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  • Open Access

    ARTICLE

    Grain Boundary Passivation Modulated by Molecular Doping for High-Performance Perovskite Solar Cells

    Yangyang Hao, Yue Liu*, Guorui Cao*

    Journal of Renewable Materials, Vol.10, No.12, pp. 3505-3519, 2022, DOI:10.32604/jrm.2022.023122

    Abstract Aiming to reduce the defects of perovskite film and improve carrier transport, an organic small molecule, benzo [d]isothiazol-3(2H)-one 1,1-dioxide (OBS), is introduced as an additive in the solution-processing of perovskite and prepare uniform perovskite films with a continuous distribution of OBS at grain boundaries. Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy are conducted to reveal the interactions of hydrogen bonding and coordination bonding between OBS and perovskite. Various characterizations (including X-ray diffraction, UV-vis spectroscopy, electrochemical impedance spectroscopy, etc.) are conducted to uncover the effect of OBS on device performance. Consequently, high efficiency of 23.26% is obtained for the OBS-treated… More > Graphic Abstract

    Grain Boundary Passivation Modulated by Molecular Doping for High-Performance Perovskite Solar Cells

  • Open Access

    ARTICLE

    Supramolecular Design of Cellulose Hydrogel Beads

    Poonam Trivedi1, Jens Schaller2, Jan Gustafsson1, Pedro Fardim1,3*

    Journal of Renewable Materials, Vol.5, No.5, pp. 400-409, 2017, DOI:10.7569/JRM.2017.634143

    Abstract In the present study, we report the supramolecular design of cellulose-sulfonate hydrogel beads by blending water soluble sodium cellulose ethyl sulfonate (CES) with the pretreated cellulose in sodium hydroxide-ureawater solvent system at −6 °C followed by coagulation in the 2M sulfuric acid system. The increasing of CES amount from 10% to 90% had a substantial effect on the viscosity and storage (G′) and loss (G″) moduli of the blended solutions. The CES concentration up to 50% in blends led to the formation of physically stable hydrogels after coagulation in acidic medium at pH-1 and showed the retention of nearly the… More >

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