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    ARTICLE

    Thermal-Mechanical Characterization of Polyurethane Rigid Foams: Effect of Modifying Bio-Polyol Content in Isocyanate Prepolymers

    Luis Daniel Mora-Murillo1, Felipe Orozco-Gutierrez2, José Vega-Baudrit2, Rodolfo Jesús González-Paz2*

    Journal of Renewable Materials, Vol.5, No.3-4, pp. 220-230, 2017, DOI:10.7569/JRM.2017.634112

    Abstract Nowadays, green polyurethane (PU) foams are mostly synthesized by replacing an amount of petrochemical polyol with biobased polyol. Here we report five different families of isocyanate prepolymer formulations that were prepared with biobased sources and the correlation between the structure of chains and the properties of the produced PU foam. Foam behavior in tension, torsion, compression, shape memory tests and physical properties were studied by dynamic mechanical thermal analysis (DMTA); interactions in the polymer chains were analyzed by Fourier transform infrared spectroscopy (FTIR); and thermal analysis was performed by thermogravimetry (TGA) and differential scanning calorimetry (DSC). The results showed that… More >

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