F.J. Santiago-Medina1, M.C. Basso1, A. Pizzi1,2,*, L. Delmotte3
Journal of Renewable Materials, Vol.6, No.4, pp. 413-425, 2018, DOI:10.7569/JRM.2017.634172
Abstract The reaction of a desulphurized kraft lignin with hexamethylene diamine and dimethyl carbonate has allowed the development of isocyanate-free polyurethane resins. The present research work is based on previous studies made with hydrolyzable and condensed tannins, but takes advantage of the higher number of hydroxyl groups present in lignin and their different aliphatic and aromatic character. The obtained materials were analyzed by Fourier transform infrared (FTIR) spectroscopy, matrix-assisted laser desorption ionization time-of-flight (MALDI-TOF) mass spectrometry and solid-state cross-polarization/magic angle spinning (CP MAS) 13 C nuclear magnetic resonance (NMR), which have revealed the presence of urethane functions. The interpretation of the… More >
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