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    ARTICLE

    Fabrication of UV–Curing Linalool–Polysiloxane Hybrid Films with High Refractive Index and Transparency

    Wenqing Xiao1,#, Lewen Tan1,2,#, Xunjun Chen1,*, Qiaoguang Li1,*, Yunqing Ruan1

    Journal of Renewable Materials, Vol.12, No.3, pp. 569-583, 2024, DOI:10.32604/jrm.2023.046662

    Abstract

    In this article, a series of high refractive indices (1.50–1.53) thiol phenyl polysiloxane (TPS) were synthesized via hydrolytic sol–gel reaction. The Fourier transform infrared spectra (FT–IR) and nuclear magnetic resonance spectra (NMR) results showed that TPS conformed to the predicted structures. Natural terpene linalool was exploited as photocrosslinker to fabricate UV–curing linalool–polysiloxane hybrid films (LPH) with TPS via photoinitiated thiol–ene reaction. LPH rapidly cured under UV irradiation at the intensity of 80 mW/cm2 in 30 s, exhibiting good UV–curing properties. The optical transmittance of LPH in the wavelength of 300–800 nm was over 90%, exhibiting good optical transparency. The water… More >

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