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  • Open Access

    EDITORIAL

    Special Issue on “Biobased Construction Materials” in the Journal of Renewable Materials

    Journal of Renewable Materials, Vol.3, No.3, pp. 161-162, 2015, DOI:10.7569/JRM.2015.634113

    Abstract This article has no abstract. More >

  • Open Access

    ARTICLE

    Modeling Degradative Chain Transfer in d-Limonene/n-Butyl Methacrylate Free-Radical Copolymerization

    Yujie Zhang1, Marc A. Dubé1,*, Eduardo Vivaldo-Lima2

    Journal of Renewable Materials, Vol.3, No.4, pp. 318-326, 2015, DOI:10.7569/JRM.2015.634115

    Abstract Renewable monomers containing allylic C-H bonds in their structure are prone to degradative chain transfer in free-radical polymerization, which will dramatically decrease the polymerization rate. In order to understand this mechanism, a kinetic model incorporating a degradative chain transfer mechanism for the free-radical copolymerization of d-limonene (LIM) and n-butyl methacrylate (BMA) was developed using PREDICI. Model predictions offered insight on how degradative chain transfer reactions affect conversion, copolymer composition and molecular weight in the polymerization. Experimental data from copolymerizations at monomer feed compositions (LIM/BMA, mol/mol) of 10/90, 20/80 and 30/70 were compared to the model’s predictions. More >

  • Open Access

    ARTICLE

    Thermally and UV Stable Natural Dyes with Potential Use in Efficient Photoelectrochemical Devices

    Mario Alejandro Mejía Escobar*, Franklin Jaramillo*

    Journal of Renewable Materials, Vol.3, No.4, pp. 302-317, 2015, DOI:10.7569/JRM.2014.634121

    Abstract Energy alternatives have been one of the most important research focal areas of the last decade due to the imminent lack of fossil fuels. This motivation has allowed the evolution of the materials science field in areas such as electrochemistry, where high availability, low cost and negligible environmental impact are the desired principal qualities. For this reason, as an example of a photoelectrochemical device, we have proposed the use of natural dyes from 37 agro-industrial wastes in dye-sensitized solar cells. We obtained dyes from red cabbage, radish and roselle wastes with a good stability for More >

  • Open Access

    ARTICLE

    Tunable Hydrophilicity of Poly(ethyl lactate acrylate-coacrylic acid)

    M. Purushothaman1, P. Santhana Gopala Krishnan1,2,*, S. K. Nayak1,2

    Journal of Renewable Materials, Vol.3, No.4, pp. 292-301, 2015, DOI:10.7569/JRM.2015.634114

    Abstract Four copolymers of poly(ethyl lactate acrylate-co-acrylic acid) were prepared by the solution polymerization technique by varying the comonomer content from 0.2 to 0.8 mole percent. The copolymers were characterized by FT-IR, 1H-NMR and proton decoupled 13C-NMR spectroscopic techniques. The reactivity ratio of ethyl lactate acrylate (ELA) and acrylic acid (AA) was calculated using the Fineman-Ross method and the values were found to be 0.101 and 0.186, respectively, indicating the formation of an alternating copolymer. From the wide-angle X-ray diffraction studies (WAXD), the average molecular interchain spacing () was calculated from the 2θ value of amorphous halo at… More >

  • Open Access

    ARTICLE

    Natural Dyes Extraction, Stability and Application to Dye-Sensitized Solar Cells

    Mario Alejandro Mejía Escobar*, Frankin Jaramillo*

    Journal of Renewable Materials, Vol.3, No.4, pp. 281-291, 2015, DOI:10.7569/JRM.2014.634142

    Abstract In recent years, the development of new materials has contributed markedly to improving the efficiency of dye-sensitized solar cells (DSSCs). Mesoporous semiconductors, solid electrolyte, non-conventional catalysts and synthetic dyes without ruthenium have been the focus of study. With respect to the last, lanthanides and porphyrins have presented good properties, but these elements have the same disadvantage as rutheniumbased dyes; being complicated to synthesize and very expensive. These limitations have stimulated much research in the use of natural dyes as sensitizers due to their exceptional photoelectochemical properties and low cost. Furthermore, they are regarded as renewable More >

  • Open Access

    ARTICLE

    Synthesis of Polyamides and Their Copolymers via Enzymatic Polymerization

    Erythrina Stavila, Katja Loos*

    Journal of Renewable Materials, Vol.3, No.4, pp. 268-280, 2015, DOI:10.7569/JRM.2015.634102

    Abstract The selective and specific features of enzymes have drawn an enormous amount of attention for use as in-vitro catalysts in polymerization reactions. Various studies on the enzymatic synthesis of polyesters, polycarbonates, polysaccharides, polypeptides, and polyamides have been performed and some have been implemented on an industrial scale. Particularly in the synthesis of polyester and polyamides, lipases are the most used enzymes as catalysts for their polymerization. Polyamides are considered to be one of the largest engineering polymer families used in the automotive, electrical and electronics, and consumer goods industries; thus the enzymatic synthesis of polyamides will More >

  • Open Access

    ARTICLE

    Mechanical Characterization of Bamboo and Glass Fiber Biocomposite Laminates

    William Eberts, Matthew T. Siniawski*, Timothy Burdiak, Nick Polito

    Journal of Renewable Materials, Vol.3, No.4, pp. 259-267, 2015, DOI:10.7569/JRM.2014.634137

    Abstract Single-ply biocomposite laminates were fabricated with two different woven fabrics and a bio-based resin using a wet layup technique at room temperature. A highly elastic, stockinette weave bamboo fiber fabric and a thicker, inelastic plain weave bamboo fabric were both investigated. The elastic fabric was pre-strained at 25% intervals, ranging from 0–100% of its original length. Samples made with E-Glass and S-Glass, two common glass fiber reinforcements, were also fabricated using the bioresin as benchmarks. The ultimate strength and modulus of elasticity characteristics of the composites were determined using the ASTM D3039/ D3039M-08 standard test… More >

  • Open Access

    ARTICLE

    Growth of clonal modules on Agropyron michnoi in the Songnen Plain of Northeast China

    Zhang J1, C Zhou2, YF Yang1

    Phyton-International Journal of Experimental Botany, Vol.84, No.2, pp. 417-422, 2015, DOI:10.32604/phyton.2015.84.417

    Abstract Spatial expansion of clonal plants and growth of their modules are of concern in the field of plant ecology. After measuring a large number of samples, we analyzed the module components and the growth patterns of vegetatively propagated Agropyron michnoi clones in the Songnen Plain on Northeast China. The results showed that the plasticity of clonal growth was large; the coefficients of variation of both extensive areas and the quantitative characters of modules were more than 20%. The numbers of ramets, seedlings, and buds and the cumulative length of the rhizomes showed exponentially and linearly increasing More >

  • Open Access

    ARTICLE

    Anatomy of flower and fruit of Vassobia breviflora (Solanaceae) in the south of the southern Yungas (Argentina)

    Bernacki FG1, PL Albornoz1,2, M Valoy1, M Ordano1,3

    Phyton-International Journal of Experimental Botany, Vol.84, No.2, pp. 478-487, 2015, DOI:10.32604/phyton.2015.84.478

    Abstract Solanaceae is a family with nearly 2400 species of cosmopolitan distribution. Vassobia breviflora is the only species of the genus present in Argentina. The goal of this work was to review and characterize the anatomy of the flower and fruit of V. breviflora from samples collected in populations of Yungas in the argentine Northwest. Conventional anatomical techniques were applied. The results showed that most flower, fruit and seed structures did not differ from those previously reported regarding the structural organization described for other species of the Solanaceae family. However, for the first time, we described the androecium, More >

  • Open Access

    ARTICLE

    Leaf architecture characters of Vachellia tortilis (Forssk.) Galasso and Banfi along longitudinal gradient in Limpopo Province, South Africa

    Mashile SP1,2, MP Tshisikhawe1

    Phyton-International Journal of Experimental Botany, Vol.84, No.2, pp. 473-477, 2015, DOI:10.32604/phyton.2015.84.473

    Abstract This paper looked at the leaf architecture characteristics of Vachellia tortilis to determine if either there is or not an effect of the tropic line on plants. Vachellia tortilis leaves were sampled along a national road (N1) in Limpopo province. Sampling points were set 10 km apart away from the Tropic of Capricon in opposite directions. Leaf morphology revealed that leaves of V. tortilis are bipinnately compound with alternate arrangement. The venation pattern of the pinnules was eucamptodromus and brochidodromous with imperfect reticulation. Areoles were imperfect and pentagonal or irregular in shape. More >

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