Zhimei Li¹, Kuan Tian², Keping Wang², Zhengyi Li², Haoli Qin^1,*, Hu Li^2,*

Journal of Renewable Materials, Vol.11, No.11, pp. 3847-3865, 2023, DOI:10.32604/jrm.2023.030122

Abstract Sustainable acquisition of bioactive compounds from biomass-based platform molecules is a green alternative for existing CO₂-emitting fossil-fuel technologies. Herein, a core–shell magnetic biocarbon catalyst functionalized with sulfonic acid (Fe₃O₄@SiO₂@chitosan-SO₃H, MBC-SO₃H) was prepared to be efficient for the synthesis of various N-substituted pyrroles (up to 99% yield) from bio-based hexanedione and amines under mild conditions. The abundance of Brønsted acid sites in the MBC-SO₃H ensured smooth condensation of 2,5-hexanedione with a variety of amines to produce N-substituted pyrroles. The reaction was illustrated to follow the conventional PallKnorr coupling pathway, which includes three cascade reaction steps: amination, loop closure and dehydration. The… More > Graphic Abstract

María Belén Colombo Migliorero, Valeria Palermo^*, Patricia Graciela Vázquez, Gustavo Pablo Romanelli

Journal of Renewable Materials, Vol.5, No.3-4, pp. 167-173, 2017, DOI:10.7569/JRM.2017.634108

Abstract The utilization and valorization of industrial waste is an effective strategy for environmental protection. Since the juice industry generates a huge amount of citrus waste, we studied the application of thermally treated orange peel in catalysis. On the other hand, Keggin heteropolyacids are excellent oxidant catalysts used as a replacement for conventional oxidants; however, their solubility in polar solvents and the low specific area limit their use as heterogeneous catalysts. The utilization of treated orange peel as heteropolyacid support for the selective oxidation of sulfides is presented here. Firstly, orange peel was thermally treated, and then it was incorporated with… More >