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  • Open Access

    ARTICLE

    Synthesis, Structure and Properties of Poly(ester-Urethane- Urea)s Synthesized Using Biobased Diamine

    Marcin Włoch, Janusz Datta*

    Journal of Renewable Materials, Vol.4, No.1, pp. 72-77, 2016, DOI:10.7569/JRM.2015.634130

    Abstract Modern polymer science and technology is focused on the development of partial or fully green polymers. This focus is related to green chemistry trends, which propose using natural and renewable resources as monomers in the synthesis of polymers. In this study, biobased diamine was used as a chain extender of ester-urethane prepolymer. Obtained poly(ester-urethane-urea) contains 16 wt% of biobased diamine. There is mention of an amine curing agent that is an amine derivative of dimerized fatty acids (obtained from vegetable oils). Application of two chain extenders, i.e., 1,4-butanediol and biobased diamine (applied separately or in mixture), with different molecular weights… More >

  • Open Access

    ARTICLE

    Improved Permeability Properties for Bacterial Cellulose/ Montmorillonite Hybrid Bionanocomposite Membranes by In-Situ Assembling

    Itxaso Algar1, Clara Garcia-Astrain1, Alba Gonzalez2, Loli Martin3, Nagore Gabilondo1, Aloña Retegi1*, Arantxa Eceiza1*

    Journal of Renewable Materials, Vol.4, No.1, pp. 57-65, 2016, DOI:10.7569/JRM.2015.634124

    Abstract Bacterial cellulose/montmorillonite (BCMMT) hybrid bionanocomposite membranes were prepared by in-situ assembling or one-step biosynthesis process. The presence of MMT in BC membranes was confi rmed by thermogravimetric analysis and quantifi ed by mass spectrometry, resulting in bionanocomposites with MMT contents between 7–13 wt%. The incorporation of MMT during BC biosynthesis modifi ed BC morphology and led to lower porosity, even though higher water holding capacity was achieved. Bionanocomposites showed improved thermal stability and water vapor and oxygen gas barrier properties up to 70 and 80% with respect to neat BC membranes. This improvement was related to the tortuous path of… More >

  • Open Access

    ARTICLE

    Ultrasound-Assisted Synthesis of Sucrose and Fructooligosaccharides Esters as Bio-Plasticizers

    Dragomir Vassilev1*, Nadezhda Petkova2, Milena Koleva1, Panteley Denev2

    Journal of Renewable Materials, Vol.4, No.1, pp. 24-30, 2016, DOI:10.7569/JRM.2015.634125

    Abstract This article presents the results obtained by the ultrasound-assisted synthesis of sucrose and fructooligosaccharides (FOS) esters with fatty acids (palmitic and 10-undecylenic), the identifi cation of the products and the study of their possible application as plasticizers in plastics processing. Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (1H and 13C NMR) spectroscopy were used to identify the synthesized carbohydrate esters. The plasticizing effect of the sucrose palmitate applied in polyvinyl chloride (PVC) was evaluated by the glass transition temperatures; the decrease of the Tg with the increase of the ester content could be accepted as confi rmation of… More >

  • Open Access

    ARTICLE

    Effect of Mechanical Pressure on the Thickness and Collagen Synthesis of Mandibular Cartilage and the Contributions of G Proteins

    Min Zhang, Fa-Ming Chen, Yong-Jin Chen∗,‡, Shun Wu, Xin Lv, Rui-Ni Zhao

    Molecular & Cellular Biomechanics, Vol.8, No.1, pp. 43-60, 2011, DOI:10.3970/mcb.2011.008.043

    Abstract To investigate the role of mechanical pressure on cartilage thickness and type II collagen synthesis, and the role of G protein in that process, in vitro organ culture of mandibular cartilage was adopted in this study. A hydraulic pressure-controlled cellular strain unit was used to apply hydrostatic pressurization to explant cultures. The explants were compressed by different pressure values (0 kPa, 100 kPa, and 300 kPa) after pretreatment with or without a selective and direct antagonist (NF023) for the G proteins. After 4, 8 and 12 h of cell culture under each pressure condition, histological sections of the explants were… More >

  • Open Access

    ARTICLE

    A Fully Coupled Poroelastic Reactive-Transport Model of Cartilage

    Lihai Zhang*, Bruce S. Gardiner*, David W. Smith*, Peter Pivonka*, Alan Grodzinsky

    Molecular & Cellular Biomechanics, Vol.5, No.2, pp. 133-154, 2008, DOI:10.3970/mcb.2008.005.133

    Abstract Cartilage maintains its integrity in a hostile mechanical environment. This task is made more difficult because cartilage has no blood supply, and so nutrients and growth factors need to be transported greater distances than normal to reach cells several millimetres from the cartilage surface. The chondrocytes embedded within the extracellular matrix (ECM) are essential for maintaining the mechanical integrity of the ECM, through a balance of degradation and synthesis of collagen and proteoglycans. A chondrocyte senses various chemical and mechanical signals in its local microenvironment, responding by appropriate adaption of the local ECM. Clearly a 'systems understanding' of cartilage behaviour… More >

  • Open Access

    ARTICLE

    Automated Synthesis of Wideband Bandpass Filters Based on Slow-wave EBG Structures

    Marco Orellana1, Jordi Selga1, Paris Vélez1, Marc Sans1, Ana Rodríguez2, Vicente Boria2, Ferran Martín1

    CMC-Computers, Materials & Continua, Vol.52, No.3, pp. 159-174, 2016, DOI:10.3970/cmc.2016.052.157

    Abstract This paper is focused on the automated synthesis of wideband bandpass filters operating at microwave frequencies and based on electromagnetic bandgap (EBG) structures. The classical counterpart of such filter consists of a combination of transmission line sections and shunt-connected grounded stubs placed at equidistant positions. By replacing the transmission line sections with capacitively-loaded lines (a kind of EBG-based lines) exhibiting the same phase shift at the lower cutoff frequency and the same characteristic (actually Bloch) impedance, filter size is reduced and the spurious pass bands can be efficiently suppressed. In practice, the loading capacitances are implemented by means of patches,… More >

  • Open Access

    ARTICLE

    In Situ Synthesis of Cuprous Oxide/Cellulose Nanofibers Gel and Antibacterial Properties

    Ying Hu1,2, Qinfei Ke1, Zhe Li2, Wanli Han3, Zhiyong Yan2,*

    CMC-Computers, Materials & Continua, Vol.56, No.3, pp. 517-527, 2018, DOI: 10.3970/cmc.2018.03608

    Abstract Cellulose nanofibers were synthesized by acetobacter xylinum (xylinum 1.1812). The cellulose nanofibers with 30-90 nm width constructed three-dimension network gel, which could be used as a wound dressing since it can provide moist environment to a wound. However, cellulose nanofibers have no antimicrobial activity to prevent wound infection. To achieve antimicrobial activity, the cellulose nanofibers can load cuprous oxide (Cu2O) particles on the surface. The cuprous oxide is a kind of safe antibacterial material. The copper ions can be reduced into cuprous oxides by reducing agents such as glucose, N2H4 and sodium hypophosphite. The cellulose nanofibers network gel was soaked… More >

  • Open Access

    ARTICLE

    A New Efficient Matrix Algorithm for a 3D Component Mode Synthesis (CMS) Model Used on Sound Transmission Problems

    M. D. C. Magalhaes1,2

    CMES-Computer Modeling in Engineering & Sciences, Vol.105, No.6, pp. 441-465, 2015, DOI:10.3970/cmes.2015.105.441

    Abstract The main goal of this study is to present an alternative and more efficient algorithm for a three-dimensional Component Mode Synthesis model to be used on sound transmission problems. The influence of fluid-structure interaction on airborne sound transmission problems is analysed using this model, which is based on simple volume geometries. In principle, the same procedure can also be applied when the component modes are obtained from alternative numerical techniques. The modal behaviour of acoustic volumes and a partition is implemented in two steps. The novelty of this alternative model is that the structural modes are incorporated on the acoustic… More >

  • Open Access

    ARTICLE

    Topological Derivative-Based Optimization of Micro-Structures Considering Different Multi-Scale Models

    E.A. de Souza Neto1, S. Amstutz2, S.M. Giusti3, A.A. Novotny3

    CMES-Computer Modeling in Engineering & Sciences, Vol.62, No.1, pp. 23-56, 2010, DOI:10.3970/cmes.2010.062.023

    Abstract A recently proposed algorithm for micro-structural optimization, based on the concept of topological derivative and a level-set domain representation, is applied to the synthesis of elastic and heat conducting bi-material micro-structures. The macroscopic properties are estimated by means of a family of multi-scale constitutive theories where the macroscopic strain and stress tensors (temperature gradient and heat flux vector in the heat conducting case) are defined as volume averages of their microscopic counterparts over a Representative Volume Element (RVE). Several finite element-based examples of micro-structural optimization are presented. Three multi-scale models, providing an upper and a lower bound for the macroscopic… More >

  • Open Access

    ARTICLE

    Optimal Plastic Synthesis of Structures with Unilateral Supports Involving Frictional Contact

    S. Tangaramvong, F. Tin-Loi

    CMES-Computer Modeling in Engineering & Sciences, Vol.49, No.3, pp. 269-296, 2009, DOI:10.3970/cmes.2009.049.269

    Abstract We consider the optimal synthesis, namely minimum weight design, of rigid perfectly-plastic structures for which some supports involve unilateral frictional contact. This problem is of interest as it is not only encountered in practice but it also involves, in the general friction case, a nonassociative complementarity condition that makes it theoretically and numerically challenging. For simplicity of exposition, we focus on the class of bar structures for which yielding is governed by either pure bending or by combined axial and flexural forces. In view of possible multiplicity of solutions due to nonassociativity, a direct optimization formulation may lead to an… More >

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