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Cellulose Acetate Blends – Effect of Plasticizers on Properties and Biodegradability

Vu Thanh Phuong1,2, Steven Verstichel3, Patrizia Cinelli1,4, Irene Anguillesi1, Maria-Beatrice Coltelli1, Andrea Lazzeri1,*

1 University of Pisa, Department of Civil and Industrial Engineering, Via Diotisalvi 2, 56126, Pisa, Italy
2 Can Tho University, Department of Chemical Engineering, 3/2 Street, Can Tho City, Vietnam
3 OWS N.V., Dok Noord 5, 9000 Gent, Belgium
4 National Interuniversity Consortium of Materials Science and Technology, Via G. Giusti 9, 50121, Florence, Italy

* Corresponding Author: email

Journal of Renewable Materials 2014, 2(1), 35-41.


Cellulose acetate (CDA) cannot be processed as raw material because it starts to decompose before melting. Triacetin and diacetin were tested to improve CDA processing versus conventional phthalate as environmentally sustainable plasticizers, because of their low toxicity and fast biodegradability. The addition of triacetin and diacetin allowed melt processing of CDA and the results of tensile tests outlined their effect as plasticizers. The values of mechanical properties were compatible with the requirements for applications in rigid packaging. From the results of biodegradation tests it can be concluded that for pure cellulose acetate, complete biodegradation was obtained within 200 days of testing after reinoculation. Incomplete biodegradation was observed for test items with 20% triacetin or with 30% phthalate. After 46 days of incubation, the test samples with 30% plasticizer based on triacetin or triacetin-diacetin were completely biodegraded. These formulations can be selected for the production of compostable blends and/or biocomposites.


Cite This Article

APA Style
Phuong, V.T., Verstichel, S., Cinelli, P., Anguillesi, I., Coltelli, M. et al. (2014). Cellulose acetate blends – effect of plasticizers on properties and biodegradability. Journal of Renewable Materials, 2(1), 35-41.
Vancouver Style
Phuong VT, Verstichel S, Cinelli P, Anguillesi I, Coltelli M, Lazzeri A. Cellulose acetate blends – effect of plasticizers on properties and biodegradability. J Renew Mater. 2014;2(1):35-41
IEEE Style
V.T. Phuong, S. Verstichel, P. Cinelli, I. Anguillesi, M. Coltelli, and A. Lazzeri "Cellulose Acetate Blends – Effect of Plasticizers on Properties and Biodegradability," J. Renew. Mater., vol. 2, no. 1, pp. 35-41. 2014.

cc This work is licensed under a Creative Commons Attribution 4.0 International License , which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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