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Evaporation of a CO2 Droplet in a High Temperature, Supercritical Pressure Environment

Yendoubouame Lare1,2,*, Koffi Sagna1,2, Amah Séna d’Almeida3
1 Department of Physics, Faculty of Sciences, Université de Lomé, Lomé, 01 BP 1515, Togo
2 Centre d’Excellence Régional Pour la Maîtrise de l’Electricité (CERME), Université de Lomé, Lomé, 01 BP 1515, Togo
3 Laboratoire d’Analyse de Modélisation Mathématique et Applications (LAMMA), Université de Lomé, Lomé, 01 BP 1515, Togo
* Corresponding Author: Yendoubouame Lare. Email: email
(This article belongs to the Special Issue: Heat and Mass Transfer on A Small Temporal and Spatial Scale)

Frontiers in Heat and Mass Transfer https://doi.org/10.32604/fhmt.2025.074506

Received 13 October 2025; Accepted 15 December 2025; Published online 19 January 2026

Abstract

This study presents a numerical investigation of the transient relaxation dynamics of a near-critical CO2 droplet immersed in a warmer supercritical environment composed of the same fluid. Three thermodynamic regimes were analysed: quasi-critical (Tr=1.01,Pr=1.01), transitional (Tr=2.01,Pr=1.01), and deep supercritical (Tr=5.01,Pr=3.01). The evolution of density, temperature, and velocity fields was examined to characterize the internal structure and stability of the interfacial transition layer. The evolution of density, temperature, and velocity fields highlights the competition between thermal diffusion, compressibility, and mass confinement in shaping the stability of the interfacial transition layer. Near the critical point, strong gradients and flux discontinuities emerge, consistent with known instabilities, whereas higher reduced conditions promote homogenization and stabilized transport. In the deep supercritical regime, smooth and nearly uniform fields indicate robust thermal stability. The model is validated against prior studies on droplet evaporation under supercritical and trans-critical conditions. Beyond theoretical insights, the results underline practical implications for advanced propulsion, heat transfer, and evaporation systems as well as for safe CO2 supercritical storage and extraction processes in energy, aerospace, pharmaceutical, and materials industries.

Keywords

Navier–Stokes equations; evaporation; supercritical pressure; temperature; density and velocity
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