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  • Open Access

    ARTICLE

    Acrylic Finished Leather Upgraded with Thermoplastic Polyurethane Filament using 3D Printing – A New Generation Hybrid Leather of Synthetic and Natural Polymer

    SIVARAJ SUDHAHARa,f, UMAMAHESWARI Gb, JAYA PRAKASH ALLAc, RAGHAVA RAO JONNALAGADDAd, SUGUNA LAKSHMIe, SANJEEV GUPTAf,*

    Journal of Polymer Materials, Vol.40, No.1-2, pp. 33-45, 2023, DOI:10.32381/JPM.2023.40.1-2.3

    Abstract Leather manufacturing process involves a lot of waste disposal which pollutes environment, some of the processes are inevitable. In the present investigation, 3D printing technology was used to reduce the wastage and to cover defective regions in leather. The present study focuses on synthesis of acrylic binder using emulsion polymerization technique. These binders were analysed for solid content for better optimisation of the amount of binder to be utilised for finishing operation. The experimental binder was prepared with 26% solids. Particle size and thermogravimetric analyses were carried out to understand the size and shape of the particles and their thermal… More >

  • Open Access

    ARTICLE

    Study on Mechanical Properties and Action Mechanism of Leather Industrial Sludge Aggregate Baking-Free Bricks

    Lei Guo1,2,3, Zekun Wang1, Lixia Guo1,2,3,*, Pingping Chen1

    Journal of Renewable Materials, Vol.11, No.1, pp. 453-471, 2023, DOI:10.32604/jrm.2023.023315

    Abstract Taking an industrial sludge and its preparation of sludge wrap shell aggregates (WSAs) instead of sand to prepare baking-free brick as the research object, the development law of mechanical properties and the influence mechanism of macro and micro characteristic parameters of the bricks under different sludge and WSAs replacement rates were studied through the macroscopic mechanical properties test, with the help of nuclear magnetic resonance (NMR), transmission electron microscopy-energy spectrum and other testing technology and pores and cracks analysis system (PCAS) software. The results showed that the compressive strength of each sample decreased with the increase of sludge content. When… More > Graphic Abstract

    Study on Mechanical Properties and Action Mechanism of Leather Industrial Sludge Aggregate Baking-Free Bricks

  • Open Access

    ARTICLE

    Covalent and Ionic Bonding between Tannin and Collagen in Leather Making and Shrinking: A MALDI-ToF Study

    Antonio Pizzi*

    Journal of Renewable Materials, Vol.9, No.8, pp. 1345-1364, 2021, DOI:10.32604/jrm.2021.015663

    Abstract Collagen powder hydrolysates were reacted with a solution of commercial mimosa bark tannin extract. The mixture was prepared at ambient temperature and prepared at 80°C to determine what reactions, if any, did occur between the collagen protein through its amino acids and the polyphenolic condensed tannin. The reaction products obtained were analyzed by matrix assisted laser desorption ionization time-of-flight (MALDI ToF) mass spectrometry. Reactions between the two materials did appear to occur, with the formation of a relatively small proportion of covalent and ionic linkages at ambient temperature but a considerable proportion of covalent linkages tannin-protein amino acids and the… More >

  • Open Access

    ARTICLE

    Clean Production for Chrome Free Leather by Using a Novel Triazine Compound

    Lu Cui1,2,*, Xihuai Qiang1,2

    Journal of Renewable Materials, Vol.7, No.1, pp. 57-71, 2019, DOI:10.32604/jrm.2019.00118

    Abstract Based on a novel triazine compound, the properties of tanned leather and commercial feasibility in pilot scale have been investigated. Then this novel approach tanning was compared with conventional chrome tanning: in the condition of less-salt pickling and chrome free, the physicochemical properties including thermal stability and mechanical strength were analyzed. Meanwhile, the surface roughness and fiber dispersion were evaluated as well. The results show that the thermal stability and mechanical strength of the triazine compound tanned leather are similar to conventional chrome tanned leather, the fiber bundle is well-dispersed and much evener than that of chrome treating. The optimized… More >

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