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  • Open Access

    ARTICLE

    Acidic Magnetic Biocarbon-Enabled Upgrading of Biomass-Based Hexanedione into Pyrroles

    Zhimei Li1, Kuan Tian2, Keping Wang2, Zhengyi Li2, Haoli Qin1,*, Hu Li2,*

    Journal of Renewable Materials, Vol.11, No.11, pp. 3847-3865, 2023, DOI:10.32604/jrm.2023.030122

    Abstract Sustainable acquisition of bioactive compounds from biomass-based platform molecules is a green alternative for existing CO2-emitting fossil-fuel technologies. Herein, a core–shell magnetic biocarbon catalyst functionalized with sulfonic acid (Fe3O4@SiO2@chitosan-SO3H, MBC-SO3H) was prepared to be efficient for the synthesis of various N-substituted pyrroles (up to 99% yield) from bio-based hexanedione and amines under mild conditions. The abundance of Brønsted acid sites in the MBC-SO3H ensured smooth condensation of 2,5-hexanedione with a variety of amines to produce N-substituted pyrroles. The reaction was illustrated to follow the conventional PallKnorr coupling pathway, which includes three cascade reaction steps: amination, loop closure and dehydration. The… More > Graphic Abstract

    Acidic Magnetic Biocarbon-Enabled Upgrading of Biomass-Based Hexanedione into Pyrroles

  • Open Access

    ARTICLE

    Manipulating Chladni Patterns of Ferromagnetic Materials by an External Magnetic Field

    Kenneth R. Podolak*, Vihan A.W. Wickramasinghe, Gareth A. Mansfield, Alex M. Tuller

    Sound & Vibration, Vol.55, No.3, pp. 235-240, 2021, DOI:10.32604/sv.2021.015008

    Abstract Ernst Chladni is called the father of acoustics for his work, which includes investigating patterns formed by vibrating plates. Understanding these patterns helps research involving standing waves and other harmonic behaviors, including studies of single electron orbits in atoms. Our experiment vibrates circular plates which result in well-known patterns. Alternatively to traditional experiments that used sand or salt, we use magnetic materials, namely iron filings and nickel powder. We then manipulate the patterns by applying a localized external magnetic field to one of the rings that moves a segment of the magnetic material in that ring to the next inner… More >

  • Open Access

    ABSTRACT

    Magnetoplastic Effect in Nonmagnetic Materials:\\ Experimental Studies and Computer Simulations

    V.I. Alshits1,2, R.K. Kotowski1,3, P. Tronczyk1

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.6, No.4, pp. 207-214, 2008, DOI:10.3970/icces.2008.006.207

    Abstract The magnetoplastic effect manifests itself in a transformation of the structure of the impurity pinning centers in crystals exposed to an external magnetic field which modifies their mechanical properties. As a result, an ordinary nonmagnetic crystal becomes a smart material whose physical properties may be controlled by means of the external magnetic treatment. The basic features of this phenomenon and its established physical mechanisms are discussed. A series of results of experimental studies and computer simulations of the magnetoplastic effect are presented. More >

  • Open Access

    ARTICLE

    Hybrid Finite Element and Volume Integral Methods for Scattering Using Parametric Geometry

    John L. Volakis1, Kubilay Sertel1, Erik Jørgensen2, Rick W. Kindt1

    CMES-Computer Modeling in Engineering & Sciences, Vol.5, No.5, pp. 463-476, 2004, DOI:10.3970/cmes.2004.005.463

    Abstract In this paper we address several topics relating to the development and implementation of volume integral and hybrid finite element methods for electromagnetic modeling. Comparisons of volume integral equation formulations with the finite element-boundary integral method are given in terms of accuracy and computing resources. We also discuss preconditioning and parallelization of the multilevel fast multipole method, and propose higher-order basis functions for curvilinear quadrilaterals and volumetric basis functions for curvilinear hexahedra. The latter have the desirable property of vanishing divergence within the element but non-zero curl. In addition, a new domain decomposition is introduced for solving array problems involving… More >

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