Shunjie Liu1,2, Yusheng Qin1,*, Xianhong Wang1,*, Fosong Wang1
Journal of Renewable Materials, Vol.3, No.2, pp. 101-112, 2015, DOI:10.7569/JRM.2014.634140
Abstract Precursors with sharp crystalline transition temperature have attracted signifi cant attention in the fi eld of
shape-memory materials; however, seldom have reports been related to amorphous ones with industrial
application prospects. This study introduced a new family of amorphous CO2
-based hydroxyl-telechelic
three-armed oligo(carbonate-ether) triol (Triol) with controllable molecular weight (Mn) and carbonate unit
content (CU), which was coupled with PEG and 1,6-hexamethylene diisocyanate (HDI) to afford crosslinked
polyurethanes (PU) networks with well-defi ned architecture. A crosslinking point was provided by Triol
and PEG was used to afford networks some crystallinity. The resulting networks were characterized using
attentuated total refl… More >
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