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  • Open Access

    ARTICLE

    Improving the Unconfined Compressive Strength of Red Clay by Combining Biopolymers with Fibers

    Zhiyu Weng1, Lina Wang1,2,*, Qiang Liu2, Xuemin Pan1, Yonghao Xu3, Jing Li1

    Journal of Renewable Materials, Vol.9, No.8, pp. 1503-1517, 2021, DOI:10.32604/jrm.2021.015003 - 08 April 2021

    Abstract To explore an environmentally friendly improvement measure for red clay, the function and mechanism of xanthan gum biopolymer and polypropylene fibers on the strength properties of red clay were investigated by unconfined compressive strength and scanning electron microscopy tests. The test results demonstrated that the contents and curing ages of xanthan gum had significant influences on the unconfined compressive strength of red clay. Compared with untreated soil, 1.5% xanthan gum content was the optimal ratio in which the strength increment was between 41.52 kPa and 64.73 kPa. On the other hand, the strength of xanthan… More >

  • Open Access

    ARTICLE

    New Biobased Polyurethane Materials from Modified Vegetable Oil

    Chakib Mokhtari1, Fouad Malek1, Sami Halila2, Mohamed Naceur Belgacem3,*, Ramzi Khiari3,4,5,*

    Journal of Renewable Materials, Vol.9, No.7, pp. 1213-1223, 2021, DOI:10.32604/jrm.2021.015475 - 18 March 2021

    Abstract Bio-based polyurethanes (PUs) have been occurred a large attention nowadays. It was found to be an alternative to the petrochemical based materials to the fact of their weak environmental influence, availability, good price and biodegradability. In addition, the nature shows several bio-derived compounds as raw materials for the synthesis of polyols, including the vegetable oils, polyphenol, terpene, and other bio-renewable sources. With the aim to develop a new family of biobased polyurethanes (PUs) via vegetable oils, the elaboration of new Jojoba-based PUs was performed by catalyst-free polycondensation reaction of a synthesized Jojoba diol with various More > Graphic Abstract

    New Biobased Polyurethane Materials from Modified Vegetable Oil

  • Open Access

    EDITORIAL

    Special Issue on 15th Brazilian Polymer Conference: Biopolymers, Eco-Friendly and Biodegradable Polymers and Other Topics Related to Polymeric Materials Derived from Renewable Materials

    Antonio Aprigio da Silva Curvelo1, Antonio José Felix Carvalho2,*, Daniel Pasquini3

    Journal of Renewable Materials, Vol.9, No.4, pp. 599-600, 2021, DOI:10.32604/jrm.2021.015335 - 01 February 2021

    Abstract This article has no abstract. More >

  • Open Access

    ARTICLE

    Removal of Cu(II), Pb(II), Mg(II), and Fe(II) by Adsorption onto Alginate/Nanocellulose Beads as Bio-Sorbent

    Ragab E. Abou-Zeid1, Korany A. Ali2, Ramadan M. A. Gawad2, Kholod H. Kamal3, Samir Kamel1, Ramzi Khiari4,5,6,*

    Journal of Renewable Materials, Vol.9, No.4, pp. 601-613, 2021, DOI:10.32604/jrm.2021.014005 - 01 February 2021

    Abstract

    Alginate blended with cellulose nanocrystals (CNC), cellulose nanofibers (CNF), and tri-carboxylate cellulose nanofibers (TPC-CNF) prepared and encapsulated in the form of microcapsules (bio-polymeric beads). The cellulosic nanomaterials that used in this study were investigated as nanomaterials for wastewater treatment applications. Batch experiments were performed to study the removal of copper, lead, magnesium, and iron from aqueous solutions by the prepared beads. The effects of the sorbent dosage and the modified polymers on the removing efficiency of the metal cations were examined. Atomic absorption was used to measure the metal ions concentrations. The modified bio-polymeric beads

    More >

  • Open Access

    ARTICLE

    Composite Biomaterials Based on Poly(L-Lactic Acid) and Functionalized Cellulose Nanocrystals

    Mariia Stepanova1, Ilia Averianov1, Olga Solomakha1, Natalia Zabolotnykh2, Iosif Gofman1, Mikhail Serdobintsev2, Tatiana Vinogradova2, Viktor Korzhikov-Vlakh1,3, Evgenia Korzhikova-Vlakh1,3,*

    Journal of Renewable Materials, Vol.8, No.4, pp. 383-395, 2020, DOI:10.32604/jrm.2020.09206 - 24 April 2020

    Abstract The biocomposite films were prepared from poly(L-lactic acid) and cellulose nanocrystals. To improve interfacial compatibility of hydrophilic cellulose nanocrystals with hydrophobic matrix polymer as well as to provide the osteoconductive properties, cellulose was functionalized with poly(glutamic acid). The modified cellulose nanocrystals were better distributed and less aggregated within the matrix, which was testified by scanning electron, optical and polarized light microscopy. According to mechanical tests, composites filled with nanocrystals modified with PGlu demonstrated higher values of Young’s modulus, elongation at break and tensile strength. Incubation of composite materials in model buffer solutions for 30 weeks More >

  • Open Access

    ARTICLE

    Thermally Reversible, Self-Healing Polyurethane Based on Propyl Gallate and Polyurethane Prepolymers with Varied Isocyanate Content

    Haiyang Ding1,2,3,4,5, Xiaohua Yang1,2,3,4,5, Lina Xu1,2,3,4,5, Shouhai Li1,2,3,4,5, Jianling Xia1,2,3,4,5, Mei Li1,2,3,4,5,*

    Journal of Renewable Materials, Vol.8, No.1, pp. 1-11, 2020, DOI:10.32604/jrm.2020.08165 - 01 January 2020

    Abstract Thermosetting polyurethanes are widely used in various fields owing to their excellent elasticity, strength and solvent resistance. Three environmental friendly propyl gallate-based self-healing polyurethanes were prepared from polyurethane prepolymers with varying isocyanate content. The thermal stabilities of the polyurethanes were tested using thermogravimetric analysis. Their self-healing and mechanical properties were analyzed using a universal testing machine and dynamic thermomechanical analysis. The polyurethanes were found with high self-healing ability and excellent mechanical properties due to the absence of phenolic carbamate. These qualities improved with increased isocyanate content and the prolonged selfhealing time. We found, therefore, that More >

  • Open Access

    ARTICLE

    Synthesis of Functional Photoactive Polysilane Copolymers with Disperse Yellow 7 Methacrylate and Study of their Optical, Photophysical and Thermal Properties

    KM. MEENU, DIBYENDU S. BAG*, REKHA LAGARKHAa

    Journal of Polymer Materials, Vol.36, No.3, pp. 275-292, 2019, DOI:10.32381/JPM.2019.36.03.7

    Abstract Functional photoactive polysilane copolymers of poly(methylphenylsilane) (PMPS) and disperse yellow 7 methacrylate (DY7MA) were synthesized using UV-technique. In the same manner functional polysilane copolymers of poly(methylphenylsilane-co-dimethylsilane) (CPS) and disperse yellow 7 methacrylate (DY7MA) were also synthesized. By the UV irradiation polysilanes (PMPS and CPS) give rise to silyl macroradicals which initiate the polymerization of photoactive monomer (DY7MA). The synthesized samples were characterized by FTIR, NMR, and UV-Vis spectroscopy. The molar mass of synthesized photoactive functional polysilane copolymers is of order of 103 gm/mol. They exhibited multimodal optical and photoluminescence functional properties. Optical absorbance was observed… More >

  • Open Access

    ARTICLE

    Novel Sugar Based Acrylate: Synthesis, Characterization and Polymerization

    MERYEM KORUYUCUa, FEHMi SALTANa,b, GÖKHAN KÖKa, HAKAN AKATa, YEŞIM SALMANa,*

    Journal of Polymer Materials, Vol.36, No.3, pp. 207-216, 2019, DOI:10.32381/JPM.2019.36.03.1

    Abstract The present study has demonstrated that novel acrylic glycopolymers are successfully prepared by using monosaccharides containing an acrylate group (9-12). For this purpose, sugar based acrylate monomers were synthesized via ring opening method (Method B) and homopolymerization of this sugar oxypropylacrylates was performed using free radical polymerization. The characterization of all the monomers and polymers were verified by 1HNMR, 13CNMR, FTIR and GPC techniques. The Glass transition temperatures and thermal characteristics of the polymers were also analyzed by using DSC and TG techniques. The thermal stability of prepared polymers have changed with the stereochemistry of the More >

  • Open Access

    REVIEW

    Recent Advancement in Comb-like Polymers: A Review

    AMRITA SHARMA, P. P. PANDE

    Journal of Polymer Materials, Vol.36, No.2, pp. 175-194, 2019, DOI:10.32381/JPM.2019.36.02.6

    Abstract ‘Comb-like polymers’ are a special class of polymers. These are consisting of two types of chains, first one is the backbone chain and second is long side chains. The structure of such a polymer is very similar to hair comb. Usually, every monomer unit in the backbone has a long n-alkyl side chain. Comb like polymers have an intrinsic ability towards forming ordered structure. Now-a-days, these polymers find wide range of applications because of their excellent physicochemical properties. Some applications are in preparation of polysoaps (polymeric disinfectants), as dispersing agent for ink and paints, textile More >

  • Open Access

    ARTICLE

    Systematically Monitoring, Relational Database and Technology Roadmapping for Trends and Innovation Opportunities in Biopolymers

    Selma B. Jaconis1,*, Augusto T. Morita2, Paulo L. A. Coutinho3, Suzana Borschiver1

    Journal of Renewable Materials, Vol.7, No.11, pp. 1221-1230, 2019, DOI:10.32604/jrm.2019.00025 - 14 July 2021

    Abstract In recent years environmental and sustainability concerns have impacted the global chemical industry and instituted a rush to produce products from renewable raw materials. This dynamic, complex and turbulent organizational scenario, around themes touching on the issue of sustainable development model, was created involving a large number of different actors: chemical/petrochemical industries, agroindustry companies, oil/gas companies, brand owners and end users, biotechnology startups, governments, universities and society. This paper proposed the application of a structured and dynamic method of technological prediction for biopolymers in three levels: systematic monitoring process, relational database and the “alive” Technology More >

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