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  • Open Access

    ARTICLE

    Role of Calcination Temperature on Isosorbide Production from Sorbitol Dehydration over the Catalyst Derived from Ce(IV) Sulfate

    Medta Boupan1,2, Kanyapak Prompang1, Achiraya Chompunuch1, Piwat Boonma1, Arthit Neramittagapong1,2,3,4, Somnuk Theerakulpisut5, Sutasinee Neramittagapong1,2,3,*

    Journal of Renewable Materials, Vol.11, No.7, pp. 2985-3000, 2023, DOI:10.32604/jrm.2023.026397

    Abstract Isosorbide is a multi-purpose chemical that can be produced from renewable resources. Specifically, it has been investigated as a replacement for toxic bisphenol A (BPA) in the production of polycarbonate (PC). In this study, the synthesis of isosorbide by sorbitol dehydration using a cerium-based catalyst derived from calcined cerium (IV) sulfate (300°C, 400°C, 450°C, 500°C, and 650°C) was investigated. The reaction occurred in a high-pressure reactor containing nitrogen gas. Advanced instrumental techniques were applied to analyze the characteristics of the calcined catalyst. The results showed that the calcined catalysts demonstrated different crystalline structures and sulfate species at different temperatures. However,… More > Graphic Abstract

    Role of Calcination Temperature on Isosorbide Production from Sorbitol Dehydration over the Catalyst Derived from Ce(IV) Sulfate

  • Open Access

    REVIEW

    Low Altitude Satellite Constellation for Futuristic Aerial-Ground Communications

    Saifur Rahman Sabuj1, Mohammad Saadman Alam2, Majumder Haider2, Md Akbar Hossain3, Al-Sakib Khan Pathan4,*

    CMES-Computer Modeling in Engineering & Sciences, Vol.136, No.2, pp. 1053-1089, 2023, DOI:10.32604/cmes.2023.024078

    Abstract This paper discusses the significance and prospects of low altitude small satellite aerial vehicles to ensure smooth aerial-ground communications for next-generation broadband networks. To achieve the generic goals of fifthgeneration and beyond wireless networks, the existing aerial network architecture needs to be revisited. The detailed architecture of low altitude aerial networks and the challenges in resource management have been illustrated in this paper. Moreover, we have studied the coordination between promising communication technologies and low altitude aerial networks to provide robust network coverage. We talk about the techniques that can ensure userfriendly control and monitoring of the low altitude aerial… More > Graphic Abstract

    Low Altitude Satellite Constellation for Futuristic Aerial-Ground Communications

  • Open Access

    ARTICLE

    Improved Beam Steering Method Using OAM Waves

    Nidal Qasem*, Ahmad Alamayreh

    Computer Systems Science and Engineering, Vol.46, No.1, pp. 417-431, 2023, DOI:10.32604/csse.2023.035603

    Abstract Orbital Angular Momentum (OAM) is an intrinsic feature of electromagnetic waves which has recently found many applications in several areas in radio and optics. In this paper, we use OAM wave characteristics to present a simple method for beam steering over both elevation and azimuth planes. The design overcomes some limitations of traditional steering methods, such as limited dynamic range of steering, the design complexity, bulky size of the steering structure, the limited bandwidth of operation, and low gain. Based on OAM wave characteristics, the proposed steering method avoids design complexities by adopting a simple method for generating the OAM-carrying… More >

  • Open Access

    CASE REPORT

    Multiple Recurrence of Primary Orbital Synovial Sarcoma: Report of Two Cases and Literature Review

    Yi Wu, Yujiao Wang, Weimin He*

    Oncologie, Vol.24, No.4, pp. 927-935, 2022, DOI:10.32604/oncologie.2022.026720

    Abstract Synovial sarcoma (SS) is typically an aggressive malignant soft tissue tumor that mostly affects adolescents and young adults. It is extremely rare in orbit and carries a high risk of recurrence and metastasis, posing a challenge to ophthalmologists in diagnosing and managing. We present two primary orbital synovial sarcoma cases with unilateral exophthalmos and limited motility. Both male patients underwent reoperation in our hospital since tumor recurrence; the pathologic diagnoses were biphasic type and occult type, respectively. Both cases were positive for EMA and CK, and SOX-9 and INI-1 were newly discovered immune markers. Fluorescence in situ hybridization analysis (FISH)… More >

  • Open Access

    ARTICLE

    Generation of OAM Waves and Analysis of Mode Purity for 5G Sub-6 GHz Applications

    Shehab Khan Noor1, Arif Mawardi Ismail1, Mohd Najib Mohd Yasin1,*, Mohamed Nasrun Osman1, Nurulazlina Ramli2, Ali H. Rambe3, J. Iqbal4,5

    CMC-Computers, Materials & Continua, Vol.74, No.1, pp. 2239-2259, 2023, DOI:10.32604/cmc.2023.031170

    Abstract This article presents the generation of Orbital Angular Momentum (OAM) vortex waves with mode 1 using Uniform Circular Array (UCA) antenna. Two different designs, namely, UCA-1 (4-element array antenna) and UCA-2 (8-element array antenna), were designed and fabricated using FR-4 substrate to generate OAM mode 1 at 3.5 GHz (5G mid-band). The proposed antenna arrays comprised rectangular microstrip patch elements with inset fed technique. The elements were excited by a carefully designed feeding phase shift network to provide similar output energy at output ports with desired phase shift value. The generated OAM waves were confirmed by measuring the null in… More >

  • Open Access

    ARTICLE

    DFT and TD-DFT Calculations of Orbital Energies and Photovoltaic Properties of Small Molecule Donor and Acceptor Materials Used in Organic Solar Cells

    Daniel Dodzi Yao Setsoafia1, Kiran Sreedhar Ram1, Hooman Mehdizadeh-Rad1,2, David Ompong1,2, Vinuthaa Murthy1,2, Jai Singh1,2,*

    Journal of Renewable Materials, Vol.10, No.10, pp. 2553-2567, 2022, DOI:10.32604/jrm.2022.020967

    Abstract DFT and TD-DFT calculations of HOMO and LUMO energies and photovoltaic properties are carried out on four selected pentathiophene donor and one IDIC-4F acceptor molecules using B3LYP and PBE0 functionals for the ground state energy calculations and CAM-B3LYP functional for the excited state calculations. The discrepancy between the calculated and experimental energies is reduced by correlating them with a linear fit. The fitted energies of HOMO and LUMO are used to calculate the Voc of an OSC based on these donors and acceptor blend and compared with experimental values. Using the Scharber model the calculated PCE of the donor-acceptor molecules… More >

  • Open Access

    REVIEW

    Biomedical overview of melanin. 2. Updating molecular modeling, synthesis mechanism, and supramolecular properties regarding melanoma therapy

    JUAN CARLOS STOCKERT1,2,*, ALFONSO BLÁZQUEZ-CASTRO3

    BIOCELL, Vol.46, No.6, pp. 1391-1415, 2022, DOI:10.32604/biocell.2022.019493

    Abstract

    Melanins represent one of the most ancient and important group of natural macromolecular pigments. They have multiple biological roles in almost all organisms across the Phyla, examples being photoprotection, anti-oxidative action, radical scavenger activity, and heavy metal removal. From the biomedical point of view, melanocytes are involved in the origin of melanoma tumors, and the main therapeutic advances for their treatment have been revised in Part 1 of this review. The chemical structure of eumelanin is a biological concern of great importance, and therefore, exploring theoretical molecular models and synthesis mechanisms will be here described, as well as molecular orbital… More >

  • Open Access

    ARTICLE

    The Intelligent Trajectory Optimization of Multistage Rocket with Gauss Pseudo-Spectral Method

    Lihua Zhu1,*, Yu Wang1, Zhiqiang Wu1, Cheire Cheng2

    Intelligent Automation & Soft Computing, Vol.33, No.1, pp. 291-303, 2022, DOI:10.32604/iasc.2022.024252

    Abstract The rapid developments of artificial intelligence in the last decade are influencing aerospace engineering to a great extent and research in this context is proliferating. In this paper, the trajectory optimization of a three-stage launch vehicle in the powering phase subject to the sun-synchronous orbit is considered. To solve the optimal control problem, the Gauss pseudo-spectral method (GPM) is used to transform the optimization model to a nonlinear programming (NLP) problem and sequential quadratic programming is applied to find the optimal solution. However, the sensitivity of the initial guess may cost the solver significant time to do the Newton iteration… More >

  • Open Access

    ARTICLE

    Method for Collision Avoidance in Spacecraft Rendezvous Problems with Space Objects in a Phasing Orbit

    Danhe Chen1,*, A. A. Baranov2, Chuangge Wang1, M. O. Karatunov3, N. Yu. Makarov3

    CMES-Computer Modeling in Engineering & Sciences, Vol.127, No.3, pp. 977-991, 2021, DOI:10.32604/cmes.2021.014662

    Abstract As the number of space objects (SO) increases, collision avoidance problem in the rendezvous tasks or re-constellation of satellites with SO has been paid more attention, and the dangerous area of a possible collision should be derived. In this paper, a maneuvering method is proposed for avoiding collision with a space debris object in the phasing orbit of the initial optimal solution. Accordingly, based on the plane of eccentricity vector components, relevant dangerous area which is bounded by two parallel lines is formulated. The axises of eccentricity vector system pass through the end of eccentricity vector of phasing orbit in… More >

  • Open Access

    ARTICLE

    Practical Optimization of Low-Thrust Minimum-Time Orbital Rendezvous in Sun-Synchronous Orbits

    Jian Ma1,2, Changxuan Wen3, Chen Zhang2,*

    CMES-Computer Modeling in Engineering & Sciences, Vol.126, No.2, pp. 617-644, 2021, DOI:10.32604/cmes.2021.014474

    Abstract High-specific-impulse electric propulsion technology is promising for future space robotic debris removal in sun-synchronous orbits. Such a prospect involves solving a class of challenging problems of low-thrust orbital rendezvous between an active spacecraft and a free-flying debris. This study focuses on computing optimal low-thrust minimum-time many-revolution trajectories, considering the effects of the Earth oblateness perturbations and null thrust in Earth shadow. Firstly, a set of mean-element orbital dynamic equations of a chaser (spacecraft) and a target (debris) are derived by using the orbital averaging technique, and specifically a slow-changing state of the mean longitude difference is proposed to accommodate to… More >

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