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Phosphorus Containing Rubber Seed oil as a Flame Retardant Plasticizer for Polyvinyl Chloride

Hongying Chu1,2,*, Huabei Li1,2, Xiaoyan Sun1, Yaowang Zhang1,2

1 Yellow River Conservancy Technical Institute, Kaifeng, 475004, China
2 Henan Engineering Technology Research Center of Green Coating Materials, Kaifeng, 475004, China

* Corresponding Author: Hongying Chu. Email: email

(This article belongs to the Special Issue: Renewable Biomass as a Platform for Preparing Green Chemistry)

Journal of Renewable Materials 2023, 11(4), 1731-1743. https://doi.org/10.32604/jrm.2022.024160

Abstract

The application of phthalate plasticizers has been restricted around the world due to their poor migration and potential harm to the human body. Hence, producing functional bio-based plasticizers via exploiting clean and reusable resources meets the satisfaction of current demands. In this study, flame-retardant rubber seed oil-based plasticize (FRP) was prepared via epoxidation reaction and ring opening addition reactions, which was used as a flame-resistant plasticizer for polyvinyl chloride to replace petroleum-based phthalate plasticizer. When DOP was replaced with FRP, the torque of PVC blends increased from 11.4 to 18.4 N⋅m, the LOI value increased from 24.3% for PVC-FRP-0% to 33.1% for PVC-FRP-20. The THR value diminished from 39 MJ/m2 (pertaining to PVC-FRC-0) to 22 MJ/m2 Tg increased from 23°C to 47°C, the weight loss of plasticized PVC blends significantly reduced from 22.6% to 2.8% in leaching tests. The study provided a new way to prepare flame retardant plasticizer using rubber seed oil as raw material.

Graphical Abstract

Phosphorus Containing Rubber Seed oil as a Flame Retardant Plasticizer for Polyvinyl Chloride

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Cite This Article

APA Style
Chu, H., Li, H., Sun, X., Zhang, Y. (2023). Phosphorus containing rubber seed oil as a flame retardant plasticizer for polyvinyl chloride. Journal of Renewable Materials, 11(4), 1731-1743. https://doi.org/10.32604/jrm.2022.024160
Vancouver Style
Chu H, Li H, Sun X, Zhang Y. Phosphorus containing rubber seed oil as a flame retardant plasticizer for polyvinyl chloride. J Renew Mater. 2023;11(4):1731-1743 https://doi.org/10.32604/jrm.2022.024160
IEEE Style
H. Chu, H. Li, X. Sun, and Y. Zhang "Phosphorus Containing Rubber Seed oil as a Flame Retardant Plasticizer for Polyvinyl Chloride," J. Renew. Mater., vol. 11, no. 4, pp. 1731-1743. 2023. https://doi.org/10.32604/jrm.2022.024160



cc This work is licensed under a Creative Commons Attribution 4.0 International License , which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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