F. Luzi¹, E. Fortunati^1*, A. Jiménez², D. Puglia¹, A. Chiralt², L. Torre¹

Journal of Renewable Materials, Vol.5, No.2, pp. 103-115, 2017, DOI:10.7569/JRM.2016.634135

Abstract Poly(lactic acid) (PLA) based nanocomposites reinforced with 1 wt% of surfactant-modified cellulose nanocrystals (s-CNC) extracted from Posidonia oceanica plant waste and zinc oxide nanoparticles (ZnO NPs) at different concentrations (0.1 and 0.5 wt%) were prepared by solvent casting process. Their thermal, morphological, optical, mechanical and water vapor permeability properties were investigated. Tensile testing showed increased values for strength and deformation at break in PLA based formulations reinforced with s-CNC and ZnO NPs as a consequence of better nanofiller dispersion compared to binary films reinforced only with ZnO NPs. Moreover, the effect of s-CNC and ZnO More >

Jithin Joy^1,2,3, Cintil Jose³, Srirama B. Varanasi⁴, Lovely Mathew P.^2,3, Sabu Thomas², Srikanth Pilla^1,5*

Journal of Renewable Materials, Vol.4, No.5, pp. 351-364, 2016, DOI:10.7569/JRM.2016.634128

Abstract Isora nanofibers (INF) were produced by a combined thermal-chemical-mechanical method from Helicteres isora plant. The resulting fibers were analyzed using transmission electron microscopy and scanning electron microscopy, which showed a network-like structure with a length of 600 nm, width of 50 nm and an aspect ratio of 12. Fourier transform infrared spectroscopy indicated that chemical treatments progressively removed noncellulosic constituents. X-ray diffraction analysis revealed that crystallinity increased with successive chemical treatments. Using the synthesized isora nanofibers, poly(butylene succinate) (PBS)-based biodegradable nanocomposites were prepared. The nanocomposites were processed using a Brabender twin-screw compounder and an injection… More >

Jose Luis Orellana, Michael Mauhar, Christopher L. Kitchens^*

Journal of Renewable Materials, Vol.4, No.5, pp. 340-350, 2016, DOI:10.7569/JRM.2016.634126

Abstract Polylactic acid (PLA) is one of the most widely used biodegradable polymers due to the ability to synthesize it economically at industrial scale and its favorable properties for many consumer products. However, the rigid nature of PLA is not desirable for specific applications, requiring the incorporation of effective bioderived additives in order to enhance the PLA toughness and broaden applications. In this work, PLA was modified by graft polymerization of polyacrylic acid (PLA-g-PAA) to increase the hydrophilicity to promote compatibilization of cellulose nanocrystals (CNCs) or high molecular polyethylene glycol (PEG). CNCs were found to act More >

Juan P. Correa^1,2*, Alejandro Bacigalupe^2,3, Jorge Maggi⁴, Patricia Eisenberg^2,3

Journal of Renewable Materials, Vol.4, No.4, pp. 258-265, 2016, DOI:10.7569/JRM.2016.634117

Abstract Poly(lactic acid)/poly(butylene adipate-co-terephthalate) (PLA/PBAT)-based nanocomposites were prepared by melt blending of PLA and PBAT with 5 wt% of unmodified (Cloisite Na) and modified (Cloisite 30B) montmorillonites. X-ray diffraction (XRD) revealed an intercalated structure in both nanocomposites. The extent of the intercalation was higher for nanocomposites based on modified clays (OMMT) with chemical affinity with the polymer matrix. Rheological measurements have shown an increase in viscosity and a better degree of clay dispersion for nanocomposites containing OMMT. Nanocomposites with OMMT showed lower PBAT separated phase particle size and improvements in thermal stability, mechanical properties and water More >

Itxaso Algar¹, Clara Garcia-Astrain¹, Alba Gonzalez², Loli Martin³, Nagore Gabilondo¹, Aloña Retegi^1*, Arantxa Eceiza^1*

Journal of Renewable Materials, Vol.4, No.1, pp. 57-65, 2016, DOI:10.7569/JRM.2015.634124

Abstract Bacterial cellulose/montmorillonite (BCMMT) hybrid bionanocomposite membranes were prepared by in-situ assembling or one-step biosynthesis process. The presence of MMT in BC membranes was confi rmed by thermogravimetric analysis and quantifi ed by mass spectrometry, resulting in bionanocomposites with MMT contents between 7–13 wt%. The incorporation of MMT during BC biosynthesis modifi ed BC morphology and led to lower porosity, even though higher water holding capacity was achieved. Bionanocomposites showed improved thermal stability and water vapor and oxygen gas barrier properties up to 70 and 80% with respect to neat BC membranes. This improvement was related More >

Marta Martínez-Sanz, Amparo López-Rubio, Maria José Fabra, José M. Lagaron^*

Journal of Renewable Materials, Vol.2, No.2, pp. 107-117, 2014, DOI:10.7569/JRM.2014.634106

Abstract Due to their high crystallinity and aspect ratio, bacterial cellulose nanowhiskers (BCNW) represent an appealing choice for the development of fully biobased nanocomposite materials with high barrier performance. However, their strong tendency to self-associate, together with their highly hydrophilic character, has restricted the production of nanocomposites containing cellulose nanowhiskers by industrial processing techniques such as melt compounding. Th is article presents an overview of the latest published results carried out within our group and also in other relevant literature, which have led to the development of an effi cient strategy for the incorporation of highly… More >

Mohammad Reza RAMEZANI¹, Hossein NADERI-MANESH^{1, *}, Hossain-Ali RAFIEEPOUR²

BIOCELL, Vol.38, No.1, pp. 11-16, 2014, DOI:10.32604/biocell.2014.38.011

Abstract Cell-based biosensors have become a research hotspot in the biosensors and bioelectronics fields. The main feature of cell-based biosensors is immobilization of living cells on the surface of transducers. Different types of polymers which are used as scaffolds for cell growth should be biocompatible and should have reactive functional groups for further attachment of biomolecules. In this work, cell attachment and proliferation on chitosan hydrogel, chitosan-gelatin and gold nanoparticle-chitosan nanocomposite membranes was studied. Characterization of the membranes was performed using scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). Cytotoxicity assessment on HEK293 More >

B.J. Yang¹, K.J. Cho¹, G.M. Kim¹, H.K. Lee^1,2

CMES-Computer Modeling in Engineering & Sciences, Vol.103, No.5, pp. 343-365, 2014, DOI:10.3970/cmes.2014.103.343

Abstract The addition of carbon nanotubes (CNTs) to a matrix material is expected to lead to an increase in the effective electrical properties of nanocomposites. However, a CNT entanglement caused by the matrix viscosity and the high aspect ratio of the nanotubes often inhibits the formation of a conductive network. In the present study, the micromechanics-based model is utilized to investigate the effect of CNT agglomeration on the electrical conductivity and percolation threshold of nanocomposites. A series of parametric studies considering various shapes and curviness distributions of CNTs are carried out to examine the effects of More >

Soleiman Ghouhestani¹, Farzad Shahabian¹, Seyed Mahmoud Hosseini^2,3

CMES-Computer Modeling in Engineering & Sciences, Vol.100, No.4, pp. 295-321, 2014, DOI:10.3970/cmes.2014.100.295

Abstract In this paper, the meshless local Petrov-Galerkin (MLPG) method is exploited for dynamic analysis of functionally graded nanocomposite cylindrical layered structure reinforced by carbon nanotube subjected to mechanical shock loading. The carbon nanotubes (CNTs) are distributed across radial direction on thickness of cylinder, which can be simulated by linear and nonlinear volume fraction. Free vibration and elastic wave propagation are studied for various value of volume fraction exponent at various time intervals. The layered cylinder is assumed to be under axisymmetric and plane strain conditions. Four types of CNTs distributions including uniform and three kinds… More >

K. S. Alan¹

CMC-Computers, Materials & Continua, Vol.44, No.1, pp. 1-21, 2014, DOI:10.3970/cmc.2014.044.001

Abstract In the framework of the piecewise homogeneous body model with the use of the three-dimensional geometrically nonlinear exact equations of the theory of elasticity, the method developed for the determination of the stress distribution in the nanocomposites with unidirectional locally curved and hollow nanofibers is used to investigate the normal stresses acting along the nanofibers. Furthermore, it is assumed that the body is loaded at infinity by uniformly distributed normal forces which act along the nanofibers and the crosssection of the nanofibers and normal to its axial line, is a circle of constant radius along More >