Open Access
ARTICLE
Renewable Resource-Based Hybrid Crosslinker for Sustainable Industrial Coatings
Dinesh Balgude, Anagha Sabnis*
Department of Polymer and Surface Engineering, Institute of Chemical Technology, Nathalal Parekh Marg, Matunga (E),
Mumbai-400019, Maharashtra, India
* Corresponding Author:
Journal of Renewable Materials 2014, 2(3), 235-245. https://doi.org/10.7569/JRM.2014.634115
Received 12 April 2014; Accepted 17 July 2014;
Abstract
Renewable resource-based hybrid crosslinker was successfully synthesized via sol-gel technology. The
synthesis involved malenization of Cashew Nut Shell Liquid (CNSL) followed by its silane modifi cation and
subsequent hydrolysis and condensation with tetraethyl orthosilicate (TEOS). The synthesized crosslinker was
characterized by spectroscopic analysis (FT-IR,
1
H-NMR,
13C-NMR and
29Si-NMR) for structural elucidation.
The crosslinker was further formulated in a conventional stoving system. Fully-cured coatings were obtained
after stoving at 120°C for ½ hr and were then evaluated for physical, mechanical, chemical, optical, accelerated
weathering, electrochemical and morphological properties. The incorporation of hybrid crosslinker in a
conventional stoving system was observed to improve overall coating properties. The excellent properties
can be attributed to the combination of an aliphatic chain of CNSL and siloxane (-Si-O-Si-) moieties within the
coating, resulting in good balance of fl exible and dense structure which would take care of load distribution
properties and penetration of corrosive chemicals through coatings.
Keywords
Cite This Article
Balgude, D., Sabnis, A. (2014). Renewable Resource-Based Hybrid Crosslinker for Sustainable Industrial Coatings.
Journal of Renewable Materials, 2(3), 235–245. https://doi.org/10.7569/JRM.2014.634115