Table of Content

Open Access iconOpen Access

ARTICLE

Synthesis and Characterization of Poly(N-(3- (hexylamino)-N-(3-(isopropylamino)-3- oxopropyl)acrylamide) Homopolymer

ARCHANA KUMARI, KHEYANATH MITRA, SAMBHAV VISHWAKARMA, SOUROV MONDAL, SHIKHA SINGH, RAJSHREE SINGH, JAYDEEP SINGH, BISWAJIT MAITI, SUSANTA KUMAR SEN GUPTA, BISWAJIT RAY*

Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi- 221005, India

* Corresponding Author: e-mail: email

Journal of Polymer Materials 2020, 37(3-4), 143-164. https://doi.org/10.32381/JPM.2020.37.3-4.3

Abstract

A new acrylamide monomer N-(3-(hexylamino)-N-(3-(isopropylamino)-3-oxopropyl) acrylamide (HA-NIPAM-AM) and a new RAFT agent O-propionyl-2-(N,N-diphenylcarbamothioylthio) propanoate have successfully been synthesized and used for the synthesis of poly(HA-NIPAM-AM) homopolymers via RAFT polymerization. The formed homopolymers have been characterized by GPC, 1 H NMR, FTIR, contact angle measurement, TG-DTA, DSC, and PXRD. Numberaveragemolar masses of the prepared polymers are in the range of 2,500 – 11,500 g/mol. Selfassembly of homopolymer has been studied viacmc determination in water using pyrene as fluorescence probe, HRTEM and DLS. Polymeris thermally stable up to 300 °C and has a glass transition temperature at 85.3 °C. XRD study reveals the presence of nanophases in the polymer matrix. DFT calculation has revealed a helical backbone structure with the pendant groups exposed to inwards and outwards, respectively.

Keywords


Cite This Article

APA Style
KUMARI, A., MITRA, K., VISHWAKARMA, S., MONDAL, S., SINGH, S. et al. (2020). Synthesis and characterization of poly(n-(3- (hexylamino)-n-(3-(isopropylamino)-3- oxopropyl)acrylamide) homopolymer. Journal of Polymer Materials, 37(3-4), 143-164. https://doi.org/10.32381/JPM.2020.37.3-4.3
Vancouver Style
KUMARI A, MITRA K, VISHWAKARMA S, MONDAL S, SINGH S, SINGH R, et al. Synthesis and characterization of poly(n-(3- (hexylamino)-n-(3-(isopropylamino)-3- oxopropyl)acrylamide) homopolymer. J Polym Materials . 2020;37(3-4):143-164 https://doi.org/10.32381/JPM.2020.37.3-4.3
IEEE Style
A. KUMARI et al., "Synthesis and Characterization of Poly(N-(3- (hexylamino)-N-(3-(isopropylamino)-3- oxopropyl)acrylamide) Homopolymer," J. Polym. Materials , vol. 37, no. 3-4, pp. 143-164. 2020. https://doi.org/10.32381/JPM.2020.37.3-4.3



cc This work is licensed under a Creative Commons Attribution 4.0 International License , which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
  • 49

    View

  • 46

    Download

  • 0

    Like

Share Link