R. S. Ali^a,*, H. S. Rasheed^b, N. D. Abdulameer^c, N. F. Habubi^d, S. S. Chiad^b

Chalcogenide Letters, Vol.20, No.3, pp. 187-196, 2023, DOI:10.15251/CL.2023.203.187

Abstract Chemical spray pyrolysis (CSP) was utilized to create pure Zinc Sulfide (ZnS) and magnesium (Mg) doped thin films on a clean glass substrate at a temperature equal to 400°C. X-ray diffraction test revealed a cubic wurtzite crystal structure with average crystallite sizes of 10.99 and 12.27 nm for ZnS and ZnS: Mg, respectively. XRD analysis of the doped films revealed a polycrystalline structure with a predominant peak along the (220) plane and additional peaks along the (111), (200), and (222) planes. The grain size raised from 10.99 to 12.27 nm as a result of the More >

R. Daira^a,*, B. Boudjemaa^b, A. Mohammedi^c

Chalcogenide Letters, Vol.20, No.4, pp. 277-284, 2023, DOI:10.15251/CL.2023.204.277

Abstract In this work, CuO thin films about the synthesis of the thin films are prepared on glass substrate using spray pyrolysis technique at room temperature different annealing times in temperature 450 0 C.In order to study the effect of annealing times onthe structural, optical and electrical properties.XRD analysis has shown that films with a polycrystalline structurehave a(Monoclinic) structure.In addition, the crystallite phase CuO increases with increasing of annealing temperature.Moreover, with a preferred orientation along (002) peak.The optical properties confirmed that the elaborated films have a transmittance of 70%. We have found that the band gap More >

A. Gahtar^a,*, C. Zaouche^b, A. Ammari^c,d, L. Dahbi^e

Chalcogenide Letters, Vol.20, No.5, pp. 377-385, 2023, DOI:10.15251/CL.2023.205.377

Abstract In this work, the bimetallic (Ni,Co) sulfide film of 852.213 nm thickness was successfully deposited using the spray pyrolysis technique at 300 °C. The compound was prepared with a mixture of nickel acetate (C₄H₆O₄Ni. 4H₂O), cobalt chloride (CoCl₂. 6H₂O), and thiourea (CS(NH₂)₂) as precursors for Ni, Co, and S, respectively. The temperature and sedimentation time were 300 °C and 10 min, respectively; the film was then, characterized without any thermal post-treatment. The structural, morphological, optical and electrical analysis were carried out to investigate the different properties of the material. The X-ray diffraction analysis confirmed the presence of NiCo₂S₄… More >

Z. Hadef^a,*, K. Kamli^a, O. Kamli^b, S. Labiod^a

Chalcogenide Letters, Vol.20, No.8, pp. 587-597, 2023, DOI:10.15251/CL.2023.208.587

Abstract Ultrasonic Spray Pyrolysis (USP) was used to deposited Co doped SnS₂ thin films on a glass substrate at different substrate temperatures (Ts = 350 °C, 375 °C, 400 °C, and 425 °C). DRX patterns shows that the synthesized films revealed a pure SnS2 phase with hexagonal structure. The mean crystalline grain sizes were showed an increasing– decreasing trend between 15.67 and 29.84 nm with an increment in the substrate temperature. The SEM images were significantly affected by the substrate temperature. Also, the optical band gap increases from 2.62 to 3.00 eV with the substrate temperatures increasing. More >

D. Dekhil^a,*, H. Guessas^a, A. Nouri^a, S. Ullah^b

Chalcogenide Letters, Vol.20, No.8, pp. 549-558, 2023, DOI:10.15251/CL.2023.208.549

Abstract SnS thin films were synthesized using the spray pyrolysis method and then annealed at 350, 400, and 450°C. According to the crystallographic analysis, the obtained SnS thin films crystallized in the polycrystalline orthorhombic system. The grains measured 47, 66, and 37 nm for the samples annealed at 350, 400, and 450°C, respectively. SEM and AFM images indicate that the samples’ surfaces were completely covered. Thus, the grains of SnS nanostructures have a granular-like shape and vary in size depending on the annealing temperatures. The transmittance measurement shows that annealing the sample at 400 °C extends… More >

J. M. Al Abbas^a,*, L. Al Taan^a, M. M. Uonis^b

Chalcogenide Letters, Vol.20, No.12, pp. 883-890, 2023, DOI:10.15251/CL.2023.2012.883

Abstract In this work, cadmium selenide (CdSe) thin films were deposited successfully by spray pyrolysis at different substrate temperatures. The influence of the preparation technique on the optical, morphological, and structural properties of the different substrate temperature CdSe films were investigated by using X-ray diffraction (XRD), scanning electron microscopy (SEM), and UV-Visible optical transmission. The XRD analysis reveals that CdSe thin film has hexagonal (wurtzite) and (cubic) crystal structures with different particle sizes depending on the substrate temperature. The SEM image shows uniform and adherent crystals. The optical energy gap was found to be in the More >

Hamdi Hachicha^1,2, Mamadou Dia², Hassine Bouafif², Ahmed Koubaa¹, Mohamed Khlif³, Flavia Lega Braghiroli^1,*

Journal of Renewable Materials, Vol.11, No.11, pp. 3807-3829, 2023, DOI:10.32604/jrm.2023.029454 - 31 October 2023

Abstract Reconstituted wood panels have several advantages in terms of ease of manufacturing, but their shorter life span results in a huge amount of reconstituted wood panels being discarded in sorting centers yearly. Currently, the most common approach for dealing with this waste is incineration. In this study, reconstituted wood panels were converted into activated biochar through a two-step thermochemical process: (i) biochar production using pilot scale fast pyrolysis at 250 kg/h and 450°C; and (ii) a physical activation at three temperatures (750°C, 850°C and 950°C) using an in-house activation furnace (1 kg/h). Results showed that… More > Graphic Abstract

Qianhao Ye¹, Mingjie Li¹, Jingyuan Hao¹, Zibo Huang¹, Jinjia Wei^1,*

The International Conference on Computational & Experimental Engineering and Sciences, Vol.25, No.4, pp. 1-1, 2023, DOI:10.32604/icces.2023.08826

Abstract The macroscopic tar-rich coal in-situ pyrolysis (TCISP) multi-physics simulation is conducted, in the fractured porous zone, by coupling heat transfer, fluid flow, and chemical reaction. A novel TCISP pattern of gas injection between fractured zones is proposed, by treating the fractured porous zone as a homogeneous porosity gradient descending region. In this case, nearly 11500 kg of oil can be produced within 6 months from a 10*10*1 m3 area. The influence of the fractured zone and porosity are investigated. Results indicated that gas injection between fractured zones is more conducive to rapid production, compared with More >

Jiapeng Wang¹, Bo Zhang^1,*, Haoqiang Cheng¹, Zhixiang Xu²

Journal of Renewable Materials, Vol.11, No.10, pp. 3595-3612, 2023, DOI:10.32604/jrm.2023.030005 - 10 August 2023

Abstract A new method of pretreatment of corn straw with Phanerochaete chrysosporium combined with pyrolysis was proposed to improve the quality of bio-oil. The characterization results demonstrated that microbial pretreatment was an effective method to decrease the lignin, which can achieve a maximum removal rate of 44.19%. Due to the destruction of biomass structure, the content of alkali metal and alkaline earth metal is reduced. Meanwhile, the depolymerized biomass structure created better pyrolysis conditions to promote the pyrolysis efficiency, increase the average decomposition rate of pyrolysis and reduce the residue. In fast pyrolysis, because of the enrichment… More > Graphic Abstract

Danyang Shao¹, Xiaojia Wang^1,*, Delu Chen¹, Fengxia An^1,2

Journal of Renewable Materials, Vol.11, No.10, pp. 3659-3680, 2023, DOI:10.32604/jrm.2023.029220 - 10 August 2023

Abstract Methanation is an effective way to efficiently utilize product gas generated from the pyrolysis and gasification of organic solid wastes. To deeply study the heat transfer and mass transfer mechanisms in the reactor, a successful three-dimensional comprehensive model has been established. Multiphase flow behavior and heat transfer mechanisms were investigated under reference working conditions. Temperature is determined by the heat release of the reaction and the heat transfer of the gas-solid flow. The maximum temperature can reach 951 K where the catalyst gathers. In the simulation, changes in the gas inlet velocity and catalyst flow… More >