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Probing Electrified Ionic Liquid-Solid Interface Using Long-Needle AFM
Pengcheng Nie1,2, Xikai Jiang1, Xu Zheng1, Dongshi Guan1,2,*
1 State Key Laboratory of Nonlinear Mechanics, Institute of Mechanics, Chinese Academy of Sciences, Beijing, 100190,
China
2 School of Engineering Science, University of Chinese Academy of Sciences, Beijing, 100049, China
* Corresponding Author: Dongshi Guan. Email:
The International Conference on Computational & Experimental Engineering and Sciences 2023, 25(1), 1-2. https://doi.org/10.32604/icces.2023.09838
Abstract
“How can we measure interface phenomena on the microscopic level” is a fundamental question that has
been with us for many years and is also listed in recent Science 125 question. It is even harder to explore
the electrified interface. In this work, we report atomic-force-microscope measurements of interfacial
dynamics of an electrified room-temperature ionic liquid (RTIL)-solid interface. RTILs are intriguing fluids
that have drawn much attention in applications ranging from tribology and catalysis to energy storage. With
strong electrostatic interaction between ions, their interfacial behaviors can be modulated by controlling
energetics of the electrified interface. Using a unique long-needle AFM technique [1-4], we measure contact
angle hysteresis (CAH) of a circular contact line formed on a micron-sized fiber, which is coated with a thin
layer of conductive film and intersects a RTIL-air interface. The measured CAH shows a distinct transition
by increasing the voltage applied on the fiber surface. Molecular dynamics simulations were performed to
illustrate variations of the solid-like layer in the RTIL adsorbed at the electrified interface. The integrated
experiments and computations demonstrate a new mechanism to manipulate the CAH by rearrangement of
interfacial layers of RTILs induced by the surface energetics.
Keywords
Cite This Article
APA Style
Nie, P., Jiang, X., Zheng, X., Guan, D. (2023). Probing electrified ionic liquid-solid interface using long-needle AFM. The International Conference on Computational & Experimental Engineering and Sciences, 25(1), 1-2. https://doi.org/10.32604/icces.2023.09838
Vancouver Style
Nie P, Jiang X, Zheng X, Guan D. Probing electrified ionic liquid-solid interface using long-needle AFM. Int Conf Comput Exp Eng Sciences . 2023;25(1):1-2 https://doi.org/10.32604/icces.2023.09838
IEEE Style
P. Nie, X. Jiang, X. Zheng, and D. Guan "Probing Electrified Ionic Liquid-Solid Interface Using Long-Needle AFM," Int. Conf. Comput. Exp. Eng. Sciences , vol. 25, no. 1, pp. 1-2. 2023. https://doi.org/10.32604/icces.2023.09838