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  • Open Access

    ARTICLE

    Synthesis, characterization of zirconium doped cobalt nanoparticles and study of their thermoelectric properties

    Y. Arooja, A. Farhanb, S. Maqsooda,c, A. Eruma, M. Ishaqd, S. Rafiquea, A. Khalidb, F. Wazahata, M. A. Qamare,*

    Chalcogenide Letters, Vol.22, No.8, pp. 707-717, 2025, DOI:10.15251/CL.2025.228.707

    Abstract Chemical co-precipitation synthesis was used to make pure and zirconium-doped cobalt sulfide (Co3S4) nanoparticles (NPs). Important characterizations such as FTIR, UV-VIS, Raman, PL, SEM, XRD, and four probe methods were used to examine the influence of the Zr (0%, 5%, 10%, 15%, and 20%) doping on optical, electrical, structural, and thermoelectric characteristics of Co3S4 NPs. X-ray diffraction and SEM examination verified the cubic structure and grain size of pure and Zr-doped Co3S4-NPs. The FTIR spectrum revealed the rotational and vibrational modes linked to the material's surface. The material is optimal for photocatalytic activity with a redshift More >

  • Open Access

    ARTICLE

    CoS Nanosheets Coated with Dopamine-Derived Carbon Standing on Carbon Fiber Cloth as Binder-Free Anode for Li-ion Batteries

    Lianyuan Ji1, Mingchen Shi1, Zengkai Feng2, Hui Yang1,*

    Journal of Renewable Materials, Vol.12, No.2, pp. 259-274, 2024, DOI:10.32604/jrm.2023.030599 - 11 March 2024

    Abstract

    Cobalt sulphides attract much attention as anode materials for Li-ion batteries (LIBs). However, its poor conductivity, low initial column efficiency and large volume changes during cycling have hindered its further development. Herein, novel interlaced CoS nanosheets were firstly prepared on Carbon Fiber Cloth (CFC) by two hydrothermal reactions followed with carbon coating via carbonizing dopamine (CoS NS@C/CFC). As a freestanding anode, the nanosheet structure of CoS not only accommodates the volume variation, but also provides a large interface area to proceed the charge transfer reaction. In addition, CFC works as both a three-dimensional skeleton and an

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