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  • Open Access

    ARTICLE

    Synthesis of Cyclohexyl Acrylate Derivative and Its Evaluation as a Plasticizer for PVC

    Zhihong Wang1,#, Wei Wei1,2,#, Song Wang1, Bingli Zhou2, Yingle Chen1, Liu Yang1, Qiaoguang Li2, Lei Zeng1,*

    Journal of Polymer Materials, Vol.42, No.2, pp. 449-462, 2025, DOI:10.32604/jpm.2025.066668 - 14 July 2025

    Abstract In this study, 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate (ECC) and refined Camellia oleifera seed oil (RCOSO) obtained from saponification and acidified hydrolysis has been used as raw materials to perform ring-opening reactions for the preparation of cyclohexyl acrylate derivative (CAR). The structure of the synthesized product was characterized using infrared spectroscopy, Raman spectroscopy, and nuclear magnetic resonance spectroscopy. CAR was employed as a plasticizer to produce modified polyvinyl chloride (PVC) films, dioctyl phthalate plasticizer (DOP) used in reference samples to investigate the influence of different plasticizer molecular structures on the properties of PVC films. Observation suggested that (1) CAR More >

  • Open Access

    ARTICLE

    Synthesis and Characterization of Phenyl Camellia oleifera Seed Oil Ester Plasticizing PVC

    Wenqing Xiao1,#, Yuhang Liu2,#, Yuxin He1, Qiaoguang Li1,*, Yongquan Li3,*

    Journal of Renewable Materials, Vol.12, No.3, pp. 615-628, 2024, DOI:10.32604/jrm.2023.046780 - 11 April 2024

    Abstract Plasticizers are essential additives in the processing of polyvinyl chloride (PVC), with phthalate plasticizers being widely used. However, these conventional plasticizers have been shown to be harmful to human health and environmentally unfriendly, necessitating the exploration of eco-friendly bio-based alternatives. In this study, Camellia oleifera seed oil, a specialty resource in China, was utilized as a raw material and reacted with 4,4′-Methylenebis(N,N-diglycidylaniline) (AG-80) to synthesize Phenyl Camellia seed Oil Ester (PCSOE). PCSOE was employed as a plasticizer to prepare modified PVC films with varying concentrations, with the conventional plasticizer dioctyl phthalate (DOP) serving as a control.… More >

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