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  • Open Access

    ARTICLE

    Swelling dynamics of Poly (N, N- Dimethylacrylamide - co- Crotonic acid) Hydrogel and Evaluation of its Potential for Controlled Release of Fertilizers

    FATMA LOUZRI, SADJIA BENNOUR

    Journal of Polymer Materials, Vol.37, No.1-2, pp. 55-76, 2020, DOI:10.32381/JPM.2020.37.1-2.5

    Abstract Poly(N,N-dimethymethylacrylamide -co-crotonic acid) (P(DMA-CAx)) hydrogels were prepared by free radical polymerization, using N,N- methylenebisacrylamide (NMBA) as cross-linking agent. The synthesized hydrogels were characterized by Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA). The effects of comonomer composition and pH of the medium on the swelling behavior of hydrogels were investigated. The obtained results showed that the swelling capabilities of hydrogels increased as crotonic acid content and pH increased. In order to evaluate the controlled release potential of the polymeric matrix, it was loaded with potassium nitrate and ammonium nitrate as fertilizers and the release kinetics was studied as a… More >

  • Open Access

    ARTICLE

    Synthesis of Novel Nanocomposite Based on Carboxymethylcellulose (CMC), Kaolin and Urea Fertilizer for Controlled Release

    NALINI SHARMA1,*, AJAY SINGH2, RAJ KUMAR DUTTA3

    Journal of Polymer Materials, Vol.37, No.1-2, pp. 1-15, 2020, DOI:10.32381/JPM.2020.37.1-2.1

    Abstract Controlled Release fertilizers (CRFs) are new generation agrochemicals which aid in decreasing environmental pollution. In the present study, novel CRF beads are synthesized by the technique of sol-gel polymerization. CMC polymer at various concentrations was used as a matrix and kaolin was used as a binder to enhance mechanical properties of the beads. The study also reveals the incorporation of Kaolin at different concentrations and optimization of the same. Fe3+ was used as a cross-linker to obtain spherical beads. Also, a study was done to optimize the cross linking time and concentration of cross linking solution. The usage of polymers… More >

  • Open Access

    ARTICLE

    Controlled-Release of Plant Volatiles: New Composite Materials of Porous Carbon-Citral and Their Fungicidal Activity against Exobasidium vexans

    Yaoguo Liu1, Yao Chen2, Huifang Liu2, Wei Chen1, Zhiwei Lei2, Chiyu Ma2, Jie Yin1, Wen Yang2,*

    Journal of Renewable Materials, Vol.11, No.2, pp. 811-823, 2023, DOI:10.32604/jrm.2022.022594

    Abstract Citral (Eo) exhibits excellent fungicidal activities. However, it is difficult to maintain long-term fungicidal activity due to its strong volatility. Herein, a controlled-release strategy by using biomass-derived porous carbon (BC) was developed to overcome the drawback of Eo. New composite materials were prepared by loading Eo on tea stem porous carbon (BC@Eo), and their controlled-release fungicidal activity against Exobasidium vexans was assessed. BC with a large specific surface area of 1001.6 m2/g and mesoporous structure was fabricated through carbonization temperature of 700°C. The BC@Eo materials were characterized using Fourier-transform infrared spectroscopy and X-ray powder diffraction. The results suggested that chemical… More > Graphic Abstract

    Controlled-Release of Plant Volatiles: New Composite Materials of Porous Carbon-Citral and Their Fungicidal Activity against <i>Exobasidium vexans</i>

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