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Gas Transport Through Nanochannels: Surface Effect and Molecular Geometry Effect
JianHao Qian1, HengAn Wu1, FengChao Wang1,*
1 CAS Key Laboratory of Mechanical Behavior and Design of Materials, Department of Modern Mechanics, University of
Science and Technology of China, Hefei, 230027, China
* Corresponding Author: FengChao Wang. Email:
The International Conference on Computational & Experimental Engineering and Sciences 2023, 26(4), 1-2. https://doi.org/10.32604/icces.2023.09144
Abstract
Gas transport through nanochannels is ubiquitous in nature and also plays an important role in industry.
The gas flow in this regime can be described by the Knudsen theory, which assumes that molecules diffusely
reflect on the confining walls [1]. However, with the emergence of low dimensional carbon-based materials
such as graphene and carbon nanotubes, it has been evidenced that this assumption might not hold for some
atomically smooth surfaces, resulting in an anomalous enhancement of gas flux [2]. Moreover, in Knudsen
theory, gas molecules are usually treated as mass points and distinguished solely by molecular weight, which
cannot interpret recent experiments that gases with similar molecular weight exhibit a remarkable
difference in the flow rate [3]. In this talk, I will present our recent research progress in this field. We
meticulously investigated the gas transport through nanochannels. For the enhancement of gas flux through
nanochannels with atomically smooth walls, we revealed the underlying mechanism as the surface
morphological effect on the gas collision with solid walls [4]. Even a subtle distinction of surface roughness
results in specular scattering on graphene surfaces while diffuse scattering on molybdenum disulfide
surfaces. We found that the curvature effect could reduce the surface roughness of interaction potential
surfaces, leading to an additional enhancement on the gas flow rate. We also ascertain the molecular
geometry effect on the transport of various gases through nanochannels [5]. Gas molecules with a complex
geometry are more likely to experience multiple reflections on the surface, leading to the diffuse scattering
and a reduced flux. During the collision, only the normal translational kinetic energy acts as a positive
contribution to the successful reflection, while the vibrational, rotational and tangential translational kinetic
energies are all ineffective in this process. The ratio of this ineffective energy to the initial kinetic energy is
suggested as the criterion whether the gas can disengage from the wall after each collision. These insights
are expected to deepen the understanding of gas transport in nanochannels, paving a promising way in the
gas permeation control. Our work also offers a new perspective to extend Knudsen theory for broader
applications.
Keywords
Cite This Article
APA Style
Qian, J., Wu, H., Wang, F. (2023). Gas transport through nanochannels: surface effect and molecular geometry effect. The International Conference on Computational & Experimental Engineering and Sciences, 26(4), 1-2. https://doi.org/10.32604/icces.2023.09144
Vancouver Style
Qian J, Wu H, Wang F. Gas transport through nanochannels: surface effect and molecular geometry effect. Int Conf Comput Exp Eng Sciences . 2023;26(4):1-2 https://doi.org/10.32604/icces.2023.09144
IEEE Style
J. Qian, H. Wu, and F. Wang "Gas Transport Through Nanochannels: Surface Effect and Molecular Geometry Effect," Int. Conf. Comput. Exp. Eng. Sciences , vol. 26, no. 4, pp. 1-2. 2023. https://doi.org/10.32604/icces.2023.09144