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  • Open Access

    ARTICLE

    Preparation and characterization of ZnO@MoS2 nanocomposites: investigating photoelectrical, electrocatalytic, and electrochemical behaviors

    J. M. Shi*, H. F. Zhang, H. C. Wang

    Chalcogenide Letters, Vol.21, No.3, pp. 263-274, 2024, DOI:10.15251/CL.2024.213.263

    Abstract This study presents the synthesis and characterization of 3D ZnO@MoS2 nanocomposites, demonstrating their superior performance in photoelectrochemical applications. Employing a combination of hydrothermal and solvothermal methods, the research focuses on creating heterostructures with optimized interfacial characteristics. The ZnO@MoS2 composites show a substantial increase in photocurrent density (1.02 mA/cm²), compared to ZnO nanorods (0.32 mA/cm²), underlining enhanced charge separation efficiency. In electrocatalytic hydrogen evolution, the heterostructures exhibit a lower onset potential (-175 mV vs RHE) and reduced Tafel slope (51 mV/dec), indicating improved catalytic activity over MoS2 nanosheets. Additionally, the composites demonstrate a significant increase in electrochemical capacitance (398 More >

  • Open Access

    ARTICLE

    Rational design of MoS2 nanosheet/ MoS2 nanowire homostructures and their enhanced hydrogen evolution reaction

    L. Yang*, X. Q. Yuan, R. Y. Liu, R. X. Song, Q. W. Wang, W. Liang

    Chalcogenide Letters, Vol.20, No.9, pp. 639-648, 2023, DOI:10.15251/CL.2023.209.639

    Abstract In this paper, we report a facile method for the synthesis of MoS2 nanosheet/ MoS2 nanowire homostructures by growing MoS2 nanosheets on the surface of MoS2 nanowires. Benefiting from the uniform coating of MoS2 nanosheets on the surface of MoS2 nanowires, the MoS2 nanosheet/ MoS2 nanowire homostructures highly expose their electrocatalytic active edge sites and exhibit an enhanced electrocatalytic performance. It demonstrates a low overpotential of 107 mV at 10 mA/cm2 and a small Tafel slope of 64 mV/dec in 0.5 M H2SO4. This work provides an inspiration for the design of efficient electrocatalysts with no stacking and aggregation More >

  • Open Access

    ARTICLE

    Self-Supported Nanoporous Gold with Gradient Tin Oxide for Sustainable and Efficient Hydrogen Evolution in Neutral Media

    Xianglong Lu1, Tianshui Yu1, Hailing Wang1, Ruichun Luo2, Pan Liu2, Songliu Yuan1, Lihua Qian1,*

    Journal of Renewable Materials, Vol.8, No.2, pp. 133-151, 2020, DOI:10.32604/jrm.2020.08650 - 01 February 2020

    Abstract Hydrogen evolution reaction (HER) in neutral medium suffers from slow kinetics as compared to that in alkaline or acidic conditions, owing to larger Ohmic loss and low proton concentration. Here we report that a self-supported nanoporous Au-SnOx (NP Au-SnOx) catalyst with gradient tin oxide surface could significantly enhance HER activity in neutral buffer solution (0.2 M PBS). The NP Au-SnOx catalyst exhibits a low onset overpotential of 38 mV and a small Tafel slope of 79 mV dec−1 . The current density of 10 mA cm−2 is manifested at an overpotential as low as 148 mV, representing the More >

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