M. Sudha^a,*, A. B. Madhan^b, M. Revathi^c

Chalcogenide Letters, Vol.21, No.10, pp. 841-845, 2024, DOI:10.15251/CL.2024.2110.841

Abstract Zinc sulfide thin films were prepared using the economical spray pyrolysis process. A thin film of exceptional quality with a temperature difference of 300 °C to 400 °C is produced by optimizing variables such as concentration, flow rate, and nozzle to substrate distance. These films' optical characteristics and structure were examined. The deposited thin films displayed a direct and allowed transition, as indicated by the optical transmittance spectra. XRD analysis confirmed that the deposited thin films were polycrystalline with a cubic phase. This film can be used in solar cell applications since the band gap More >

G. M. Liu^a, G. Hu^b, P. Tang^c, L. L. Wu^a,d,*, X. Hao^a,d, G. G. Zeng^a, W. W. Wang^a, J. Q. Zhang^a,d

Chalcogenide Letters, Vol.21, No.10, pp. 797-808, 2024, DOI:10.15251/CL.2024.2110.797

Abstract V-doped CdTe polycrystalline films can achieve both doping activation and defect passivation by high-temperature CdCl₂ heat treatment, but this requires simultaneous modulation of the amount of CdCl₂ introduced to obtain high-quality films. It is found that increasing the CdCl₂ introduction does not change the physical phase structure and lattice constant of CdTe:As thin films, but promotes grain recrystallisation, and can promote the formation of A-center, and inhibit the formation of Cd vacancy (VCd) defects, as well as the formation of deep energy level defects. The results provide guidance for the improvement of high-temperature CdCl₂ heat treatment of More >

L. Bouras^a, A. Beggas^a,*, D. Sahnoune^b, M. Ghougali^a, R. Ferhat^a

Chalcogenide Letters, Vol.21, No.11, pp. 917-926, 2024, DOI:10.15251/CL.2024.2111.917

Abstract The present study intends to provide the impact of nitric acid on the structural and optical characteristics of thin films of ZnO. The latter was grown on substrates of glass via spray pyrolysis with 400°C, using Zinc acetate aqueous solution acidified by different amounts of nitric acid to obtain a pH ranging from 6.8 to 2.9. The film properties were analyzed as a function of pH. In the light of the XRD analysis, all the films have a preferential direction along the (002) plane. Depending on pH conditions, the crystal size increased from 32.38 to More >

S. M. Hadi^*, I. H. Khudayer

Chalcogenide Letters, Vol.21, No.11, pp. 885-893, 2024, DOI:10.15251/CL.2024.2111.885

Abstract Chalcogenide have attracted great interest over the last years due to their thermal, electrical and optical properties. Understanding the crystal structures of chalcogenide is crucial in the hunt for novel materials. In this study, we prepared Cu₂Se_0.8Te_0.2 thin film on a glass substrate using thermal evaporation method and then annealed at different temperatures (403, 453 &503) K to study the effect of annealing on the structure and optical properties of the film, we find that Cu₂Se_0.8Te_0.2 the composition is cubic structural and this is shown by X-ray analyses. And the optical properties improve with different annealing More >

M. Temiz^a,*, S. Çelik^b

Chalcogenide Letters, Vol.21, No.11, pp. 867-872, 2024, DOI:10.15251/CL.2024.2111.867

Abstract Ternary thin films have garnered significant attention due to their adjustable band gap characteristics, making them suitable for many applications. In this research, we examined the structural and optical characteristics of PbZnS thin films fabricated onto glass substrates employing the spray pyrolysis techniuqe. The films were fabricated at different temperatures ranging from 300 to 400°C. X-ray diffraction (XRD) analysis indicated that all films displayed a cubic structure with a preferred orientation along the (200) plane. From the analysis of XRD peaks, it was observed that the crystal structure initially improved with increasing temperature but then More >

L. N. Ibrahimova^a,b, Kh. N. Ahmadova^c,d,e, M. E. Aliyev^b, Y. I. Aliyev^f,g,*

Chalcogenide Letters, Vol.21, No.12, pp. 1035-1039, 2024, DOI:10.15251/CL.2024.2112.1035

Abstract In this research, we investigated the optical properties of CdSe thin films on glass substrates using spectroscopic ellipsometry. The samples were analysed using an M-2000 rotation compensator spectroscopic ellipsometer at room temperature, covering a photon energy range of 1.5-7.0 eV. We used an appropriate dispersion model to obtain the spectral dispersion of the optical constants. We calculated the thickness, dielectric permittivity (real and imaginary parts), refraction, and extinction coefficients of the thin layers. The results showed high transparency that varied with the size of the CdSe thin films. Additionally, we determined the bandgap width for More >

Clara Pastor, Chelo González-Martínez, Maite Cháfer, Amparo Chiralt^*

Journal of Renewable Materials, Vol.12, No.12, pp. 1949-1962, 2024, DOI:10.32604/jrm.2024.056404 - 20 December 2024

Abstract Chitosan films with propolis aqueous extract were obtained in order to improve the antioxidant capacity of the materials. Likewise, oleic acid (OA) was also incorporated to enhance the film hydrophobicity, with and without previous infusion with propolis, to extract other potentially active compounds. The propolis extracts and the chitosan film-forming dispersions were characterised as to their particle size distribution, zeta potential and rheological behaviour. Chitosan-based films with aqueous extract and with oleic acid, containing or not propolis compounds, were obtained and characterised as to their microstructure, mechanical, barrier and optical properties and antioxidant capacity in… More > Graphic Abstract

Norma E. Marcovich¹, Matías Federico Hernández^1,2, María Roberta Ansorena^2,*

Journal of Renewable Materials, Vol.12, No.12, pp. 2049-2068, 2024, DOI:10.32604/jrm.2024.055151 - 20 December 2024

Abstract In this work, active and edible films for food packaging were obtained by intensive mixing and compression molding of the wheat gluten (WG) glycerol-plasticized paste. Thyme essential oil (TEO, 10 and 15 wt.%) was incorporated as the active component microencapsulated in β-cyclodextrins (β-CD) and included directly into the biopolymer matrix for comparison. It was found that films incorporating microencapsulated TEO are more soluble in water (total soluble matter (dry method) of about 33% and 36.6% vs. 22.4% and 18.6%, for films containing 10% and 15% TEO, respectively) but less rigid than those obtained with free oil… More > Graphic Abstract

Dong Li¹, Feilong Zhang², Shutao Wang^3,*, Huajian Gao^1,4,*, Xiaodong Chen^2,5,*

The International Conference on Computational & Experimental Engineering and Sciences, Vol.32, No.2, pp. 1-2, 2024, DOI:10.32604/icces.2024.011040

Abstract Three-dimensional (3D) architectures and related devices have been widely concerned in recent years due to their unique geometrical advantages and superior performance. Existing approaches to transforming planar thin films into 3D architectures require the use of active materials [1,2] or need substrates to maintain 3D shapes [3,4]. Here, we propose a peeling-induced shape morphing strategy to construct freestanding 3D architectures from 2D plastic films including inert polymers, such as polyethylene terephthalate (PET) and polyimide (PI), which are significant substrate materials for flexible electronics. The plastic strains generated by peeling the film from an adhered plane… More >

Rui Li^1,*, Yonggang Huang², John A. Rogers²

The International Conference on Computational & Experimental Engineering and Sciences, Vol.31, No.4, pp. 1-2, 2024, DOI:10.32604/icces.2024.012578

Abstract Bioresorbable electronic devices represent an emerging class of technology that involves components which physically disappear, in whole or in part, at prescribed rates and at programmed times [1,2]. Obtaining reliable performance and favorable degradation behavior demands materials that can serve as biofluid barriers in encapsulating structures that avoid premature degradation of active electronic components [3–5]. We have recently presented a multilayer organic–inorganic film design that addresses this need, with properties in water impermeability, mechanical flexibility, and processability that are superior to alternatives [6,7]. Theoretical modeling for water permeation across the multilayer films provides an important More >