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  • Open Access

    ARTICLE

    Towards Solar-Driven Formation of Robust and Self-Healable Waterborne Polyurethane Containing Disulfide Bonds via in-situ Incorporation of 2D Titanium Carbide MXene

    Sai Gong1,2,#, Shanglin Xiang1,#, Tingwei Wang1,*, Dongyu Cai2,*

    Journal of Renewable Materials, Vol.11, No.3, pp. 1063-1076, 2023, DOI:10.32604/jrm.2022.023011

    Abstract Waterborne polymers are vital for coating industry to reduce carbon emissions. However, formation of robust and self-healable films at ambient temperature remains a challenge owing to high energy cost of film formation process. This work reports a solar-driven film formation of waterborne polyurethanes (WPUs) containing disulfide bonds via in-situ incorporation of 2D titanium carbide (MXene) with ability to convert light to heat. Instead of directly mixed with WPUs, MXene is added to join the reaction with isocyanate-terminated pre-polymer before emulsification process. This approach not only prevents aggregation of MXene in water but stabilizes MXene against thermal degradation which is the… More > Graphic Abstract

    Towards Solar-Driven Formation of Robust and Self-Healable Waterborne Polyurethane Containing Disulfide Bonds via <i>in-situ</i> Incorporation of 2D Titanium Carbide MXene

  • Open Access

    ABSTRACT

    Thin Film Formation and Photovoltaic Application of Transition Metal Dichalcogenides By Liquid Exfoliation

    Seung Kyo Lee, Dongil Chu, Eun Kyu Kim*

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.21, No.4, pp. 93-93, 2019, DOI:10.32604/icces.2019.04995

    Abstract We studied on a liquid exfoliation technique for the robust production of transition metal dichalcogenides (TMDC) thin films, because this technique has advantages for residue-free, large-scale, and low-cost fabrication. During the process of liquid exfoliation, a mixture of DI water and ethanol was used to obtain higher concentrations of TMDC flakes in the solution compared to that in water-based solution. The film thicknesses were controlled by a two-step centrifuge process to analyze the influence on the photovoltaic properties with gold/TMDC/silicon geometry. Based on ultraviolet photoelectron spectroscopy measurement results, the energy band diagram of the devices using MoS2 and WS2 films… More >

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