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    ARTICLE

    Material Properties and Molecular Aspects of Highly Acetylated Starch-Based Films

    Kristine Koch1,*, Daniel Johansson2, Kalle Johansson3, Karin Svegmark4

    Journal of Renewable Materials, Vol.2, No.2, pp. 134-144, 2014, DOI:10.7569/JRM.2014.634110

    Abstract Properties of starch triacetate fi lms from different botanical origins were evaluated. Tensile and barrier properties, glass transition temperatures and moisture uptake were measured, and the molecular structure was characterised. High-amylose starches were good fi lm formers, normal potato starch formed continuous but brittle fi lms and potato amylopectin formed very brittle fi lms even after plasticisation. Barley amylopectin did not form continuous fi lms. Different plasticisers were studied and diacetin was shown to perform better than the standard plasticiser triacetin. All fi lms were water resistant, and the best fi lms gave water vapour barriers in the range of… More >

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