S. Saleem^a, U. Parveen^a, H. AL-Ghamdi^b,*, M. Yaseen^a, I. Sajjad^a, Nasarullah^a

Chalcogenide Letters, Vol.22, No.3, pp. 223-237, 2025, DOI:10.15251/CL.2025.223.223

Abstract Present research reveals the doping effect on physical properties of Sr_1-xFe_xS by employing ab-initio calculations. The negative formation energy and optimization outcomes exhibit the stability of the Sr_1-xFe_xS alloys with ferromagnetic phase. Spin dependent band structure (BS) and density of states (DOS) interpret that Sr_1-xFe_xS revealed half metallic ferromagnetic (HMF) nature at 6.25% and 12.5% of Fe doping while metallic character is revealed at 25% concentration of dopant. Spin-up state of Sr_0.9375Fe_0.0625S and Sr_0.8750Fe_0.1250S depicts semiconductive behavior with bandgap value of 2.01/2.33 eV, correspondingly, while metallic in spin-down channel. The magnetism in the system is mainly originated because… More >

S. Çelik^a,*, M. Temiz^b

Chalcogenide Letters, Vol.22, No.1, pp. 89-96, 2025, DOI:10.15251/CL.2025.221.89

Abstract In this study, PbZnS thin films with varying concentrations of lead (Pb) and zinc (Zn) were successfully produced using the spray pyrolysis method. The structural, optical and surface properties of the films were systematically investigated as a function of the Pb/Zn ratio. Xray diffraction (XRD) analysis confirmed the polycrystalline nature of the films, showing a cubic zinc blende structure with improved crystallinity as Pb content increased. Initially, with the increase in Pb concentration, larger crystallite sizes and decreased microstress were observed, but with the increase of Pb addition, the formation of secondary phases and the… More >

A. G. Kumar^a,*, V. K. V. Krishna^b, A. P. Lingaswamy^c, S. Masma^d, G. Prathibha^e, G. Sujatha^f, P. S. Kumar^g, T. V. Kumar^h, J. V. V. N. K. Raoⁱ, B. H. Rao^a

Chalcogenide Letters, Vol.22, No.2, pp. 143-149, 2025, DOI:10.15251/CL.2025.222.143

Abstract SnS thin films doped with two atomic % Ag are deposited on a pyrex glass substrates using chemical bath deposition method. The impact of 2 atomic % silver doping on the physical properties of SnS thin films is studied. X-ray diffraction studies confirmed that the deposited SnS films were of α-SnS phase with an orthorhombic crystal structure, which remained stable despite the addition of 2 at.% silver. It is observed that the addition of 2 atomic % silver to SnS chemical bath solution does not greatly influence the structural properties of SnS thin film. The More >

J. H. Azzawi^a, Yaseen A. Al-Zahraa^b, M. A. Abdulmajeed^c, K. A. Jasim^c, A. Muravitskaya^e, A. A. Al-Hamadani^d,e, A. H. Al-Dulaimi^d,e

Chalcogenide Letters, Vol.22, No.7, pp. 593-601, 2025, DOI:10.15251/CL.2025.227.593

Abstract Four Se₇₀Ge₂₀Sb₁₀ alloy samples were prepared using the melt quenching technique. To improve the energy states of the mobility gap, the samples were exposed to gamma radiation from 60Co source at various doses of 600, 1200, 1500, and 2000 Gy. The electrical characteristics were examined both before and after irradiation. The conductivity analysis revealed that all of our samples were impacted by gamma radiation. The reorganization of the amorphous lattice and the degree of radiation-induced disorder have been involved in the changes that occurred in the electrical characteristics of the irradiated samples. All irradiated and non-irradiated… More >

M. Abbas^a, M. Haseeb-u-Rehman^a, M. Sohail^b, G. H. Tariq^a,*

Chalcogenide Letters, Vol.22, No.7, pp. 561-577, 2025, DOI:10.15251/CL.2025.227.561

Abstract This work presents the fabrication of NiO thin films via versatile sol-gel spin coating method and investigation of annealing effects on their physical properties. After the deposition process, the NiO thin films underwent annealing process at different values of temperatures ranging from 200°C to 350°C for one hour duration. XRD patterns confirmed the polycrystalline nature, along the preferred orientations (110) and (101) planes. Nanoparticles in NiO thin films demonstrated an increase in crystallite size with rising annealing temperatures, reaching a maximum size of 49 nm at annealing temperature 300°C. FTIR patterns revealed Ni-O bands at… More >

Lekaa K. Abdul Karem¹, Badriah Saad Al-Farhan², Ghada M. G. Eldin³, Samir Kamel⁴, Ahmed M. Khalil^5,*

Journal of Renewable Materials, Vol.13, No.7, pp. 1459-1473, 2025, DOI:10.32604/jrm.2025.02025-0046 - 22 July 2025

Abstract In this study, the casting process is used to fabricate modified polyvinyl alcohol (PVA), starch (S), and carboxymethyl cellulose (CMC) polymer blend films (PVA/S/CMC) loaded with various concentrations of iron-doped carbon quantum dots (Fe-CQDs) and denoted as (PVA/S/CMC@Fe-CQDs). A one-step microwave strategy was employed as a facile method to prepare Fe-CQDs. Through a series of characterization techniques, fourier-transform infrared (FTIR) spectroscopy, x-ray diffraction (XRD) analysis, and scanning electron microscopy (SEM) have been used to show the successful integration of Fe-CQDs into the PVA/S/CMC matrix. Loading the synthesized Fe-CQDs to the polymeric matrix significantly enhanced the… More > Graphic Abstract

P. Chaiworn^a, S. Kaewja^a, E. Wongrat^b,c, C. Wichasilp^a, A. Tubtimtae^d,*

Chalcogenide Letters, Vol.21, No.5, pp. 423-429, 2024, DOI:10.15251/CL.2024.215.423

Abstract Bismuth antimony telluride (Bi_2-xSb_xTe₃) thin films were synthesized using chemical bath deposition (CBD) with various amounts of antimony. The structural, morphological, and optical properties of Bi_2-xSb_xTe₃ thin films have been scrutinized using X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), UV-Vis spectrophotometry. A higher amount of Sb contents can be observed the Sb_0.405Te_0.595, BiTe, and Bi₄Te₃ phases consisted in the pattern. Meanwhile, the energy band gaps are tuned in the range of 2.95 to 3.30 eV. Finally, measurement of resistance with various temperatures for activation energy (E_AC) estimation was performed. The highest E_AC value was equal to 0.654 More >

A. Ouahab^a,*, L. Boudaoud^a, N. Boudaoud^b, H. Bradai^a, N. Hachemi^a, S. Menezla^c, N. Bounefla^a

Chalcogenide Letters, Vol.21, No.7, pp. 529-541, 2024, DOI:10.15251/CL.2024.217.529

Abstract The structural and electronic properties of (CdS, CdSe, and CdTe) compounds in rock-salt, zinc-blend, and wurtzite crystal structures were calculated using ab initio calculation. In addition to these properties, the thermodynamic properties were added advantage to clarify their comportment as temperature variation. Under the context of density functional theory DFT, the calculations were carried out using the full potential linearized augmented plane wave FP-LAPW approach. The generalized gradient approximations GGA-PBE established by Perdew-Burke-Ernzerhof and the local density approximation LDA and modified Bucke Jhonson have both been employed for the exchange-correlation energy and related potential MBJ.… More >

M. Sudha^a,*, A. B. Madhan^b, M. Revathi^c

Chalcogenide Letters, Vol.21, No.10, pp. 841-845, 2024, DOI:10.15251/CL.2024.2110.841

Abstract Zinc sulfide thin films were prepared using the economical spray pyrolysis process. A thin film of exceptional quality with a temperature difference of 300 °C to 400 °C is produced by optimizing variables such as concentration, flow rate, and nozzle to substrate distance. These films' optical characteristics and structure were examined. The deposited thin films displayed a direct and allowed transition, as indicated by the optical transmittance spectra. XRD analysis confirmed that the deposited thin films were polycrystalline with a cubic phase. This film can be used in solar cell applications since the band gap More >

M. S. Tivanov^b,, T. M. Razykov^a, K. M. Kuchkarov^a,b,, A. N. Olimov^a, R. R. Khurramov^a, D. Z. Isakov^a, Z. A. Makhmudov^a, M. Pirimmetov^a, A. Nasirov^c, D. S. Bayko^b, O. V. Korolik^b

Chalcogenide Letters, Vol.21, No.10, pp. 819-828, 2024, DOI:10.15251/CL.2024.2110.819

Abstract Using the thermal evaporation method, thin crystalline films of Sb₂(S_xSe_1-x)₃ are produced at the substrate temperature of 300℃. The mixed powders of the Sb₂S₃ and Sb₂Se₃ is used as a source material. The influence of the S/Se component ratio on the morphology and structural characteristics of Sb₂(S_xSe_1-x)₃ thin films is investigated. As demonstrated by the results of X-ray energy dispersive spectroscopy, the formed films of Sb₂(S_xSe_1-x)₃ have a components ratio close to the stoichiometry. Besides, Morphological and structural analyses reveal significant differences in the surface morphology of Sb₂(S_xSe_1-x)₃ thin film absorbers, indicating that the properties of the films More >