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    ARTICLE

    Low-Temperature Synthesis of Nano-AlN Based on Solid Nitrogen Source by Plasma-Assisted Ball Milling

    Zhuoli Yang1, Xianbin Hou2, Leyang Dai2,*

    Journal of Renewable Materials, Vol.11, No.6, pp. 2941-2951, 2023, DOI:10.32604/jrm.2023.025723

    Abstract Plasma-assisted ball milling was carried out on the Al+C3H6N6 system and Al+C4H4N4 system, respectively. The phase structure, functional groups and synthesis mechanism were analyzed by XRD and FT-IR, and the differences in the synthesis process of nano-AlN with different solid nitrogen sources were discussed. The results show that C3H6N6 has a stable triazine ring structure, and its chemical bond is firm and difficult to break, so AlN cannot be synthesized directly by solid-solid reaction at room temperature. However, there are a large number of nitrile groups (-CN) and amino groups (-NH2) in C4H4N4 molecules. Under the combined action of plasma… More >

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