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    ARTICLE

    Synthesis and Characterization of DOPO-g-CNSL and Its Effect on the Properties of Phenolic Foams

    Yufeng Ma1, Xuanang Gong1, Bing Xie1, Xiang Geng1, Puyou Jia2,*

    Journal of Renewable Materials, Vol.7, No.10, pp. 1037-1046, 2019, DOI:10.32604/jrm.2019.07454

    Abstract In order to improve the mechanical properties without reducing its flame retardancy of phenolic foams (PFs), 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) was introduced in the structure of cashew nut shell liquid (CNSL) to improve its flame retardant, and the product of DOPO grafting CNSL (DOPO-g-CNSL) was obtained to modify phenolic resin, and to prepare DOPO-g-CNSL modified PFs (DCMPFs). The structures of DOPO-g-CNSL were verified by Fourier transform infrared spectroscopy (FT-IR) and nuclear magnetic resonance (1H-NMR). Compared with CNSL, thermal stability of DOPO-g-CNSL was decreased and Ti decreased by 3.53%, but the residual carbon (800°C) was increased by 35.05%. Compared with pure PF,… More >

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