the More >