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  • Open Access

    ARTICLE

    Study on Flame-retardant Mechanism of Epoxy Resin containing Polyvinylphenylsilsesquioxane

    JIANGBO WANG*

    Journal of Polymer Materials, Vol.36, No.4, pp. 381-389, 2019, DOI:10.32381/JPM.2019.36.04.7

    Abstract In this study, a novel flame retardant polyvinylphenylsilsesquioxane (PVP) was added into epoxy resin (EP) to prepare EP/PVP (FREP) composites. The results of cone calorimeter measurement showed that in comparison with virgin EP, the peak heat release rate (PHRR) and total heat release (THR) of FREP were reduced by 27.3% and 10.4%, respectively. Moreover, the thermal degradation behavior of FREP was studied by the Kissinger and Ozawa-Flynn-Wall methods. The results suggested that the addition of PVP greatly enhanced the thermal stability of EP in the final stage, which could be attributed to that the branched silicone with vinyl and phenyl… More >

  • Open Access

    ARTICLE

    Study of Burning Behaviors and Fire Risk of Flame Retardant Plywood by Cone Calorimeter and TG Test

    Liping Yu1, Zhongyou Luo1, Lifen Li1, Xuedong Xi2,3, Zhigang Wu1,2,*, Bengang Zhang4,*

    Journal of Renewable Materials, Vol.9, No.12, pp. 2143-2157, 2021, DOI:10.32604/jrm.2021.016092

    Abstract A flame retardant composition was prepared by using phosphoguanidine, guanidine sulfamate, disodium octaborate tetrahydrate and dodecyl dimethyl benzyl ammonium chloride. Veneers were immersed in such flame retardant mixture to prepare plywood. The combustion characteristics and thermal stability of plywood were assessed using a cone calorimeter and TG. Results showed that: (1) High concentration and loading of flame retardant were beneficial for the fire resistance of the plywood. (2) The limiting oxygen index (LOI) and residual mass of plywood processed using the flame retardant was increased by 87.52% and 58.66% compared to those of the untreated plywood, while the average heat… More >

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