Thomas J. Nelson, Lindsey Bultema, Neal Eidenschink, Dean C. Webster^*

Journal of Renewable Materials, Vol.1, No.2, pp. 141-153, 2013, DOI:10.7569/JRM.2013.634113

Abstract Bio-based polyols with high functionality were successfully synthesized by ring-opening epoxidized sucrose esters of soybean oil with methanol under acidic conditions, and were subsequently formulated with blocked isocyanates to form one package polyurethanes (1KPU). The bio-based polyols were characterized by gel permeation chromatography (GPC), Fourier transform infrared (FTIR) spectroscopy, proton nuclear magnetic resonance (1 H-NMR) spectroscopy, and Brookfi eld viscosity. Bio-based coatings were prepared by formulating the polyols with blocked polyisocyanates based on isophorone diisocyanate (IPDI) and hexamethylene diisocyanate (HDI). Two types of bio-based polyols were synthesized and the ratio of NCO:OH functional groups was varied to explore the effect… More >

Xu Yan¹, Changheng Liu², Liang Qiao¹, Kaili Zhu², Hongsheng Tan^1,*, Shuhua Dong¹, Zhitao Lin¹

Journal of Renewable Materials, Vol.10, No.4, pp. 1039-1048, 2022, DOI:10.32604/jrm.2022.017239

Abstract The crystallization behavior, crystal morphology and form, and viscoelastic behavior of poly(butylene succinate) (PBS) and coir fiber/PBS composites (CPB) were investigated by differential scanning calorimetry (DSC), polarized optical microscopy (POM), X-ray diffraction (XRD) and dynamic mechanical analysis (DMA). The results of DSC measurement show that the crystallization temperature increases with the filling of coir fibers. POM images reveal that the spherulitic size and crystallization behavior of PBS are influenced by the coir fibers in the composites. XRD curves show that the crystal form of pure PBS and CPB are remaining almost identical. In addition, the storage modulus of CPB significantly… More >

M. Asim¹, M. Jawaid^1,2*, M. Nasir³, N. Saba¹

Journal of Renewable Materials, Vol.6, No.4, pp. 383-393, 2018, DOI:10.7569/JRM.2017.634162

Abstract This study deals with the analysis of dynamic mechanical, thermal and flammability properties of treated and untreated pineapple leaf fiber (PALF) and kenaf fiber (KF) phenolic composites. Results indicated that storage modulus was decreased for all composites with increases in temperature and pattern of slopes for all composites, having almost the same values of E' at glass transition temperature (Tg). The peak of the loss modulus of pure phenolic composites was shown to be much less. After the addition of kenaf/PALF, peaks were higher and shifted towards a high temperature. The Tan delta peak height was low for pure phenolic… More >